Walterring0591

The degradation rates of parent PAHs increased with aromaticity (6-ring ≫ 2-ring PAHs) and followed pseudo-first order degradation kinetics. The presence and transformation of degradation products, were captured by PARAFAC. NOM influenced the diversity of photoproducts. From the GC-MS results, photoproducts were only detected in Ant, BAnt and the PAH mixture solutions, but optical property analyses indicated that diverse changes occurred with all PAHs. Spectrometric and chromatographic data demonstrated that parent PAHs and photoproducts co-existed at various stages, which is significant for freshwater systems contaminated with these compounds if photoproducts have higher-toxic potential. These results may be used to model the hazard-potential associated with PAHs present in freshwater systems and understanding the mechanisms that govern their environmental fate.As a neurotoxicant, lead (Pb) primarily affects central nervous system, and particularly impacts developing brain. This study explores the associations of blood Pb level and children's behavioral health. A total of 213 preschool children aged 3-7 years old were recruited from Guiyu (the e-waste-exposed area) and Haojiang (the reference area). The behavioral health of children was assessed using the 'behavioral symptoms' subscale of the Strengths and Difficulties Questionnaire (SDQ). Results showed that there was a significant difference in percent of children categorized as "at risk" between Guiyu (48.2%) and Haojiang (13.9%) (p less then 0.001). The blood Pb level of children in Guiyu was significantly higher than those in Haojiang (median 5.19 μg/dL vs. 3.42 μg/dL, p less then 0.001). The serum Neuropeptide Y (NPY) was significantly lower in Guiyu children than those in Haojiang. Spearman correlation analyses demonstrated that blood Pb levels was negatively correlated with NPY (rs = -0.25, p less then 0.001), but positively correlated with behavioral symptom scores; while serum NPY levels were negatively associated with behavioral symptom scores. Behavioral symptom scores were higher in children with blood Pb level ≥5.00 μg/dL (high) than those with blood Pb level less then 5.00 μg/dL (low). After adjusting for confounding factors, children with lower NPY levels were at higher risk of having behavioral difficulties. In conclusion, Pb exposure in e-waste-exposed areas may lead to decrease in serum NPY and increase in the risk of children's behavioral problems. In addition, NPY may mediate the association between Pb exposure and behavioral difficulties.Little attention has been given to the combined effects of elevated atmospheric CO2-induced ocean acidification (OA) and heavy metal pollution on marine macroalgae at the young stage. This study investigated the mutual effects of copper (Cu) and elevated CO2 on the young sporophytes of brown macroalgae Sargassum fusiforme. A matrix of four copper concentrations, 0, 0.025, 0.075 and 0.15 mg‧L-1, and two levels of CO2 (ambient CO2 400 μatm; elevated CO2 1,000 μatm) were used. High concentration of copper exposure greatly depressed photosynthesis and growth of the young sporophytes of S. fusiforme by reducing the apparent photosynthetic efficiency (ɑ), maximum net photosynthetic oxygen evolution rate (Pmax), maximum photochemical quantum yield (Fv/Fm) and pigments content (Chl a and Car). While elevated CO2 alone had obscure impact on this alga. Selleckchem Fluzoparib However, the inhibition of Cu stress on Fv/Fm was weakened by elevated CO2, which also decreased the light compensation point (Ic). Meanwhile, the Cu2+-induced ascent in the dark respiration rate (Rd) and superoxide dismutase (SOD) activity was mitigated under the growth with elevated CO2, suggesting an alleviated oxidative stress. Overall, we propose that, under CO2 enrichment condition, the young sporophytes of S. fusiforme may increase photosynthesis efficiency and synthesize less enzymatic antioxidants in face of increasing Cu stress.Stable isotopes are often used to determine the ecological role of different age classes of animals, but particularly for young animals this approach may be compromised. During gestation and or incubation body tissues of the young are derived directly from the mother. In neonates or post hatching, there is a period of transformation as the young grow and forage independently, but during this period different organs will continue to reflect the maternal isotopic signature as a function of their turnover rate. How long this maternal hangover persists remains poorly understood. We applied a multi-tracer approach (δ15N, δ13C and δ34S) to stable isotope signatures in juvenile bull sharks (Carcharhinus leucas) up to 6.5 years post parturition. We found that maternal provisioning was detectable for up to 3.5 years after birth in muscle but only detectable in young-of-the-year for liver. Inclusion of sulphur revealed when maternal signatures disappeared from low-turnover tissue, while also identifying the spatial and trophic ecology patterns from fast-turnover tissue. These results reveal the importance of sampling fast turnover tissues to study the trophic ecology of juvenile elasmobranchs, and how the use of only δ15N and δ13C isotopes is likely to make maternal patterns more difficult to detect.The new challenges to adsorption are imposed for the diversity of contaminants in wastewater in recent years. Herein, titanate-based materials (peroxide sodium titanate, PST) were modified by three different kinds of surface charged surfactant dodecyl dimethyl betaine (BS-PST), sodium dodecyl sulphate (SDS-PST) and dodecyltrimethyl ammonium chloride (DTAC-PST) to enhance the versatile adsorption performance for four typical contaminants including ammonia nitrogen (NH4+, inorganic and cationic), phosphate (H2PO4-, inorganic and anionic), methylene blue (MB, organic and cationic) and Acid Red G (ARG, organic and anionic). The batch adsorption experiments showed that the DTAC-PST exhibited better in the removal of MB, ARG and H2PO4- than that of other adsorbents. The theoretical maximum adsorption capacity of DTAC-PST is 49.28 mg g-1 for NH4+, 34.74 mg g-1 for TP, 81.87 mg g-1 for MB and 545.81 mg g-1 for ARG. The simultaneous adsorption results showed that the concentration (10 mg L-1 of NH4+, 3 mg L-1 of TP, 50 mg L-1 of MB and 50 mg L-1 of ARG) of all the four chemicals in simulated wastewater could be controlled to be below the discharge levels in China (GB, 18918-2002) by DTAC-PST at the pH of 3.