Bendersteensen5446

Furthermore, Cu and Zn formed clusters with Cu-O and Zn-O interatomic distances of 1.97 and 2.21 Å, (coordination numbers 1.0 and 5.6), respectively. In non-contaminated oysters, the less abundant Cu and Zn existed mainly as copper(I) sulfide (Cu2S) and zinc sulfide (ZnS) forming clusters with Cu-S and Zn-S (thiolates) bond distances of 2.09 and 1.23 Å (coordination numbers of 4.6 and 2.4). These results provide further understanding on the chemical speciation of Cu and Zn in contaminated and non-contaminated oyster soft tissues as well as the bioaccumulation of trace metals in the oyster soft tissues.The urea oxidation reaction (UOR) and nitrophenol reduction are safe and key limiting reactions for sustainable energy conversion and storage. Urea and nitrophenol are abundant in industrial and agricultural wastes, human wastewater, and in the environment. Catalytic oxidative and reductive removal is the most effective process to remove urea and 4-nitrophenol from the environment, necessary to protect human health. 2D carbon-supported, cobalt nanoparticle-based materials are emerging catalysts for nitrophenol reduction and as an anode material for the UOR. In this work, cobalt modified on a porous organic polymer (CoPOP) was synthesized and carbonized at 400 and 600 °C. The formation of CoPOP was confirmed by FT-IR spectroscopy, the 2D graphitic layer and amorphous carbon with cobalt metal by TEM, SEM, and PXRD, and the elemental composition by TEM mapping, EDX, and XPS. The catalytic activity for the 4-nitrophenol reduction was studied and the related electrocatalytic UOR was scientifically evaluated. The catalytic activity toward the reduction of 4-NP to 4-AP was tested with the addition of NaBH4; CoPOP-3 exhibited enhanced activity at a rate of 0.069 min-1. Furthermore, LSV investigated the catalytic activity of materials toward UOR, producing hydrogen gas, the products of which were analyzed via gas chromatography. Among the electrocatalysts studied, CoPOP-2 exhibited a lower onset potential, and the Tafel slope was 1.34 V and 80 mV dec-1. This study demonstrates that cobalt metal-doped porous organic polymers can be used as efficient catalysts to remove urea and nitrophenol from wastewater.Antimony is a priority environmental contaminant. Increasing attention is being paid to the behaviors and mobilities of the various Sb species in the environment. Sb speciation in the environment and the mobilities of Sb species at mining sites have been studied well, but Sb speciation and mobility in shallow lakes requires further study. Here, we studied Sb behavior in sediment of a shallow lake in the plain rivers network in Taihu Basin that suffers continual Sb inputs from textile plants. The diffusive gradients in thin films techniques (DGT) made of zirconium oxide based binding resin gel (ZrO-Chelex), agarose diffusive gel and polyvinylidene fluoride filter were deployed in water and sediment to obtain a high-resolution record in situ. The results indicated that (1) pollutants released by textile plants caused relatively high Sb(Ⅲ), Sb(Ⅴ) and organoantimony concentrations in the eutrophic shallow lake, (2) Sb was seldomly mobile in the oxic layer where Sb(Ⅲ) was sorbed on Fe(Ⅲ) oxides and gradually formed Fe-Sb complexes in the sediment, but in the anoxic environment (oxidation-reduction potential 366 - -344 mv) Sb(V), Fe(Ⅱ) and P (V) were simultaneously released to resupply the porewater, (3) the release of Sb from solid phase is decided by the redox condition, and the rate of release is dependent on the labile Sb content of the sediment. The mobility of Sb should be given sufficient attention when the potential ecological risk of metal(loid)s in shallow lakes and wetlands sediment are evaluated.Sustainable agricultural, food-related strategies and geographic traceability require understanding of the plant physiological response to stress potentially generated by contaminated soils. Here, we have investigated the effect of contaminated substrate on growth of Vitis vinifera L. plants analysing the distribution of full Rare Earth Elements (REE) spectra in different parts of the plant. Experiments were carried out using pristine plants growing in a handmade substrate (blank experiment) and in REE artificially-enriched soil (spiked experiment). Our results show that both plant mass and REE amount in leaves are not influenced by the substrate enrichment while roots are by one-order of magnitude enriched for three-orders of magnitude enhancement of the soil substrate. This clearly indicates that soil contamination does not significantly influence the REE amount in the aerial parts. However, the spectra of REE normalized changes when the soil is enriched. We found that Light-REE (from La to Gd) are by more than one order of magnitude enriched compared to Heavy-REE (from Tb to Lu plus Y) in spiked experiment showing the specific response of Vitis vinifera L. to the stress generated by soil contamination. We propose that REE distribution spectra is a marker of Vitis vinifera L. substrate of growth and providing a new tool for tracing the geographical origin of agri-food products.Environmental biotechnology is the use of biotechnology to develop and regulate biological systems for the remediation of environmental contamination. Nature has gifted ample material for remediation of its resources, among which chitosan is one of the most important and largely available biomaterial globally. Chitosan is a biopolymer obtained by deacetylation of chitin extracted from marine waste and its applications from drug delivery to food additives are broadly available. Chitosan exhibit several properties such as availability, low cost, high biocompatibility, and biodegradability. These properties make it biologically and chemically acceptable for use in various fields. Due to some limitations of pure chitosan, there has been a growing interest in modifying the chitosan in order to improve the original properties and widen the applications of pure phase chitosan. Various modified forms of chitosan and their associated applications are reviewed here with emphasis on their use in environmental remediation. The demand of chitosan in the global industrial market is growing which is briefly explained in this paper. Chitosan is used for water purification since a long time and still progress is going on for making it more efficient in the removal process. It can be used as a flocculent and coagulant, as an adsorbent for removing the contaminants like heavy metals, dyes, pesticides, antibiotics, biological contaminants from wastewater. Soil remediation using chitosan material is explained in this review. Various other applications such as drug delivery, food additives, tissue engineering are thoroughly reviewed.In the present study, microplastics (MPs) and metal concentrations were studied in the widely consumed tilapia (Oreochromis niloticus) fishes (n = 15) collected from a metropolitan reservoir of the Atoyac River basin, Mexico. Nearly 139 fibers were extracted from the gastrointestinal tracts and assessed using optical microscopy to evaluate their physical characteristics. The colour distribution of the fibers was mainly black (40%), blue (19%), red and white (14%). Epalrestat SEM images represented the surface morphology, while the elemental composition of the fibers was studied using EDX spectra. Polymer characterization using μFTIR aided in confirming the fibers as plastics (polyamide, polyester, and synthetic cellulose) and non-plastics (natural cellulose). Henceforth, ∼33% of the fibers, provisionally thought to be plastics, were natural fibers. The total metal concentrations were higher in the liver (259.24 mg kg-1) than the muscle (122.56 mg kg-1) due to diverse metabolic functions in the hepatic tissues. Human health risk assessment in terms of Hazard Index (HI) presented Pb and Zn values above unity in both adults and children, prompting regulatory measures. Statistical tests between MPs and fish biometry did not present any substantial correlations. The present study also affirmed that the presence of MPs and metals in fishes of a highly contaminated region is not only governed by their bioavailabilities, but also on the physiological characteristics of the individual organism.Pineapple leaves were used as a natural fiber source to prepare various modified microcrystalline cellulose (MCC) samples as sorbents for H2S sorption. Pineapple leaf fibers were first extracted from pineapple leaves, followed by hydrolyzing to produce MCC before various modifications using primary amine (3-aminopropyltrimethoxysilane, APS), secondary amine (N-methyl-3-aminopropyltrimethoxysilane, MAPS), or tertiary amine (N,N-dimethyl-3-aminopropyltrimethoxysilane, DAPS). The characterization results proved that all the aminosilane groups were successfully grafted onto the MCC. In addition, the thermal stability and the porosity of the modified sorbents were enhanced relative to those of unmodified MCC. The H2S sorption studies of MCC modified with APS, MAPS, and DAPS at 0, 3, or 5%w/w showed that MCC-MAPS had better H2S sorption performance than MCC-APS and MCC-DAPS, respectively, when comparing the H2S sorption performance at the same loading level. The optimum H2S sorption performance of each aminosilane group was achieved from MCC-APS at 5%, MCC-MAPS at 3%, and MCC-DAPS at 5%. An additional study of H2S sorption of these three sorbents in the presence of CO2 showed that MCC-DAPS at 5% was the best sorbent for selective H2S removal. Our results indicated that MCC modified with the aminosilane groups, especially MAPS, were promising materials for H2S sorption, with potential application in gas separation.A natural consequence of everyday tissue metabolism is cell injury or stress. This injury activates a canonical immune-mediated inflammatory response in order to achieve tissue repair so that homeostasis is maintained. With aging there is increased tissue injury and therefore increasing demands placed on an immune system, which itself is aging (immunosenescence). Thus, the increased reparative demands are reflected by an increased inflammatory load both locally and systemically. Eventually, if the reparative demands are excessive, the aging immune system is overwhelmed and disease ensues. In the macula this age-related failure in repair gives rise to age-related macular degeneration (AMD). The hypothesis proposed herein is therefore, that AMD is due to age-related failure of tissue repair and the chronic inflammation associated with this failure ('inflammaging') is both a surrogate and biomarker of this reparative failure and not in itself the primary cause of disease. Such a hypothesis can be applied to all the diseases of aging and by extension suggests that effective therapies should be aimed at facilitating repair through immunotherapy, possibly and perhaps controversially, through the promotion of inflammation rather than the current approach of its inhibition (anti-inflammatory strategies), the latter which can ultimately only hinder the repair process and thereby lead to the persistence of disease.Hypoxia inducible factor-1 (HIF-1) is a transcriptional factor that regulates gene expressions in response to decreased oxygen levels in the tissue, or hypoxia. HIF-1 exerts protective effects against hypoxia by mediating mitochondrial metabolism and consequently reducing oxidative stress. Recently, increased levels of oxidative stress and abnormal energy metabolism in the brain have been suggested to play essential roles in the pathogenesis of depression. Given that HIF-1 activates creatine metabolism and increases phosphocreatine levels in the intestinal epithelial cells, we assume that HIF-1 may induce similar processes in the brain. Elevated phosphocreatine levels in the brain, as measured by magnetic resonance spectroscopy, were associated with better treatment response to the antidepressants in individuals with depression. In addition, oral creatine supplements, which led to increased phosphocreatine levels in the brain, also enhanced the effects of antidepressants in individuals with depression. As such, we hypothesized that increasing the HIF-1, which potentially facilitates creatine metabolism in the brain, might be a new therapeutic target in depression.