Valenciastampe2054

Furthermore, solid-state hydrogel electrolyte is employed to fabricate a flexible Al-I2 battery, which shows performance comparable to batteries using liquid electrolyte and can be integrated to power wearable devices as a reliable energy supply.The discovery of durable, active, and affordable electrocatalysts for energy-related catalytic applications plays a crucial role in the advancement of energy conversion and storage technologies to achieve a sustainable energy future. Transition metal borides (TMBs), with variable compositions and structures, present a number of interesting features including coordinated electronic structures, high conductivity, abundant natural reserves, and configurable physicochemical properties. https://www.selleckchem.com/products/dcemm1.html Therefore, TMBs provide a wide range of opportunities for the development of multifunctional catalysts with high performance and long durability. This review first summarizes the typical structural and electronic features of TMBs. Subsequently, the various synthetic methods used thus far to prepare nanostructured TMBs are listed. Furthermore, advances in emerging TMB-catalyzed reactions (both theoretical and experimental) are highlighted, including the hydrogen evolution reaction, the oxygen evolution reaction, the oxygen reduction reaction, the carbon dioxide reduction reaction, the nitrogen reduction reaction, the methanol oxidation reaction, and the formic acid oxidation reaction. Finally, challenges facing the development of TMB electrocatalysts are discussed, with focus on synthesis and energy-related catalytic applications, and some potential strategies/perspectives are suggested as well, which will profit the design of more efficient TMB materials for application in future energy conversion and storage devices.The imbalance of Zn2+ /Cd2+ in the human body can lead to many serious diseases due to the overuse of antibiotics and deposition in animal products. Developing a functional material for detecting is challenging and in demand. Herein, silicon quantum dots (SiQDs) are designed as a functional platform for the detection of tetracycline and Zn2+ /Cd2+ . The COOH functionalized SiQDs with the emission wavelength of 450 nm are chelated with Eu(NO3 )3 to form SiQDs-Eu3+ ratio fluorescent probes, which can be used to detect tetracycline (TCs) and Zn2+ /Cd2+ by fluorescence resonance energy transfer (FRET) principle sequentially. The fluorescent probe showed good linearity between ion concentration and fluorescence enhancement. The detection limit of TCs and Zn2+ /Cd2+ are 0.2 × 10-6 m and 3 × 10-6 m, respectively, when the pH of the solution is 7.4. In addition, the synthesized SiQDs-Eu3+ exhibited good stability (from 94.9% to 103.1%). The relative standard deviations (RSD, n = 10) of human serum and urine were both less than 3%. Therefore, the SiQDs-Eu3+ ratio fluorescence probe will provide a good application prospect in actual sample detection.2D heterostructures exhibit a considerable potential in electrolytic water splitting due to their high specific surface areas, tunable electronic properties, and diverse hybrid compositions. However, the fabrication of well-defined 2D mesoporous amorphous-crystalline heterostructures with highly active heterointerfaces remains challenging. Herein, an efficient 2D heterostructure consisting of amorphous nickel boron oxide (Ni-Bi ) and crystalline mesoporous iridium (meso-Ir) is designed for water splitting, referred to as Ni-Bi /meso-Ir. Benefiting from well-defined 2D heterostructures and strong interfacial coupling, the resulting mesoporous dual-phase Ni-Bi /meso-Ir possesses abundant catalytically active heterointerfaces and boosts the exposure of active sites, compared to their crystalline and amorphous mono-counterparts. The electronic state of the iridium sites is tuned favorably by hybridizing with Ni-Bi layers. Consequently, the Ni-Bi /meso-Ir heterostructures show superior and stable electrochemical performance toward both oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) in an alkaline electrolyte.The degradation mechanism in a sodium cell of a layered Na0.48 Al0.03 Co0.18 Ni0.18 Mn0.47 O2 (NCAM) cathode with P3/P2 structure is investigated by revealing the changes in microstructure and composition upon cycling. The work aims to rationalize the gradual performance decay and the alteration of the electrochemical response in terms of polarization, voltage signature, and capacity loss. Spatial reconstructions of the electrode by X-ray computed tomography at the nanoscale supported by quantitative and qualitative analyses show fractures and deformations in the cycled layered metal-oxide particles, as well as inorganic side compounds deposited on the material. These irreversible morphological modifications reflect structural heterogeneities across the cathode particles due to formation of various domains with different Na+ intercalation degrees. Besides, X-ray photoelectron spectroscopy data suggest that the latter inorganic species in the cycled electrode are mainly composed of NaF, Na2 O, and NaCO3 formed by parasitic electrolyte decomposition. The precipitation of these insulating compounds at the electrode/electrolyte interphase and the related structural stresses induced in the material lead to a decrease in cathode particle size and partial loss of electrochemical activity. The retention of the NCAM phase after cycling suggests that electrolyte upgrade may improve the performance of the cathode to achieve practical application for sustainable energy storage.Lattice plasmons, i.e., diffractively coupled localized surface plasmon resonances, occur in long-range ordered plasmonic nanostructures such as 1D and 2D periodic lattices. Such far-field coupled resonances can be employed for ultrasensitive surface-enhanced Raman spectroscopy (SERS), provided they are spectrally matched to the excitation wavelength. The spectral positions of lattice plasmon modes critically depend on the lattice period and uniformity, owing to their pronounced sensitivity to structural disorder. We report the fabrication of superlattices by templated self-assembly of gold nanoparticles on a flexible support, with tunable lattice-plasmon resonances by means of macroscopic strain. We demonstrate that the highest SERS performance is achieved by matching the lattice plasmon mode to the excitation wavelength, by post-assembly fine-tuning of long-range structural parameters. Both asymmetric and symmetric lattice deformations can be used to adapt a single lattice structure to both red-shifted and blue-shifted excitation lines, as exemplified by lattice expansion and contraction, respectively. This proof-of-principle study represents a basis for alternative designs of adaptive functional nanostructures with mechanically tunable lattice resonances using strain as a macroscopic control parameter.Although there are various pre-existing technologies for engineering vasculatures, multiscale modeling of the architecture of human vasculature at a capillary scale remains a challenge. In this study, a novel technology is developed for the production of a functional, multiscale microvasculature comprising of endothelialized channels and tissue-specific capillary networks. Perfusable, endothelialized channels are bioprinted, after which angiogenic sprouts are grown into user-designed capillary networks. The induction of branched and liver-lobule-like capillary networks confirm that the technology can produce various types of tissue-specific multiscale microvasculatures. Further, the channels and capillaries are deemed to be functional when evaluated in vitro. An ex vivo assay demonstrates that the microvasculature can induce neovessel ingrowth, integrate with host vessels, and facilitate blood flow. Remarkably, blood flows through the implanted capillary network without any change in its morphology. Finally, the technology is applied to produce a vascularized liver tissue; it significantly improves its hepatic function. It is believed that this new technology will create new possibilities in the development of highly vascularized and functional tissues/organs on a clinically relevant scale.The continuous miniaturization of microelectronics is pushing the transformation of nanomanufacturing modes from top-down to bottom-up. Bottom-up manufacturing is essentially the way of assembling nanostructures from atoms, clusters, quantum dots, etc. The assembly process relies on nanowelding which also existed in the synthesis process of nanostructures, construction and repair of nanonetworks, interconnects, integrated circuits, and nanodevices. First, many kinds of novel nanomaterials and nanostructures from 0D to 1D, and even 2D are synthesized by nanowelding. Second, the connection of nanostructures and interfaces between metal/semiconductor-metal/semiconductor is realized through low-temperature heat-assisted nanowelding, mechanical-assisted nanowelding, or cold welding. Finally, 2D and 3D interconnects, flexible transparent electrodes, integrated circuits, and nanodevices are constructed, functioned, or self-healed by nanowelding. All of the three nanomanufacturing stages follow the rule of "oriented attachment" mechanisms. Thus, the whole-lifetime bottom-up manufacturing process from the synthesis and connection of nanostructures to the construction and service of nanodevices can be organically integrated by nanowelding. The authors hope this review can bring some new perspective in future semiconductor industrialization development in the expansion of multi-material systems, technology pathway for the refined design, controlled synthesis and in situ characterization of complex nanostructures, and the strategies to develop and repair novel nanodevices in service.Miniaturized energy storage devices are essential to power the growing number and variety of microelectronic technologies. Here, a concept of self-propelled microscale energy storage elements that can move, reach, and power electronic circuits is reported. Microrockets consisting of a nickel sulfide (NiS) outer layer and a Pt inner layer are prepared by template-assisted electrodeposition, and designed to store energy through NiS-mediated redox reactions and propel via the Pt-catalyzed decomposition of H2 O2 fuel. Scanning electrochemical microscopy allows visualizing and studying the energy storage ability of a single microrocket, revealing its pseudocapacitive nature. This proves the great potential of such technique in the field of micro/nanomotors. On-demand delivery of energy storage units to electronic circuits has been demonstrated by releasing microrockets on an interdigitated array electrode as an example of electronic circuit. Owing to their self-propulsion ability, they reach the active area of the electrode and, in principle, power its functions. These autonomously moving energy storage devices will be employed for next-generation electronics to store and deliver energy in previously inaccessible locations.Lithium titanate is one of the most promising anode materials for high-power demands but such applications desire a complete understanding of the kinetics of lithium transport. The poor diffusivity of lithium in the completely lithiated and delithiated (pseudo spinel) phases challenges to explain the high-rate performance. This study aims at clearing the kinetics of lithium transport using an innovative technique that employs optical microscopy in a constrained region of sputter-deposited thin-film samples. It enables the in situ observation of the transport of lithium through the electrode. Furthermore, with a thermostatically controlled cell, the Arrhenius-like temperature dependence is revealed. The quantitative findings demonstrate that indeed the end phases have poor diffusivity which is, however, accelerated at intermediate Li concentrations in the spinel structured Li4/3+ δ Ti5/3 O4 phase. Surprisingly, the slow migration of the phase boundary hinders the formation of the Li-rich (rock-salt) phase in the initial stages.