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The large quantities of non-degradable single use plastics, production and disposal, in addition to increasing amounts of municipal and industrial wastewaters are among the major global issues known today. Biodegradable plastics from biopolymers such as Poly-β-hydroxybutyrates (PHB) produced by microorganisms are potential substitutes for non-degradable petroleum-based plastics. This paper reviews the current status of wastewater-cultivated microbes utilized in PHB production, including the various types of wastewaters suitable for either pure or mixed culture PHB production. PHB-producing strains that have the potential for commercialization are also highlighted with proposed selection criteria for choosing the appropriate PHB microbe for optimization of processes. The biosynthetic pathways involved in producing microbial PHB are also discussed to highlight the advancements in genetic engineering techniques. Additionally, the paper outlines the factors influencing PHB production while exploring other metabolic pathways and metabolites simultaneously produced along with PHB in a bio-refinery context. Furthermore, the paper explores the effects of extraction methods on PHB yield and quality to ultimately facilitate the commercial production of biodegradable plastics. This review uniquely discusses the developments in research on microbial biopolymers, specifically PHB and also gives an overview of current commercial PHB companies making strides in cutting down plastic pollution and greenhouse gases.Dam operations considerably influence water temperature regimes in rivers, which affects fish spawning activities. Previous studies have focused on the effects of critical temperature (CT) alterations during the spawning period, and largely ignored the effects of accumulated temperature (AT) alterations on gonadal development. Successful spawning relies on the simultaneous achievement of the two thermal requirements at appropriate times. River damming may cause a mismatch between the times of achieving CT and AT thresholds, and in turn influence fish reproduction. In the present study, spawning events of Coreius heterodon (C. heterodon) from 2009 to 2015 in the upper reaches of the Yangtze River, which are under the influence of cascade dams, were analysed based on the times of achievement of CT and AT thresholds. The CT and AT thresholds for C. heterodon spawning were 18.4 °C and 1324.9 °C·d, respectively. Under pre-impoundment conditions, the time of achievement of the AT threshold was 23 d on average later than that under post-impoundment conditions; however, the time of achievement of the CT threshold was similar under both conditions. The time of achievement of the AT threshold was 10 d earlier than that of achievement of the CT threshold in post-impoundment conditions. Earlier achievement of AT thresholds was followed by reduced spawning. The alteration of temperature rhythm caused by reservoir operations could be the major factor decreasing spawning abundance after river damming. The results of the present study could facilitate sustainable reservoir operations with regards to water temperature management, and thereby improve the conservation of fish resources.Wetland biofilms were exposed to the herbicide glyphosate via in situ field exposures and controlled microcosm experiments to measure bioconcentration and metabolism of glyphosate by biofilm organisms. Concentrations of glyphosate in biofilms were two to four orders of magnitude higher than the surrounding water, bioconcentration factors averaged 835 and 199 L·kg-1 in field- and lab-exposed biofilms, respectively. Glyphosate in water where it had been detected in biofilms at field-exposed sites ranged from below detection ( less then 1 μg·L-1) up to 130 μg·L-1. Bioconcentration of glyphosate in biofilms was inversely proportional to concentrations in the surrounding water, and the retention kinetics were similar to both adsorption and enzymatic models. Microorganisms present in both the water and biofilms metabolized glyphosate to its primary breakdown product aminomethyl phosphonic acid (AMPA), with increased rates of breakdown in and around the biofilms. Photosynthetic efficiency of the algae within the biofilms was not affected by 24 h controlled glyphosate exposures. Our results demonstrate the role of biofilms in improving wetland water quality by removing contaminants like glyphosate, but also as a potential exposure route to higher trophic levels via consumption. Due to bioconcentration of pesticides, exposure risk to organisms consuming or living in biofilms may be much higher than indicated by concentrations in ambient water samples.In the present study, the photoinduced degradation of the antidepressant drug sertraline under artificial solar radiation was examined. Photolysis was studied under different experimental conditions to explore its photolytic fate in the aqueous environment. https://www.selleckchem.com/products/donafenib-sorafenib-d3.html Photolytic degradation kinetics were carried out in ultrapure water, wastewater effluent, as well as in the presence of dissolved organic matter (humic acids), bicarbonate and nitrate ions which enabled their assessment on sertraline photo-transformation. The reaction of sertraline with photoactive compounds accelerated sertraline transformation in comparison with direct photolysis. Moreover, TiO2-mediated photocatalytic degradation of sertraline was investigated, and focus was placed on the identification of by-products. As expected, photocatalysis was extremely effective for sertraline degradation. Photocatalytic degradation proceeded through the formation of forty-four transformation products identified by HPLC-HRMS and after 240 min of irradiation total mineralization was achieved. Microtox bioassay (Vibrio fischeri) was employed to assess the ecotoxicity of the photocatalysis-treated solutions and results have indicated that sertraline photo-transformation proceeds through the formation of toxic compounds.Conventional activated sludge (CAS)-based wastewater treatment processes have the potential to emit high concentrations of nitrous oxide (N2O) during nitrification and denitrification, which can significantly impact the environmental performance and carbon footprint of wastewater treatment operations. While N2O emissions from CAS have been extensively studied, there is little knowledge of N2O emissions from aerobic granular sludge (AGS) which is now an increasingly popular secondary treatment alternative. The N2O emissions performance of AGS needs to be investigated to ensure that the positive benefits of AGS, such as increased capacity and stable nutrient removal, are not offset by higher emissions. This study quantified N2O emissions from a pilot-scale AGS reactor operated under a range of organic loading rates. A second CAS pilot plant was operated in parallel and under identical loading rates to allow for side-by-side comparison of N2O emissions from floc-based activated sludge. Under low loadings of less then 0.