Ditlevsenpehrson7630

A modification was proposed to the Dušek model that incorporates an additional term, which accounts for the probability of finding elastic chains in a polymer network. Using the modified equation, Mc values were varied as expected with the molecular weight of DGEBA and insensitive to the amount of the solvent initially used during cure. Furthermore, the modified Mc values were shown to be consistent with the dry Tg values in view of the Fox and Loshaek model.Current oil-water separation methods require a significant power, a high processing time, and costly equipment, which typically yield low treatment efficiency. Pulsed direct current (dc) electric fields and recently nonuniform electric fields caught considerable attention in the petroleum industry research in order to address the most common oil-water separation issues such as chain formation, partial coalescence, and low efficiency in either the energy consumption or coalescence rate. Here, a contact-less charge injection method induced by corona discharge is utilized to investigate the impacts of nonuniform and pulsed dc electric fields on the coalescence of water droplets inside an oil medium. The operating process parameters were experimentally calibrated and optimized with the goal of increasing the effectiveness and energy consumption efficiency of the coalescence process. High-speed imaging and image processing techniques were used in order to investigate the effect of different active forces (i.e., dipole-dipole interaction, migratory coalescence, or electrophoresis, and dielectrophoresis) during the coalescence process. Different pulsed dc frequencies and pure dc waveforms were utilized and their impact on the coalescence of water droplets was investigated. Trichostatin A An optimal coalescence recipe was proposed by continuous measurement of the distance, velocity, and acceleration of the coalescing water droplets. The results of this study suggest use of pulsed dc and pure dc electric fields for coalescence of water droplets in concentrated and dispersed emulsions, respectively.In this work, a series of para-substituted α-phenyl-N-tert-butyl nitrones (PBN) were studied. Their radical-trapping properties were evaluated by electron paramagnetic resonance, with 4-CF3-PBN being the fastest derivative to trap the hydroxymethyl radical (•CH2OH). The redox properties of the nitrones were further investigated by cyclic voltammetry, and 4-CF3-PBN was the easiest to reduce and the hardest to oxidize. This is due to the presence of the electron-withdrawing CF3 group. Very good correlations between the Hammett constants (σp) of the substituents and both spin-trapping rates and redox potentials were observed. These correlations were further supported by computationally determined ionization potentials and atom charge densities. Finally, the neuroprotective effect of these derivatives was studied using two different in vitro models of cell death on primary cortical neurons injured by glutamate exposure or on glial cells exposed to t BuOOH. Trends between the protection afforded by the nitrones and their lipophilicity were observed. 4-CF3-PBN was the most potent agent against t BuOOH-induced oxidative stress on glial cells, while 4-Me2N-PBN showed potency in both models.A ternary photocatalyst, Fe3O4-loaded g-C3N4/C-layered composite (g-C3N4/C/Fe3O4) was fabricated by a facile sonication and in situ precipitation technique. Carbon nanosheets were prepared using the remaining non-metallic components of waste printed circuit boards as carbon sources. In this hybrid structure, g-C3N4 was immobilized on the surfaces of carbon nanosheets to form a layered composite, and 10-15 nm Fe3O4 nanoparticles are uniformly deposited on the surface of the composite material. The photocatalytic performance of the catalyst was studied by degrading tetracycline (TC) under simulated sunlight. The results showed that the photoactivity of the g-C3N4/C/Fe3O4 composite to TC was significantly enhanced, and the degradation rate was 10.07 times higher than that of pure g-C3N4, which was attributed to Fe3O4 nanoparticles and carbon nanosheets. Carbon sheets with good conductivity are an excellent electron transporter, which promotes the separation of photogenerated carriers and the Fe3O4 nanoparticles can utilize electrons effectively as a center of oxidation-reduction. Moreover, a possible photocatalytic mechanism for the excellent photocatalytic performance was proposed.Cholinesterases (ChE) are well-known drug targets for the treatment of Alzheimer's disease (AD). In continuation of work to develop novel cholinesterase inhibitors, we utilized a structure-based scaffold repurposing approach and discovered six novel ChE inhibitors from our recently developed DNA gyrase inhibitor library. Among the identified hits, two compounds (denoted 3 and 18) were found to be the most potent inhibitor of acetylcholinesterase (AChE, IC50 = 6.10 ± 1.01 μM) and butyrylcholinesterase (BuChE, IC50 = 5.50 ± 0.007 μM), respectively. Compound 3 was responsible for the formation of H-bond and π-π stacking interactions within the active site of AChE. In contrast, compound 18 was well fitted in the choline-binding pocket and catalytic site of BuChE. Results obtained from in vitro cytotoxicity assays and in silico derived physicochemical and absorption, distribution, metabolism, and excretion (ADME) properties indicate that repurposed scaffold 3 and 18 could be potential drug candidates for further development as novel ChE inhibitors.Controlled synthesis of GaAs nanowires (NWs) with specific phases and orientations is important and challenging, which determines their electronic performances. Herein, single-crystalline GaAs NWs are successfully synthesized by using complementary metal-oxide semiconductor compatible Cu2O catalysts via chemical vapor deposition at an optimized temperature of 560 °C. In contrast to typically Au catalyzed GaAs NWs, the Cu2O catalyzed ones are found to grow along nonpolar orientations of zincblende . The Cu2O catalysts are found to change into orthorhombic Cu5As2 after the NW growth, which is also significantly distinguished from the Au-Ga catalyst alloy in the literature. The Cu5As2 alloy plays the epitaxy role in the nonpolar GaAs NW growth due to the lattice matching with the nonpolar planes of GaAs, which is verified by the atomic stack model. These nonpolar oriented GaAs NWs have minimized stacking faults, promising for the other semiconductor synthesis as well as electronic applications.