Carrollwyatt5442

We provide here a tool to evaluate the environmental persistence of benzotrifluoride contaminants, as well as to design more photodegradable new active ingredients.Knowledge of the transport and retention behaviors of soft deformable particles on the microscale is essential for the design, evaluation, and application of engineered particle materials in the fields of energy, environment, and sustainability. Emulated convergent-divergent microchannels were constructed and used to investigate the transport and retention behaviors of soft deformable polyacrylamide microspheres at various conditions. Five different types of transport and retention patterns, i.e., surface deposition, smooth passing, direct interception, deforming remigration, and rigid blockage, are observed. Flow resistance variation characteristics caused by different patterns were quantitatively analyzed. Effects of flow rate, pore-throat size, particle size, and injection concentration on transport and retention patterns have been studied, and transport and retention pattern maps are presented and discussed.Microbial anaerobic alkane degradation is a key process in subsurface oil reservoirs and anoxic environments contaminated with petroleum, with a major impact on global carbon cycling. However, the thermophiles capable of water-insoluble paraffins (>C17) degradation under methanogenic conditions has remained understudied. Here, we established thermophilic (55 °C) n-paraffins-degrading (C21-C30) cultures from an oil reservoir. After over 900 days of incubation, the even-numbered n-paraffins were biodegraded to methane. The bacterial communities are dominated by a novel class-level lineage of actinobacteria, 'Candidatus Syntraliphaticia'. These 'Ca. Syntraliphaticia'-like metagenome-assembled genomes (MAGs) encode a complete alkylsuccinate synthases (ASS) gene operon, as well as hydrogenases and formate dehydrogenase, and several enzymes potentially involved in alkyl-CoA oxidation and the Wood-Ljungdahl pathway. Metatranscriptomic analysis suggests that n-paraffins are activated via fumarate addition reaction, and oxidized into carbon dioxide, hydrogen/formate and acetate by 'Ca. Syntraliphaticia', that could be further converted to methane by the abundant hydrogenotrophic and acetoclastic methanogens. selleck compound We also found a divergent methyl-CoM reductase-like complex (MCR) and a canonical MCR in two MAGs representing 'Ca. Methanosuratus' (within candidate phylum Verstraetearchaeota), indicating the capability of methane and short-chain alkane metabolism in the oil reservoir. Ultimately, this result offers new insights into the degradability and the mechanisms of n-paraffins under methanogenic conditions at high temperatures.Manganese and arsenic both threaten groundwater quality globally, but their chemical behavior leads to both co-contamination and separation of these contaminants from individual well to regional scales. Here we tested manganese and arsenic retention under conditions commonly found within aquifer redox fluctuating and transition zones where both arsenic and iron phases are present in oxidized forms, but manganese persists as reduced and soluble Mn(II). Analysis of column aqueous breakthrough data and characterization of solid-phase products using X-ray photoelectron (XPS) and absorption spectroscopies (XAS) show that the addition of bicarbonate increased manganese retention but decreased arsenic retention, while the presence of manganese and arsenic together increased both arsenic and manganese retention. In the presence of O2 arsenic remained oxidized as arsenate under all conditions measured; however, reduced Mn(II) was oxidized to an average Mn oxidation state of ∼3 in the absence of arsenate. The presence of arsenate partially inhibited Mn(II) oxidation likely by blocking ferrihydrite surfaces needed to catalyze Mn(II) oxidation by O2 and by stabilizing Mn(II) via ternary complex formation. These results highlight the interactions between reduced and oxidized contaminants that can contribute to the co-occurrence or physical separation of manganese and arsenic in groundwater systems under changing or stratified redox conditions.We here present a novel Ti4O7-based electrode loaded with amorphous Pd clusters that achieve efficient anodic destruction of perfluorooctanoic acid (PFOA), a persistent water pollutant with significant environmental and human health concerns. These amorphous Pd clusters were characterized by the disordered, noncrystalline arrangement of Pd single atoms in close proximity, in contrast to crystalline Pd nanoparticles that have been often employed to tailor the electronic properties of an electrode. We found that the Ti4O7 electrode loaded with amorphous Pd clusters significantly outperformed the Ti4O7 electrode loaded with crystalline Pd particles due to enhanced electron transfer through dominant Pd-O bonds. Combined with the efficient binding of PFOA and its degradation intermediates to the fluorinated electrode surface, this electrode was capable of mineralizing PFOA and releasing fluoride as F-. The reaction pathway was found to proceed without involving reactive oxygen species and therefore was not quenched by common anions in complex natural water systems such as chloride ions.Empirical evidence suggests that human occupants indoors, through their presence and activities, can influence the dynamics of semivolatile organic compounds (SVOCs). To better understand these dynamics, a transient multimedia human exposure model was developed (Activity-Based Indoor Chemical Assessment Model (ABICAM)). This model parametrizes mass-balance equations as functions of time-dependent human activities. As a case study, ABICAM simulated exposures of an archetypal adult and toddler over 24 h to diethyl phthalate (DEP), butyl benzyl phthalate (BBzP), and di-2-ethylhexyl phthalate (DEHP) that span a wide range of gas-particle partitioning tendencies. Under baseline (no activities beyond respiration), the toddler's time-average internal doses were three to four times higher than the adult's, due to differences in physical human attributes (e.g., inhalation rate). When time-dependent activities were considered, interindividual (e.g., adult vs toddler) variability was accentuated by up to a factor of 3 for BBzP.