Waltonthorup2670

A set of nanocomposite films of poly-vinyl alcohol (PVA) and 0.1-0.4 wt% CdSe nanoparticles (NPs) were developed by spin coating and their surface resistance (R) was measured as a function of light illumination intensity (IL ) and applied magnetic field (H). The ferromagnetic CdSe NPs were synthesized by a facile chemical method which ensured in situ surface stabilization with a skinny layer of graphitic carbon. The CdSe NPs were uniformly dispersed in an aqueous solution of 2.0 wt% PVA and spin-coated on fluorine-doped tin oxide coated glass substrates. The photoresponse of the nanocomposite films at low H exhibits their efficacy for pertinent applications in optoelectronics.The behaviour of stoichiometric U1-y Pu y O2 compounds used as nuclear fuel is relatively well understood. Conversely, the effects of stoichiometry deviation on fuel performance and fuel stability are intricate and poorly studied. In order to investigate what affect these have on the thermophysical properties of hypo-stoichiometric U1-y Pu y O2-x mixed oxide fuel, new interaction parameters based on the many-body CRG (Cooper-Rushton-Grimes) potential formalism were optimized. The new potential has been fitted to match experimental lattice parameters of U0.70Pu0.30O1.99 (O/M = 1.99) and U0.70Pu0.30O1.97 (O/M = 1.97), where M represents the total amount of metallic cations, through a rigorous procedure combining classical molecular dynamic and classical molecular Monte Carlo simulation methods. This new potential provides an excellent description of the U1-y Pu y O2-x system. read more Concerning lattice parameter, although fitted on only one Pu content (30%) and two stoichiometries (1.99 and 1.97), our potential allows good predictions compared to available experimental results as well as to available recommendations in wide ranges of O/M ratio, Pu content and temperature. For the U0.70Pu0.30O2-x hypo-stoichiometric system (30% Pu content and O/M ratio ranging from 1.94 to 2.00), some direct properties (lattice parameter and enthalpy) and some derivative properties (linear thermal expansion coefficient and specific heat) were systematically investigated from room temperature up to the expected melting temperatures and a good agreement with experiments is found. Moreover, our potential shows good transferability to the plutonium sesquioxide Pu2O3 system.A microscopic model is still strongly needed to understand the intrinsic photoluminescence (iPL) of metallic nanostructures. In this paper, a phenomenological model concerning the electron dynamics at the excited states, including the electron-phonon (e-p) and electron-electron (e-e) interactions, is developed. This model shows that the dynamics of non-equilibrium electrons at the excited states influence the iPL features significantly. Two main aspects determine the iPL process of metallic nanostructures the photonic density of states relating to the Purcell effect caused by the surface plasmon resonances, and the electrons transition factor. This model takes into account the contribution of the e-p and e-e interactions to the dynamic electron distribution. The decay process of the non-thermal electrons at the excited states helps understanding most of the iPL features of metallic nanostructures. The calculated and experimental results coincide well regarding the spectral shape, temperature-dependent anti-Stokes emission, and nonlinear behaviors, and time-resolved spectra. The results presented in this paper provide a concise, intuitive, and comprehensive understanding of the iPL of metallic nanostructures.Constructing biological affinity devices is considered as an effective strategy for isolating circulating tumor cells (CTCs), and electrospun nanofibers (ESNFs) have recently received attention. However, the current research focuses on polymer fibers, and fabricating stimuli-responsive inorganic nanofibers for cancer diagnosis and analysis is still challenging. In this work, Zn-Mn oxide nanofibers (ZnMnNFs) are used to capture and purify cancer cells after modification with specific antibodies. Then, the hierarchical nanofibers are degraded by reductive weak acid to release the captured cells efficiently without residues. Fusion of Zn and Mn, two transition metals, enhances the surface activity of oxides so that ZnMnNFs are easier to be degraded and modified. By using MCF-7 cancer cells, the cell capture efficiency of ZnMnNFs is up to 88.2%. Furthermore, by using citric acid, it is discovered that, by comparison with Mn oxide nanofibers, the cell release efficiency of ZnMnNFs is improved to 95.1% from 15.4%. In addition, the viability of released cells exceeds 90%. Lastly, the robustness of ZnMnNFs substrates is tested in peripheral blood from breast cancer patients (BCP) and colorectal cancer patients (CCP). Combined with fluorescence labeling, CTCs are confirmed to be isolated from all the clinical samples. This is the first trial of using ternary inorganic ESNFs for cancer cell capture. It is anticipated that the degradable ESNFs will provide biocompatible theranostic platforms and overcome the current limitations of cell release for high-precision gene analysis.In this paper, NiCo2S4 sulphide spinel nanoparticles are prepared using a modified solvothermal route, after which the obtained siegenite nanoparticles are tailored on graphite-like carbon nitride (g-C3N4) nanosheets. The morphology of tailored nanostructures is accomplished via an ion exchange process. Interestingly, the g-C3N4 stick structures are fabricated based on an innovative approach. Moreover, interfacial polarizations at heterojunction interfaces, and medium effects on microwave characteristics are examined, using polystyrene (PS) and polyvinylidene fluoride (PVDF) as polymeric matrices. The specimens are characterized via Fourier transform infrared (FTIR), X-ray powder diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and transmission electron microscopy (TEM) analyses. The optical performance of nanostructures is studied by means of diffuse reflection spectroscopy (DRS) analysis, and is suggestive of a narrow band gap for NiCo2S4 and NiCo2S4/g-C3N4 nanostructures. Finally, the material's microwave absorbing features are clarified using a vector network analyzer (VNA) instrument via a wave guide technique.