Boswellxu7196

0 in UV/PMS process. Humic acid and bicarbonate obviously suppress the photodegradation of ROX. In addition, arsenic in ROX is mainly converted to As(V) in the three UV-based AOPs. Overall, this study provides essential information for the degradation of ROX via the traditional UV-based AOPs.The abundant iron rust of no value generated from industrial scraps presents environmental problem and burden. Chemical etching and related methods deployed to convert rust into α-Fe2O3 nanoparticles, however, have serious shortcomings namely higher chemical consumption and generation of secondary pollution. In an unprecedented illustration, herein the intercalation of ammonium bicarbonate (ABC) as a gaseous bubble template into bulky iron rust is described; formation of ammonium iron carbonate hydroxide hydrate and the reduction of particle size using a simple ball milling method followed by calcination is accomplished. The salient features of ABC, optimization of ratios (rust ABC), and the ideal calcination temperature were optimized for attaining desirable properties of meso-α-Fe2O3 NPs. The electrode obtained at 500 °C delivered a superior reversible capacity of 1,055 mAh g-1 at 1 A g-1 over 100 cycles, which is comparable to the best performance reported for meso-α-Fe2O3 NPs. The superior electrochemical performance is ascribed to the porous nature of meso-α-Fe2O3 NPs maximizing the surface area, ensuring good charge transfer kinetics and enhanced pseudocapacitive contribution. Thus, we believe that the high-energy ball milling (HEBM) process represents a novel route for the scalable recycling of iron rust scraps for promoting the sustainable production of lithium-ion batteries.In this study, the modified gangue (GE) was prepared by calcination at lower temperatures using potassium hydroxide (KOH) as the activating agent. The field emission scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), Fourier transform infrared spectroscopy (FTIR), and X-ray fluorescence (XRF) methods were employed to analyze the physicochemical characteristics of GE before and after the modification. Besides, the GE and commercial zeolite (ZE) were compared in the remediation of Cd-contaminated soil in field experiments. The results showed that both the GE and ZE had positive effects on the stabilization of Cd, decreasing the available Cd by 21.2-33.9% and 22.1-28.2%, respectively, while no significant difference was observed between the two amendments, indicating that the modification of GE was successful. Moreover, the application of GE decreased the Cd mobilization and uptake in lettuce shoot and root by 54.9-61.5% and 9.3-13.2%, respectively, and at the same time, the bio-available Cd decreased by 20.9-34.5%. Moreover, with the addition of GE, activities of urease and alkaline phosphatase increased in soil, while the peroxidase and superoxide dismutase activities were notably reduced in plants. Therefore, GE could be used as an effective amendment for the alleviation of Cd accumulation and toxicity, and thereby improve food safety.Researchers have been committed to reducing the hazardous pollutants by developing efficient catalysts while ignoring the pollution caused by the use of toxic surface capping agents, reductants and/or organic solvents in the catalyst preparation process. To alleviate such problems, we here report a novel one-step oxygenated functional group-driven electroless deposition strategy to synthesize clean and uniformly distributed Pd nanoparticles (NPs) using porous carbon nanosheets (PCN) as both substrates and reducing agents. It is observed that the oxygenated functional groups enriched PCN possesses a low work function and allows the spontaneous reduction of PdCl42- ions to Pd NPs deposited on the PCN support (Pd/PCN). The particle size of Pd NPs can be flexibly modulated by simply controlling the immersing time and thereby their maximum catalytic performances can be achieved. Specifically, the optimal Pd/PCN-08 with a Pd loading of 3.0 wt% shows an excellent activity with a turnover frequency of 0.38 min-1 for electrocatalytic hydrodechlorination (ECH) of 4-chlorophenol (4-CP), superior to the previously reported materials. The stability of Pd/PCN-08 for 4-CP ECH is impressive in repetitive cycles. This work proposes a facile and efficient strategy to synthesize high-performance catalysts for detoxifying the hazardous organic pollutants.Soil washing process enhanced by surfactants is a promising technique in removing organic pollutants from soil. In this work, a simultaneous sorption and biodegradation technique was used to remove 16 PAHs from a soil washing solution (SWS) obtained by rinsing a heavily contaminated soil from a coking plant with Triton X-100 (TX-100). This was done by immobilizing a pyrene-degrading bacterial strain in polyvinyl alcohol-sodium alginate (PVA-SA) hydrogel beads. Removal performance of free bacteria, blank PVA-SA beads and beads with immobilized degrading bacteria at a low, medium and high initial concentration was evaluated. The recycling and removal performance of the used beads were also examined. Our findings showed that hydrogel beads with immobilized bacteria at a medium concentration can remove around 77% ∑16PAHs from SWS in 96 h. The beads can be recycled and reused to treat a new SWS; 32-55% ∑16PAHs was removed in 24 h. The bead provided protection for bacteria against the co-existing substances such as TX-100. The bacteria-immobilized beads are more efficient and sustainable than free bacteria and blank beads due to simultaneous sorption and biodegradation processes, thus providing a solid reference for possible industrial application of bacteria immobilization technique to deal with SWSs with complex composition.In recent years, sodium p-perfluorous nonenoxybenzene sulfonate (OBS) has emerged as a substitute for PFOS with large demand and application in the Chinese market. However, little is known about potential developmental effects of OBS. In this study, zebrafish embryos were acutely exposed to different concentrations of OBS and the positive control PFOS for a comparative developmental toxicity assessment. OBS caused hatching delays, body axis curvature, neurobehavioral inhibition and abnormal cardiovascular development. These organismal effects were accompanied by change of development related genes expression profile, in which some cases were similar to PFOS. Overall, the toxic effects induced by OBS were generally milder than that of PFOS. Further investigation suggested that both OBS and PFOS disrupted ciliogenesis, evidenced by the ciliary immunostaining, changes in gene expression of kinesin family, dynein arm family and tubulin family members, as well as downregulation of the abundance of motor proteins including KIF3C, DYNC1H1 and DYNC1LI1. The influence of PFOS was stronger than that of OBS on ciliary genes and proteins. Molecular docking analysis revealed that both OBS and PFOS fitted into the motor proteins tightly, but binding affinity between OBS and motor proteins was lower than PFOS. Collectively, OBS and PFOS may act on ciliary motor proteins to interfere with ciliogenesis, leading to ciliary dysfunction and providing a novel probable action mode linked to developmental toxicity. This raises concerns regarding the health risks of the novel PFOS alternative OBS.Previous observations from in-situ biological treatments in the subsurface of a perchlorate-contaminated site revealed multiple reduction processes occurring parallel to perchlorate degradation. Iron reduction was accelerated and correlated with a decline in the efficiency of the in-situ perchlorate reduction. In the current study, we examined the influence of iron forms on perchlorate reduction. A series of kinetic laboratory experiments were conducted, using an indigenous mixed perchlorate-reducing culture, enriched from the polluted soil that was undergoing bioremediation. The results show that ferrous iron was a non-competitive inhibitor with a 41% decrease in µmax for perchlorate reduction. Moreover, chlorate was accumulated in all samples treated with ferrous iron, indicating a disruption to the chlorate reduction step. Ferric iron, however, had less impact on perchlorate degradation with non-competitive inhibition reaching a 23% decrease in µmax. Scanning electron microscopy (SEM) revealed that the presence of ferrous iron in the perchlorate degradation enrichment culture initiated cell encrustation. We propose that during perchlorate reduction and the emission of oxygen from chlorite dismutation, the chemical oxidation of ferrous iron occurred near the bacteria's surface where the enzyme is located, forming an oxidized iron crust layer that can directly affect the perchlorate reduction enzymatic system.Knowledge of the behavior of technologically enhanced naturally occurring radioactive materials derived through the decay of U and its daughter products, and their subsequent fractionation, mobilization and retention, is essential to develop effective mitigation strategies and long-term radiological risk prediction. In the present study, multiple state-of-the-art, spatially resolved micro-analytical characterization techniques were combined to systematically track the liberation and migration of radionuclides (RN) from U-bearing phases in an Olympic Dam Cu flotation concentrate following sulfuric-acid-leach processing. The results highlighted the progressive dissolution of U-bearing minerals (mainly uraninite) leading to the release, disequilibrium and ultimately upgrade of daughter RN from the parent U. This occurred in conjunction with primary Cu-Fe-sulfide minerals undergoing coupled-dissolution reprecipitation to the porous secondary Cu-mineral, covellite. The budget of RN remaining in the leached concentive blueprint for understanding of the mobility and retention of U and its daughter products in complex anthropogenic and natural processes in the mining and energy industries.Conventional flue gas nitrogen oxides (NOx) abatement technologies commonly convert NOx into harmless compounds, while less effort has been made to recycle NO2 as a profitable chemical in many industries. Towards this end, adsorption is a promising technology for which an advanced technique for NO2 desorption and efficient sorbent regeneration provides the key step for success in practical applications. This work reports a novel cyclic adsorption process for NOx removal with recycling of NO2 from iron-ore sintering flue gas of a steel plant. This process using self-prepared and validated pelletized Na-ZSM-5 zeolites as low-cost sorbents involves NOx catalytic adsorption and reversible desorption using multiple hot gas circulations (GC) within the enclosed fixed bed followed by scavenging and purge at mild conditions. In comparison to conventional cyclic processes, greater amount of recyclable NO2 was obtained, rendering the NOx recovery of >92% and the mean NO2 concentration of >2% significantly enriched from original 20 ppm in feed gas. A robust adsorption-desorption performance with appreciable NOx working capacity was achieved for up to 16 cycles. CC-90001 concentration The key role of the segmentation of GC in boosting NOx regenerability was addressed, providing an economical three-tower strategy for continuous NO2 production for practical use.