Bellgroth1708

2-8.2 torr at 298 K. The rate coefficient kHCl = (4.8 ± 0.4) × 10-11 cm3 molecule-1 s-1, is comparable to the only literature value kHCl = (4.6 ± 1.0) × 10-11 cm3 molecule-1 s-1 reported by Foreman et al.The suitability of ethylenediamine (en) as an alternative solvent to liquid ammonia in beryllium chemistry was evaluated. Therefore, BeF2, BeCl2, BeBr2, BeI2, [Be(NH3)4](N3)2, [Be(NH3)4](CN)2 and [Be(NH3)4](SCN)2 were reacted with ethylenediamine and analysed via NMR and IR spectroscopy. Additionally single crystal structures of [BeF2(en)]n, [Be(en)3]Cl2, [Be(en)3]Br2, [Be(en)2]I2·en, [Be(en)2](N3)2·en, [Be(en)2]4(SCN)7Cl and [Be3(OH)3(en)3][C2H9N2](SCN)4 were obtained. Cy7 DiC18 The anions were found to have a distinct influence on the solubility as well as on the species present in solution and the solid state, while ethylenediamine can act as mono- and bidentate ligand or as a crystal solvent.The short-range structures of LiF-ThF4, NaF-AnF4, KF-AnF4, and Cs-AnF4 (An = Th, U), were probed using in situ high temperature Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy. Signally, the EXAFS spectra of pure molten ThF4 and UF4 were measured for the first time. The data were interpreted with the aid of Molecular Dynamics (MD) and standard fitting of the EXAFS equation. As in related studies, a speciation distribution dominated by [AnFx]4-x (x = 7, 8, 9) coordination complexes was observed. The average coordination number was found to decrease with the increasing size of the alkali cation, and increase with AnF4 content. An average coordination number close to 6, which had not been detected before in melts of alkali actinide fluorides, was seen when CsF was used as solvent.A nitrogen replacement process that directly incorporates the 15N atom of glycine-15N into anilines was reported. The process involves a Csp2-N bond cleavage of anilines driven by dearomatization and a Csp3-N bond cleavage of glycine-15N driven by aromatization. A variety of 15N-labeled aromatic heterocycles can be prepared via this process.Metal-organic frameworks (MOFs), as a new class of proton conductors, have attracted much attention in the application of proton exchange membranes due to their precisely defined structure and tailorable functionality. However, for most of the MOF materials, their long-term stability is a huge barrier to practical application. Therefore, the structural stability of MOFs is an important prerequisite for the design and development of proton conductors with ultra-high conductivity. In this study, the stable UiO-66-NH2 is optimized as the precursor, and the modified material of DT-UiO-66 is designed and developed by introducing the 3,5-diamino-1,2,4-triazole molecule into the framework of UiO-66-NH2 through a post-synthesis strategy. Satisfactorily, DT-UiO-66 maintains the stability of the original skeleton. The alternating current impedance measurements indicate that a significantly improved proton conductivity of 4.47 × 10-3 S cm-1 is obtained at 100% relative humidity (RH) and 373 K for DT-UiO-66, which is attributed to the increasing number of proton sources and hopping sites. Moreover, DT-UIO-66 shows an outstanding stability under high temperature and high humidity conditions for at least 16 h, suggesting its potential application as a proton exchange membrane.Dehydrogenative cross-coupling (DCC) between pyridine and benzene proceeded selectively using a TiO2 photocatalyst under visible light irradiation at optimized concentrations of the substrates. Visible light induces ligand-to-metal charge transfer (LMCT) between pyridine and a TiO2 surface to give a pyridine radical cation, which produces a pyridyl radical by its deprotonation or oxidation of another pyridine molecule. The pyridyl radical attacks a benzene ring to form an sp2C-sp2C bond and a hydrogen atom is subsequently removed to complete DCC. Selective excitation of the pyridine LMCT complex in the presence of an excess amount of benzene would be the key for higher selectivity.A barbiturate-functionalized supramolecular monomer bearing an ester-linked biphenyl and azobenzene π-conjugated core affords wavy supramolecular polymers. The periodic inversion of curvature is due to the conformational rigidity of the monomer and repulsive interactions between rosettes. Photoisomerization of the azobenzene moiety increases the fragility of the main chain without deteriorating its periodic structure.Among various kinds of materials that have been investigated as electrocatalysts for the hydrogen evolution reaction (HER), oxygen evolution reaction (OER) and oxygen reduction reaction (ORR), metal-organic frameworks (MOFs) has emerged as a promising material for electrocatalyzing these vital processes owing to their structural merits that integrate advantages of both homogeneous and heterogeneous catalysts; however there is still big room for their improvement in terms of inferior activity and poor conductivity, as well as the ambiguity of real active sites. In this review, advanced strategies with the aim of solving the activity and conductivity problems are summarized as microstructure engineering and conductivity improvement, respectively. The structural evolution of some MOFs and their real active species has also been discussed. Finally, perspectives on the development of MOF materials for HER, OER and ORR electrocatalysis are provided.A novel emulsion-template synthesis approach was developed for the preparation of nickel oxide nanoflowers (NiO-NFs) composed of crossed mesoporous nanosheets. The interface assembly process was regulated by tuning the dosage of NH3·H2O, resulting in the tunability of thickness and size of mesoporous NiO nanosheets. The as-prepared NiO-NFs were characterized by field emission scanning electron microscopy, transmission electron microscopy, Brunauer-Emmett-Teller analysis, X-ray diffraction, and X-ray photoelectron spectroscopy (XPS). The results indicate that NiO-NFs have a mesopore size of about 9.5-15 nm and a crossed nanosheet thickness of about 12.4-50 nm. XPS results demonstrated that all NiO-NF samples consisted of Ni2+ and Ni3+. Electrochemical nitrogen reduction reaction (NRR) measurements revealed that NiO-NF-3.0 showed an optimal NRR performance of NH3 yield and faradaic efficiency (16.16 μg h-1 mg-1cat. and 9.17% at -0.4 V vs. RHE) in 0.1 M Na2SO4. Interestingly, NiO-NF-3.0 also displayed the highest Ni3+ content, which correlates with the order of electrochemical NRR performance.