Buggegreer8154

The excellent decontamination in meat preservation endowed C-Chx-F films with potential application in food packaging.In this study, different types of starch-based double emulsion (SDE) structures were developed to improve the bioavailability of astaxanthin (AST). Droplet size, microstructure, zeta potential of the AST-loaded SDEs were measured during in vitro digestion model. Compared with the C-type SDEs prepared with high amylose starch (HAS), the AST-loaded SDEs prepared using native corn starch of 5 wt% (B-type structure) and 7 wt% (A-type structure) presented small mean droplet diameters (MA = 11.18 ± 0.40 μm and 8.23 ± 0.37 μm, respectively) and were more stable after simulated gastric digestion. Furthermore, the lipid digestion products (free fatty acids) were studied after simulated intestinal digestion. Interestingly, the bioaccessibility (57.54 ± 1.88%) of AST-loaded SDEs prepared by HAS was six times higher than that of digested unencapsulated AST. Thus, SDEs were found to be suitable carriers for liposoluble nutrient delivery and bioavailability in foods, beverages, and nutraceuticals.Fully green and renewable choline amino acid (choline glycine, [Cho][Gly]) ionic liquid (IL) was firstly explored and evaluated as a solvent for starch. By a thorough investigation of microstructure evolution of water-[Cho][Gly] (wIL) mixtures, its regulation mechanism on disaggregation behaviors of starch was revealed and illuminated. Compared with pure water, existed hydrated free ions in wIL-91 and wIL-73 restrict starch-water interactions to disaggregate of starch, thus hampering gelatinization of starch. While the gelatinization temperatures decreased at wIL-55 and wIL-46 mixtures with a result of homogeneous starch solutions. The tight and water-separated ion pairs existed at wIL-55 and wIL-46 mixtures allow adequate ions to interact with starch to facilitate the disaggregation of starch. At wIL-28 and wIL-010 mixtures, an exothermic dissolution of starch was observed at high temperatures as a result of predominant starch-ion interactions. These results provide the possibility of using [Cho][Gly] solvent to meet various application requirements of starch.Abundant and renewable cellulose is a potential candidate for petroleum-derived synthetic polymers. However, the efficient dissolution of this material is problematic because of the high cost, severe reaction condition (e.g., high temperature) and environmentally unfriendly (e.g., toxic reagents, and solvent recyclability). Herein, to realize the room temperature dissolution of cellulose with an inexpensive and eco-friendly solvent, we design a novel low-cost deep eutectic solvent that is composed of zinc chloride, water and phosphoric acid for the efficient dissolution of cellulose. This solvent is featured as having both the superior hydrogen bonding acidity and the hydrogen bonding basicity, and thus can act as a hydrogen bond molecular scissors to cleave the hydrogen bonds within cellulose. BTK inhibitor In this process, microcrystalline cellulose can be easily dissolved in the solvent at room temperature with a dissolution ratio up to 15 wt%. The dissolved cellulose can also be recovered without any derivatization. The universality, recyclability and pilot production of dissolving cellulose using this solvent are also demonstrated. This work provides a new strategy for the design of novel deep eutectic solvent capable of disrupting the hydrogen bonds of cellulose under mild conditions.Chitosan is a biopolymer that is natural, biodegradable, and relatively low price. Chitosan has been attracting interest as a matrix of nanocomposites due to new properties for various applications. This study presents a comprehensive overview of common and recent advances using chitosan as a nanocomposite matrix. The focus is to present alternative processes to produce embedded or coated nanoparticles, and the shaping techniques that have been employed (3D printing, electrospinning), as well as the nanocomposites emerging applications in medicine, tissue engineering, wastewater treatment, corrosion inhibition, among others. There are several reviews about single chitosan material and derivatives for diverse applications. However, there is not a study that focuses on chitosan as a nanocomposite matrix, explaining the possibility of nanomaterial additions, the interaction of the attached species, and the applications possibility following the techniques to combine chitosan with nanostructures. Finally, future directions are presented for expanding the applications of chitosan nanocomposites.In recent years, nanocellulose-based materials have been increasingly applied as a lot of biosorbents for the treatment of water pollutants due to their large specific surface area, easy modification, environmental friendliness, and reproducibility. In this review, surface modification of nanocellulose-based adsorbents with various effective adsorption groups is described, as well as polymer grafting and hybrid composite fabrication. The adsorption mechanisms involved in the adsorption process of pollutants by adsorbents are further analysed and summarized. The regeneration methods of nanocellulose adsorbents with different adsorption mechanisms are also demonstrated. In addition, this paper also briefly describes the forms of nanocellulose-based adsorbents with large-scale application including membranes, gels, flocculants and magnetic composites.Plastic pollution has steadily become a global issue due to its ubiquity and degradation into micro and nanoparticles. Herein, we report the construction of surface-enhanced Raman scattering (SERS)-active array substrates with regenerated cellulose (RC) and plasmonic nanoparticles (AuNRs and AgNWs) via a simple vacuum-assisted filtration method using a silicon mask for rapid nanoplastic detection. The AgNWs/RC film exhibited a SERS intensity of crystal violet approximately six times higher than that of the AuNRs/RC film with a high enhancement factor of 1.8 × 107. Moreover, the AgNWs/RC film exhibits a better SERS activity for polystyrene nanoplastic detection than the AuNRs/RC film because the dense AgNW network structures are well suited for nanoplastic detection. The AgNWs/RC film can detect PS nanoplastics down to 0.1 mg/mL with a good reproducibility of the SERS signal. The low-cost, flexible, and highly sensitive AgNWs/RC films could provide an efficient and rapid SERS-based method for nanoplastic detection.The selection of sacrificial support materials is important in the fabrication of complex freeform structures. In this study, a dual droplet-based, freeform 3D printing method for pseudoplastic alginate biomaterial inks was developed using Bingham plastic cellulose nanocrystals (CNCs) as support nanomaterials. CNCs-CaCl2 mixture compositions and alginate concentrations were varied to enhance printability with rheological properties of shape fidelity and structural stability. The mixtures supported the shape of alginate and allowed CaCl2 diffusion-based cross-linking during 3D printing. The hydrogels showed rheological and physicochemical properties similar to those of pure alginate hydrogel, as CNCs were removed during post-printing processing. BSA-loaded multi-layered spheres, freeform 3D-printed for oral protein drug delivery, protected BSA in the gastric environment and provided controlled and sustained release of BSA into the intestinal environment as layer width and alginate concentration increased. This method can facilitate freeform 3D printing of diverse pseudoplastic biomaterial inks for biomedical applications.The properties of chiral nematic and iridescent cellulose nanocrystal films with different monovalent cations (CNC-X) obtained through evaporation-induced self-assembly (EISA) can be modified by a variety of external stimuli. Here, we study the transformations of their optical and structural properties when the films are thermally annealed at 200 °C and 240 °C for up to 2 days. The chiral nematic structure of the most thermally stable films is not destroyed even after extensive heating due to the thermochemical stability of the cellulose backbone and the presence of surface alkali counterions, which suppress catalysis of early stage degradation. Despite the resilience of the cholesteric structure and the overall integrity of heated CNC-X films, thermal annealing is often accompanied by reduction of iridescence, birefringence, and transparency, as well as formation of degradation products. The versatility, sustainability, and stability of CNC-X films highlight their potential as temperature indicators and photonic devices.Sustainable industry practices and circular economy concepts encourage the transformation of production waste into by-products. Saccharomyces cerevisiae is widely used in fermentation industry worldwide, generating large amounts of spent yeast which is mainly directed to animal feed or discarded as waste. Instead of becoming and environmental problem, spent yeast can be directed to the extraction of valuable compounds such as mannans and mannan oligosaccharides (MOS). This review presents a compilation of the studies up to date regarding the different chemical, enzymatic, mechanical or physical processes addressed for mannans extraction and MOS production. Additionally, the existing studies on the chemical modification of mannans aimed to improve specific characteristics are also discussed. Finally, the more relevant bioactivities and potential applications of mannans, MOS and mannose are presented, together with products on the market containing these compounds.Practicability of advanced and innovative techniques facilitates the high yield of cellulose extraction within a short period. The research aimed at the extraction of naturally abundant cellulose from Acer platanoides by "Nitrogen protected microwave assisted extraction (NPMAE)". The NPMAE uses microwaves for heating the sample and helps in fast extraction of cellulose in the presence of nitrogen atmosphere. Cellulose extraction was intensified by bleaching treatment in closed multimode NPMAE system at 100 W and 120 °C for 15 min. Experiment's result found that Acer platanoides fiber contains 70% cellulose content and diffferent analysis were studied for all chemically pre-treated fibers and found variations in results after each chemical treatment. The SEM results of bleached fibers show the rough surface due to the removal of lignin and hemicellulose. XRD pattern and FTIR analysis are in the favor of cellulose extraction and results show the presence of type I cellulose with 65% crystallinity index whileTGA and dTGA results explain that cellulose of Acer platanoides bleached fibers (APBF) is more thermally stable below 370 °C than other pre-treated fibers.Nowadays, cancer is one of the most prominent issues related to human health since it causes more than one-tenth of death cases throughout the world. On the other hand, routine therapeutic approaches in cancer suppression such as radiation therapy, chemotherapy, surgery, etc. due to their undesirable therapeutic outputs, including low efficiency in cancer inhibition, non-targeted drug delivery, nonselective distribution, and enormous side effects, have been indicated inefficient potency in cancer therapy or at least its growth inhibition. As a result, the development of novel and practical therapeutic methods such as nanoparticle-based drug delivery systems can be outstandingly beneficial in cancer suppression. Among various nanoparticles used in the delivery of bioactive to the tumor site, chitosan (CS) nanoparticles have received high attention. CS, poly [β-(1-4)-linked-2-amino-2-deoxy-d-glucose], is a natural linear amino polysaccharide derived from chitin which is made of irregularly distributed d-glucosamine and N-acetyl-d-glucosamine units.