Bartonbugge6363

In this study, the Songgang River (SR) was selected as a typical contaminated urban river in a highly urbanized city (Shenzhen) that is extensively polluted by heavy metals (HMs). Five representative sampling sites were selected from different urban functional areas along the SR, and the spatial and vertical distributions of HMs and the related environmental risk were investigated. In addition, the distribution variability, composition, and abundance of microbial communities, as well as the correlation between the abundance of the operational taxonomic units (OTUs) and the HM contents were analyzed. The spatial distribution of HMs in the sediment revealed wide variation among the different urban functional areas. Industrial and residential areas had higher HM contents, following the order of Cu > Zn > Ni > Cr > Pb. In addition, the vertical characterization (5-300 cm) of HM content showed a decreasing trend with depth, with a distinct layer around 120-180 cm that might have been caused by anthropogenic activity. An ecological risk assessment indicated that Cu, Ni, and Cr pose high potential risks in these industrial and residential areas (at the depth of 5-180 cm). Furthermore, microbial community analysis indicated that some HM-tolerant bacteria (e.g., Gallionella, Acidovorax, Arenimonas, Curvibacter, and Sideroxydans) were dominant in the 5-120 cm layer, corresponding to high HM contents. A canonical correspondence analysis and co-occurrence network further confirmed that there was a strong correlation among the urban functional areas, HM contents, and the abundance of microorganisms in the urban river sediment. The results of this study have the potential to provide a bio-augmentation strategy for the in-situ bioremediation of sediment contaminated by HMs.Sustainable intensive cropping systems have been implemented for three decades in suburban agricultural districts of Shanghai, China. These human-managed soils have been developed from paleosol or alluvial soils across different regions. However, little is known about the geographical distribution patterns of microbes and microbial community assembly in the sustainable intensive soils after decades of anthropogenic disturbances. Here, we investigated the impact of local geochemical properties and geographic distance on stochastic/deterministic microbial community assembly processes using high-throughput sequencing and phylogenetic null modeling analysis. Our results showed that soil pH was the most important environmental factor determining bacterial and fungal community structure. Importantly, only soil organic matter was positively correlated with fungal α-diversity, suggesting the efficient use of carbon substrates in sustainable agricultural systems, compensating for the lack of chemical fertilization andnge preferable for most soil microbes. These results unveil assembly mechanisms of soil microbial community after several decades of sustainable intensive management, and contribute to understand the role of microbes in ecosystems in establishing a functional equilibrium which may enable sustainability to be preserved.A series of experiments on the oxidative removal of NO from flue gas using a novel in situ Fenton (IF) system was performed in the presence of ultraviolet light (UV). The comparison tests revealed that the in situ Fenton system facilitated by UV (UV/IF) has a better oxidation ability of NO than that of the IF system due to the photochemical effect on the generation of oxidative species like (OH). Both of the aforementioned oxidation efficiencies were higher than that of the conventional Fenton system (CF) depending on the premix of Fe2+ and H2O2 solutions, which attribute to the improvement of (OH) yield and valid utilization with continuous addition of fresh reagents and UV radiation. In follow-up experiments, the effects of UV power, gas flow rate, reagent temperature, Fe2+/H2O2 molar ratio, initial pH, initial concentration of NO and SO2 and volume fraction O2 and CO2 on the oxidative removal of NO by UV/IF method were investigated respectively. Moreover, the results of kinetic analysis indicated that NO oxidation was confirmed to have a pseudo-first-order kinetics pattern. The rate constants decreased slightly with increasing liquid temperature, and then the apparent activation energy of NO oxidation reactions in the UV/IF system was calculated as -5.62 kJ/mol by the Arrhenius equation. Furthermore, the reaction mechanism and application prospects concerning NO oxidative removal by using the UV/IF system was speculated in brief. Finally, the computational fluid dynamics (CFD) simulations revealed that the improvement of axial and radial gas hold-up would enhance the gas-liquid contact and accelerate the oxidation reactions on the interface. In addition to reasonable control of process parameters, the optimization of reactor interior structure needs to be carried out via CFD simulation and experimental validation in future research, both are favourable to promote the NO oxidation efficiency and large-scale development of this technology.The aim of this study was a detailed chemical characterisation of the particles released during the preparation of popular Portuguese dishes. NX-2127 ic50 PM2.5 samples were collected from the exhaust stacks on the roofs of a university canteen, a charcoal-grilled chicken restaurant and a wood-oven roasted piglet restaurant. The speciation of organic compounds was carried out by gas chromatography-mass spectrometry. The canteen was responsible for the lowest emissions of PM2.5, while emissions from the roasted piglet restaurant were the highest. Naphthalene was quantified as the most abundant aromatic compound in particle emissions from the canteen, while phenanthrene, fluoranthene, pyrene and chrysene were the dominant polycyclic aromatic hydrocarbons in samples from the other establishments. Benzo[a]pyrene equivalent concentrations obtained for the charcoal-grilled chicken and piglet restaurant indicate a dangerous carcinogenic potential to human health. Cholesterol was the prevalent sterol. Its highest values were obtained in particles from the charcoal-grilled chicken restaurant (621 ± 233 μg g-1 PM2.5). Oleic and palmitoleic were the unsaturated fatty acids identified at highest concentrations (from trace levels to 34.4 and to 6.89 mg g-1 PM2.5, respectively). Resin acids, such as dehydroabietic and abietic, were detected in all samples from the wood-oven roasted piglet restaurant. Nicotinamide was the amide detected at highest amount in emissions from the university canteen during the preparation of stews (7.67 mg g-1 PM2.5). Levoglucosan and its isomers were identified in all samples from the roasted piglet restaurant, but only the first monosaccharide anhydride was present in emissions from the university canteen and the charcoal-grilled chicken restaurant. Additionally, emission rates were estimated for the most representative compounds, taking into account the specific activity of each restaurant.