Andreasenbernard2251

An improved Savitzky-Golay (S-G) filtering algorithm was developed to denoise the absorption spectroscopy of nitrogen oxide (NO2). A deep learning (DL) network was introduced to the traditional S-G filtering algorithm to adjust the window size and polynomial order in real time. The self-adjusting and follow-up actions of DL network can effectively solve the blindness of selecting the input filter parameters in digital signal processing. The developed adaptive S-G filter algorithm is compared with the multi-signal averaging filtering (MAF) algorithm to demonstrate its performance. The optimized S-G filtering algorithm is used to detect NO2 in a mid-quantum-cascade-laser (QCL) based gas sensor system. A sensitivity enhancement factor of 5 is obtained, indicating that the newly developed algorithm can generate a high-quality gas absorption spectrum for applications such as atmospheric environmental monitoring and exhaled breath detection.We report a robust technique to fabricate a cost-efficient Raman substrate which is composed of polyvinylpyrrolidone (PVP) coated gold nanoparticles layer on commercial aluminum foil. The layer of metal nanoparticles on the aluminum foil, i.e., the nanoparticle-on-mirror (NPoM) structure was fabricated by spraying nanoparticle colloidal solution directly on the foil. The detection limit (LOD) of NPoM substrate is investigated by performing the SERS for Rhodamine 6G (R6G) with the concentration ranging from mM to nM without any post treatment of the substrate. The findings show that the LOD of 1 nM and maximum intensity enhancement factor of ~ 24 is accomplished. Field enhancement owing to reflection from the metallic mirror is the reason behind the signal enhancement and it would be beneficial for routine clinical applications, trace chemical detection, and disease diagnostics.Mural paintings within the tomb of Setka, Qubbet el-Hawa, in Aswan, Upper Egypt, were investigated using a multi-disciplinary analytical approach (Stereomicroscopy, SEM-EXD and FT-IR spectroscopy). The walls of the tomb were hewn from fragile sandstone and covered by a clay plaster, overlaid by two layers of white gypsum plaster. SEM micrographs were indicative of the penetration of fungal mycelium within the pores of the gypsum plaster, forming white encrustations due to the re-precipitation of gypsum. SEM micrographs revealed that the calcification of the gypsum plaster had occurred due to its exposure to a high temperature. The EDX pattern for the white plaster gave the characteristic spectrum of gypsum, the blue pigment was Egyptian blue, the black pigment was magnetite, the white pigment was of gypsum (or anhydrite) and the yellow pigment was limonite. Finally, the FT-IR spectrum of the binder gave the characteristic features of gum Arabic.In this research, the simultaneous absorption of Salmeterol (SAL) and Fluticasone (FLU) in Seroflo spray was investigated using a spectrophotometric device via employing continuous wavelet transform (CWT) and radial basis function neural network (RBF-NN) methods. Root mean square error (RMSE) related to the RBF model was obtained 3.17 × 10-13 and 1.41 × 10-13 for SAL and FLU, respectively. Limit of detection (LOD) and limit of quantification (LOQ) corresponding to the CWT method were 0.004, 0.280 μg/mL, and 0.431, 0.479 μg/mL for SAL and FLU, respectively. Root mean square error (RMSE) of SAL and FLU was obtained 3.17 × 10-13 and 1.41 × 10-13, respectively in RBF-NN method. In the end, the results obtained from all methods were compared with the high-performance liquid chromatography (HPLC) as a reference method. According to the one-way analysis of variance with a 95% confidence level, there is no significant difference between the proposed techniques and HPLC. Therefore, chemometrics methods are sufficiently accurate, as the reference method for the analysis of drugs. The suggested methods are simple, fast, and cheap. Also, there is no need for pre-preparation steps. These methods can be used for quality control laboratories in the pharmaceutical industry.Greenhouse cultivation in the Mediterranean region has undoubtedly enhanced the economic growth and has generated social benefits by making an efficient use of resources. However, these production systems caused undesirable environmental impacts. In order to move towards cleaner production in greenhouse areas, this study has assessed the potential environmental benefits and trade-offs of the integration of an on-farm reverse osmosis system powered by photovoltaic solar energy to recycle the drainage effluents from greenhouses. To that end, we compare the environmental footprint of a greenhouse tomato crop using this technology in a hydroponic system (HS), versus the conventional sanded soil 'enarenado' (CS) with free-drainage to soil. Additionally, for comparison, three independent irrigation sources (desalinated seawater with low electrical conductivity and two different mixes of underground and desalinated water, with moderate and high electrical conductivity, respectively) were evaluated. The use of desalireenhouse structure, and the production of fertilisers and electricity for fertigation represented the highest environmental burdens. When comparing the three irrigation treatments, it was observed that the partial substitution of desalinated seawater by brackish groundwater substantially mitigated (27 %) the global warming footprint. The sensitivity analysis revealed that a significant reduction in the environmental impact is feasible.Green technology innovation is an important driving force for high-quality development in China. Recently, much attention has focused on the connotation, influencing factors and mode selection of green technology innovation, yet few studies have systematically tested the transmission paths between green technology innovation and economic performance. Green technology innovation can be divided into green process innovation and green product innovation, both of which can improve the environmental and economic performance of enterprises. Drawing on previous research, this study constructs a model of economic performance transmission for green technology innovation and upgrading, and conducts an empirical analysis based on data from 642 industrial enterprises in China. The results show that green process innovation and green product innovation can effectively improve the economic performance of enterprises. The environmental performance and market competitiveness of enterprises are important mediating variables in the paths of economic performance improvement. An enterprise's green process innovation can positively promote green product innovation, and there is also room for technological innovation upgrading. There are two main differences in the transmission paths for different types of green technology innovation (1) Green process innovation can improve economic performance directly, whereas green product innovation can only do this indirectly; (2) In most cases, the path from green product innovation to economic performance is more important than that from green process innovation to economic performance. This study deepens understanding of the green technology innovation process and has implications for optimizing policy design for green development.In the present work, effect of coexisting anions on the degradation performance of UV/chlorine (UV/Cl) processes as an advanced oxidation treatment for the dye containing wastewater was investigated. The results showed that by increasing pH of the solution from 3 to 11, degradation efficiency of UV/Cl process was reduced from 96.2 ± 1.4% to 62.9 ± 3.1%. In the case of 100 mg/L of DR831, the removal efficiency was improved from 30.2 ± 1.5% to 93.3 ± 4.7% when the chlorine dose was increased from 100 to 1000 μM. The HCO₃- and Br- ions were the main inhibitor and promotor anions responsible for the degradation of DR831. The relative contribution of Cl• was higher than that for HO• and UV, which was about three-times higher than that for HO•. The lowest and highest amounts of trihalomethanes were generated at acidic and alkaline conditions as well as low disinfection by products at low pH due to the generation of more HO• radicals at acidic pH in comparison to higher pH such that less intermediates were remained to react with chlorine.In the current scenario, the word waste management holds much importance in every individual's life. Pollution and the generation of vast waste quantities with no proper waste management process have become one of humanity's biggest threats. This review article provides a complete review of the innovative technologies currently employed to handle and dispose of the waste successfully. This work aims to include the different solid, liquid, gaseous, and radioactive waste management processes. The novel and improved plasma gasification concepts, transmutation, incineration, bio-refineries, microbial fuel cells (MFC) have been thoroughly explained. In addition, some new techniques like Mr. Trash Wheel and the Smart bin approach provide much hope of adequately managing waste. The work's novelty lies in adopting several successful methods of various countries for waste disposal and management. To incorporate or improve India'sIndia's same techniques and processes, we have to tackle the ever-increasing waste disposal problems and find economic and eco-friendly ways of waste management.The widespread usage of veterinary antibiotics results in antibiotic contamination and increases environmental risks. This study was evaluated the single and ternary competitive adsorption-desorption and degradation of three amphenicol antibiotics (AMs) chloramphenicol (CAP), thiamphenicol (TAP), and florfenicol (FF) in three agricultural soils. The adsorption capacity of amphenicol antibiotics in the soil was weak, and the Kf value was in the range of 0.15-3.59 μg1-1/nL1/n kg-1. In the single adsorption-desorption experiment, the ranked order of adsorption capacity was TAP > FF > CAP. However, in the ternary competitive adsorption experiment, the order was changed to be CAP > FF > TAP. The degradation of AMs in soils was performed at various conditions. All AMs were vulnerable to microbial degradation in soils. A higher initial concentration would reduce the degradation rate and enhance the persistence of AMs in soil. selleck kinase inhibitor The degradation of AMs was positively influenced by changes in soil moisture content and culture temperatures up to 30 °C and decreased at higher temperatures. An equation was used to predict the leachability of AMs in soils and assess their risk to the water environment. The weak adsorption capacity and poor persistence of FF indicated that it may have a strong effect on groundwater based on the equation. It is imperative to further assess the biological impacts of FF at environmentally relevant concentrations given its mobility and extensive use in the livestock industry.This paper proposes a methodology to design the biomethane production chain from MSW at the regional level and to assess the environmental and economic performance of the chain. In the design phase, the following parameters are considered number and production capacity of biomethane plants, localization of plants, waste flows among municipalities and plants. The model is adopted to design the biomethane chain in the Rome Metropolitan Area (Italy). Several structures of production chain are designed and their performances are assessed. The economic factors mostly able to affect the performance of the chain are waste disposal tariff, biomethane selling price, and the economic incentive provided to biomethane producers. Their impacts are discussed through sensitivity analyses. Results show that the structure maximizing the economic performance has the worst environmental performance and vice versa. Hence, a new structure of the economic incentive is proposed, aimed at re-aligning economic and environmental performance.