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The risk of heavy metal contamination of infiltrated water and underground soil on a permeable brick paving system was investigated. The paving system was constructed as a frame structure base on top of a 1.0-m-thick clay layer with permeable ceramic brick at the surface. The concentrations of heavy metals (Zn, Cu, and Pb) in infiltrated water and soil at different underground depths under the paving system were measured. Speciation rates of Zn, Cu, and Pb at different clay depths were further determined to ascertain the probability of downward migration of the unstable forms. The results showed reduced risk of infiltrated water pollution by heavy metals due to underground soil acting as an effective trap. click here However, topsoil was more susceptible to heavy metal pollution, with the different pollution soil depths of Cu, Zn, and Pb mainly attributed to the different binding abilities between the heavy metals and soil. Soil Cu and Zn remained relatively stable, whereas there was a potentially high risk of Pb migration. The study found that topsoil could accumulate non-degradable heavy metals to unacceptable levels over a period of 30 years and that topsoil should therefore be replaced after 30 years to reduce the risk of soil pollution. This study fills a knowledge gap by both determining the risks of heavy metal pollution to underground soil and infiltrated water and exploring effective ways to reduce heavy metal pollution.The physiological and biochemical responses of Sorghum bicolor (L.) Moench. to cadmium (Cd) (30 mg kg-1) and oil sludge (OS) (16 g kg-1) present in soil both separately and as a mixture were studied in pot experiments. The addition of oil sludge as a co-contaminant decreased Cd entry into the plant by almost 80% and simultaneously decreased the stimulation of superoxide dismutase (SOD) and peroxidase. The decrease in glutathione reductase (GR) activity and the increase in glutathione-S-transferase (GST) activity under the influence of oil sludge indicated that its components were detoxified by conjugation with glutathione. Cd additionally activated the antioxidant and detoxifying potential of the plant enzymatic response to stress. This helped to enhance the degradation rate of oil sludge in the rhizosphere, in which the participation of the root-released enzymes in the degradation could be possible. Cd increased the extent of soil clean-up from oil sludge, mainly owing to the elimination of paraffins, naphthenes, and mono- and bicyclic aromatic hydrocarbons. The mutual influence of the pollutants on the biochemical responses of sorghum and on soil clean-up was evaluated. The results are important for understanding the antistress and detoxification responses of the remediating plant to combined environmental pollution.The main objective of this study is to examine the impacts of globalization, financial development, government expenditures, and institutional quality on CO2 emissions, incorporating energy consumption, and GDP per capita in the Environmental Kuznets Curve (EKC) model for 47 Emerging Market and Developing Economies (EMDEs) between 1990 and 2014. Owing to the presence of cross-sectional dependence and slope heterogeneity in the panel data, CADF and CIPS unit root tests are employed to validate the stationarity of the variables. Westerlund (Oxf Bull Econ Stat 69709-748, 2007) and Banerjee and Carrion-i-Silvestre (J Time Ser Anal 38610-636, 2017) cointegration tests denote the occurrence of cointegration among the variables. We employed CCEMG, AMG, and DCCE estimators to estimate heterogeneous parameters. The findings demonstrate that globalization, financial development, and energy consumption increase CO2 emissions. Besides, the EKC hypothesis is affirmed in EMDEs. The accrual of governments' financial and governance activities also boosts carbon dioxide emissions. Moreover, the analysis of Dumitrescu and Hurlin causality provides evidences for the feedbacks among the variables and CO2 emissions. From the aforementioned results, there exists the trade-off effect between economic growth and environmental quality in EMDE countries. Finally, the empirical findings of this study indicate profound implications for policy makers, which recommend governments to consider the role of finance and governance in order to ensure that energy consumption, financial development, and sustainable economic growth are in harmony with the environment in the globalization era.A large number of defective mulberries are discarded each year because mulberries are easy to break. The red pigments from defective mulberries are recognized as the sustainable sources of anthocyanins extracted from nature. Cyanidin-3-O-rutinoside and cyanidin-3-O-glucoside are the main components of mulberry red pigments, accounting for 50% and 40% of the total, respectively. Cyanidin-3-O-glucoside exhibits anticancer, hypoglycemic, and liver and visceral protection properties. Cyanidin-3-O-glucoside can be prepared by enzymatically hydrolyzing the rhamnosidase bond of cyanidin-3-O-rutinoside. To obtain mulberry red pigment with a high purity of cyanidin-3-O-glucoside, immobilized α-L-rhamnosidase was added to the aqueous two-phase system to construct a liquid-liquid-solid three-phase enzyme catalytic system. After optimization, the three-phase system was composed of 27.12% (w/w) ethanol, 18.10% (w/w) ammonium sulfate, 15% (w/w) mulberry juice, 4.24% (w/w) immobilized α-L-rhamnosidase, and 35.54% (w/w) pure water. The three-phase system was employed to enrich and purify cyanidin-3-O-glucoside at pH 5 and 45 °C for 1 h. The purity of cyanidin-3-O-glucoside was increased from 40 to 82.42% with cyanidin-3-O-rutinoside conversion of 60.68%. The immobilized α-L-rhamnosidase could be reused seven times, maintaining a relative activity of over 50%. Overall, the developed system provided an efficient and simple approach for high purity mulberry red pigment production and recycling in the field of sustainable agriculture. Graphical abstract.Recently, the research on conversion of biodiesel by-products to high value-added products has received much attention, due to the adverse effects of large accumulations of biodiesel by-products caused by the rapid increase in biodiesel production. Herein, this study investigated the utilization of by-products crude glycerol (CG-1 and CG-2) from two different industrial methods of biodiesel production and the favorable fermentation conditions for the high yield of β-farnesene by an engineered Escherichia coli F4, which harbored an optimized mevalonate pathway. Through analyzing by-products' components and fermentation performance, we found that CG-2 did not contain harmful impurities such as methanol and black solid impurities, and the β-farnesene production was up to 2.7 g/L from CG-2, which was similar to that from pure glycerol (2.5 g/L) and higher than that (2.21 g/L) from CG-1. Therefore, CG-2 was more suitable for β-farnesene production than CG-1, which might provide a reference for choosing a more suitable method on practical biodiesel production.