Carterhove6546

ising public awareness regarding chemicals in children's products are recommended.A new biorefinery conceptual process is proposed for biohydrogen and biomethane production from a combination of fruits and vegetable wastes (FVW) and corn stover (CS). The objective of this work was to perform the acid hydrolysis (HCl 0.5% v/v, 120 °C, 2 h) of the FVW and CS at 31 dry basis ratio, and to process its main physical phases, liquid hydrolyzates (LH) and hydrolyzed solids (HS), by mesophilic dark fermentation (DF) and anaerobic digestion (AD), respectively. In DF of LH as carbon source, hydrogen was produced at maximum rate of 2.6 mL H2/(gglucose h) and maximum accumulation of 223.8 mL H2/gglucose, equivalent to 2 mol H2/molglucose, in a butyric-pathway-driven fermentation. Darolutamide HS were digested to methane production assessing inoculum to substrate ratios in the range 2-4 ginoculum/gVS. The main results in AD were 14 mmol CH4/gvs. The biorefinery demonstrated the feasibility to integrate the acid hydrolysis as pretreatment and subsequently use the LH for hydrogen production, and the HS for methane production, with an energy yield recovery of 9.7 kJ/gvs, being the energy contribution from anaerobic digestion 8-fold higher than of dark fermentation.Faster spread of epidemics has turned local concerns into global crises; antimicrobial resistance (AMR) is being considered a major threat to public health in the twenty-first century. Antibiotic misuse plays a great role in accelerated AMR; thus, understanding and discussing consumption patterns has been a trend topic over the past years. Developing countries, such as Brazil, have high growth rates in antibiotic consumption, potentially impacting global environmental safety. This study presents the compiled information from the Brazilian Health Regulatory Agency (ANVISA) on antibiotic dispensation across the country and maps the consumption trends between the years of 2013 and 2016. The most consumed substances were beta-lactams (amoxicillin and cephalexin) and macrolides (azithromycin). National relative growth consumption in the mentioned period was 18%. At the local level, growth of consumption ranged from 4 to 85%, with rampage growth concentrated in the North and Northeast regions. Brazilian laws, such as restriction of over-the-counter sales and mandatory report on dispensation, seem to have little effect on the national antibiotic consumption growth. This phenomenon growth is still elevated if compared with developed countries, demonstrating the need for further surveillance as well as coordinated efforts aiming at antibiotic use and AMR prevention.Endocrine disruptors represent risks to aquatic ecosystem and humans, and are commonly detected in surface water. Photochemical treatments can be used to remove 17β-estradiol (E2), but few studies have analyzed the kinetics, intermediates, and 17β-estradiol degradation pathways in natural matrices. In this study, the photochemical behavior of E2 under ultraviolet irradiation (UVC, 254 nm) associated with oxidants (H2O2 or O3) or photocatalyst (TiO2) was investigated to evaluate the degradation potential and the transformation pathway in a natural surface water matrix. Additionally, computational modeling analyses with Ecological Structure Activity Relationships (ECOSAR) software were performed to predict the toxicity from the E2 and its transformation byproducts. E2 degradation kinetics showed adjusted to the pseudo-first-order kinetic model, being kUV/O3 > kUV/TiO2 > kUV/H2O2 > kUV. Eight transformation byproducts were identified by liquid chromatography with time-of-flight mass spectrometry (HPLC/TOF-MS) in natural surface water samples. These byproducts formed as the result of opening the aromatic ring and adding the hydroxyl radical. The E2 degradation pathway was proposed based on the byproducts identified in this study and in previous studies, suggesting the formation of aliphatic and hydroxylated byproducts. E2 treatment presented both very toxic and not harmful byproducts.A detailed characterization of municipal solid waste (MSW) beyond a standard compositional analysis may offer insights useful for improving waste management systems. The present paper contributes to the scarce literature in the field by presenting new data from a rapidly developing Central Asian city, the capital of Kazakhstan, Nur-Sultan. Three sampling campaigns (each 1 week long) have been conducted at the city landfill over a 1-year period (2018-2019), and a detailed characterization for selected waste components and sub-components has been performed. The major fractions of MSW were organics (46.3%), plastics (15.2%), paper (12.8%), and diapers (5.9%). The detailed composition analysis showed high LDPE (low-density polyethylene) content (5.5%) mostly comprised of plastic bags (4.5%), transparent glass (3.2%), pharmaceuticals (0.4%), and fine (i.e., less then  12 mm) organic fraction content (29%). The MSW generation rate of Nur-Sultan was estimated as 1.47 kg capita-1 day-1 based on the field collection as well as literature data. Among sustainable waste management recommendations addressed for Nur-Sultan and applicable to other cities in Central Asia, composting is recommended due to high organics fraction in MSW and its great potential to reduce the landfilled waste volume and to help valorizing the waste.Rainfall runoff pollution is one of the main causes of water quality deterioration in urban water system. Setting up initial rainwater storage tank could be one of the rapid and effective methods to control runoff pollution. In order to speed up the water environment management processes, the Chinese government has adopted the Public-Private-Partnership (PPP) mode in the water environment treatment to deal with the shortage of funds. Ensuring water quality and controlling water environment management cost are key to PPP projects. Therefore, factors such as pollutant accumulation characteristics of the catchment, land space availability, sewage treatment plants capacity, and river water management cost should be considered during the design of the initial rainwater storage tank on the premise of ensuring water quality. The empirical design method can hardly meet these requirements simultaneously. Under the background of PPP water environment treatment project, a constrained economic optimization model of the initial rainwater storage tank was presented in this paper.