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Water temperature is a controlling indicator of river habitat since many physical, chemical and biological processes in rivers are temperature dependent. Highly precise and reliable predictions of water temperature are important for river ecological management. In this study, a hybrid model named BP_PSO3, based on the BPNN (back propagation neural network) optimized by the PSO (particle swarm optimization) algorithm, is proposed for water temperature prediction using air temperature (Ta), discharge (Q) and day of year (DOY) as input variables. The performance of the BP_PSO3 model was compared with that of the BP_PSO1 (with Ta as the input) and BP_PSO2 (with Ta and Q as the inputs) models to evaluate the importance of the inputs. In addition, a comparison among the BPNN, RBFNN (radial basis function neural network), WNN (wavelet neural network), GRNN (general regression neural network), ELMNN (Elman neural network), and BP_PSO-based models was carried out based on the MAE, RMSE, NSE and R2. The eight artificial intelligence models were examined to predict the water temperature at the Cuntan and Datong stations in the Yangtze River. The results indicated that the hybrid BPNN-PSO3 model had a stronger ability to forecast water temperature under both normal and extreme drought conditions. Optimization by the PSO algorithm and the inclusion of Q and DOY could help capture river thermal dynamics more accurately. The findings of this study could provide scientific references for river water temperature forecasting and river ecosystem protection.Platanusx hispanica (London plane) is a tree species widely used in urban areas due to the diversity of ecosystem services it provides. However, its functions also have some negative effects or associated disservices, such as the emission of Biogenic Volatile Organic Compounds (BVOCs) and allergens. selleck compound This work aims to analyze the effect that urban environmental conditions and air pollutants have on pollen emissions of plane tree. The study has been carried out in Granada, in the southeast of the Iberian Peninsula, a city with a Mediterranean climate and one of the most polluted in Spain. Granada is also one of the Mediterranean cities in which the increase in the percentage of the population affected by allergy to Platanus pollen in recent decades has been most significant. The 1992-2019 Platanus pollen data series has been considered to establish the main aerobiological parameters, trends and correlations with meteorological variables and particulate and gaseous atmospheric pollutants, both before and during the flowering period. The average Seasonal Pollen Integral (SPIn) of about 2700 pollen grains has shown a significant increase throughout the series. This increase in allergen emissions could be related to the increase in crown volume associated with tree growth, but also to other environmental factors. Precipitation and minimum temperatures of the winter prior to flowering were the parameters that have shown the most influence with SPIn, while O3 and NOx are the pollutants that have the most effect on the peak value. Due to the good adaptation that London plane has to changing climatic conditions in urban environments, its hegemonic presence as an element of Urban Green infrastructure must be reviewed so that the net balance of ecosystem services is not diminished by the disservices.In recent years, biochar composites have received considerable attention for environmental applications. This paper reviews the current state of research on Layered Double Hydroxides (LDHs) tailored biochar composites in terms of their synthesis methods, characteristics, and their use as adsorbents for the removal of various pollutants from water, highlighting and discussing the key advancement in this area. The adsorption potential of LDHs-biochar composites for different inorganic and organic contaminants, important factors affecting composites' properties and the adsorption process, and the mechanisms involved in adsorption are discussed in this review. Though the adsorption capacities are high for the composites studied, partition coefficient which suggest the performance of composites remain low for most adsorbents. Despite the recent progress in the synthesis of LDHs-biochar composites, further research is needed to improve the performance of composites for different classes of aquatic pollutants, and to test their applicability in pilot-scale with real wastewater under real environmental conditions.Polyhydroxyalkanoate (PHA), a family of biodegradable and renewable biopolymers that could potentially play a significant role in bioeconomy. In this study we investigated the potential of date waste (DW) biomass as feedstock to produce PHA by the halophilic archaeon Haloferax mediterranei. The concentration of essential trace elements for H. mediterranei cells during growth and PHA biopolymer accumulation was optimized. A maximum cell dry mass of (CDM) (12.8 g L-1) and PHA concentration of (3.20 g L-1) were achieved in DW extract media that was not supplemented with trace elements, indicating that DW is a promising source for trace elements. The cultivation was scaled-up to fed-batch bioreactor fermentations under non-sterile conditions and resulted in CDM and PHA content of 18.0 g L-1 and 25%, respectively. The produced PHA was confirmed to be poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) with high 3-hydroxyvalerate (3 HV) content of 18.0 mol%. This 3 HV molar percent was achieved without the addition of expensive precursors. The PHBV is of high molecular weight (746.0 kDa) and narrow polydispersity (PDI = 1.5), and displayed reduced melting at 148.1 °C. The X-ray diffraction (XRD) analysis showed that the PHBV has amorphous nature which increases the degradation rates and workability of the biopolymer. The isotopic ratio 13C/12C (δ 13C) for PHBV was found to be - 19.1‰, which indicated that H. mediterranei prefers lighter bonds to break and uses the lighter atoms for the biosynthesis of PHBV.To evaluate the effect of clay on greenhouse gas (GHGs) emissions and humification during pig manure (PM) composting, two lab-scale composting experiments, a control and a 10% clay treatment, were established. The results showed that adding clay reduced the emissions of CH4 and N2O by 45.88% and 86.79%, respectively, promoted the degradation of organic matter (OM) and facilitated the synthesis of humic acid (HA). The spectrum of dissolved organic matter (DOM) indicated that adding clay promoted the formation of aromatic carbon compounds and the degradation of aliphatic carbon. Furthermore, compared with the control, the spectral parameters including the specific UV absorbance at 254 nm (SUVA254), the specific UV absorbance at 280 nm (SUVA280) and the ration of the area at 435-480 nm and at 300-345 nm (A4/A1) of DOM were increased by 5.45%, 3.66% and 29.26%, respectively. Combined with the excitation - emission matrix (EEM) and the percentage fluorescence response (Pi,n), the clay amendment promoted the decomposition of tyrosine and Tryptophan and the formation of humic-like substances, and thus increased humification.

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