Valdezcoates5910

Herein, this study not only offers a new strategy for reusing OS as value-added persulfate activators but also deepens the fundamental understanding on the nonradical regime.Long-term exposure of anammox process to 1,4-dioxane was investigated using periodic anammox baffled reactor (PABR) under different 1,4-dioxane concentrations. The results generally indicated that PABR (composed of 4 compartments) has robust resistance to 10 mg-dioxane/L. The 1st compartment acted as a shield to protect subsequent compartments from 1,4-dioxane toxicity through secretion of high extracellular polymeric substance (EPS) of 152.9 mg/gVSS at 10 mg-dioxane/L. However, increasing 1,4-dioxane to 50 mg/L significantly inhibited anammox bacteria; e.g., ~ 93% of total nitrogen removal was lost within 14 days. The inhibition of anammox process at this dosage was most likely due to bacterial cell lysis, resulting in the decrease of EPS secretion and specific anammox activity (SAA) to 105.9 mg/gVSS and 0.04 mg N/gVSS/h, respectively, in the 1st compartment. However, anammox bacteria were successfully self-recovered within 41 days after the cease of 1,4-dioxane exposure. The identification of microbial compositions further emphasized the negative impacts of 1,4-dioxane on abundance of C. Brocadia among samples. Furthermore, the development of genus Planococcus in the 1st compartment, where removal of 1,4-dioxane was consistently observed, highlights its potential role as anoxic 1,4-dioxane degrader. Overall, long-term exposure to 1,4-dioxane should be controlled not exceeding 10 mg/L for a successful application.Atmospheric Hg is a highly toxic heavy metal with bioaccumulative properties. However, relatively few studies have focused on the distribution of Hg in cellular and subcellular structures of plants and factors influencing its accumulation. In this study, we selected Tillandsia usneoides, which is a widely used bioindicator for Hg, to analyze the concentration of Hg in different cells (foliar trichomes, epidermal cells, mesophyll cells, and vascular bundle cells), different subcellular structures (cell wall, cell membrane, vacuoles, and organelles) and different cell wall components (pectin, hemicellulose 1, and hemicellulose 2). It was determined that Hg was present in different types of cells, but there was no significant difference, suggesting that atmospheric Hg circulates dynamically in the surface and internal structural cells of T. usneoides leaves. Subcellular analysis showed that as Hg concentration increased, more Hg accumulated in the vacuoles and cell wall through the compartmentalization mechanism. Hemicellulose had the highest content of Hg, indicating that it is the primary Hg-binding component of the cell wall. The FTIR analysis results showed that after the Hg treatment, the cell wall -OH and COO- absorption peaks changed most significantly, indicating that these functional groups play a vital role in the Hg accumulation process.2,4-Dichlorophenol (2,4-DCP) is a highly toxic water contaminant. Calcium folinate In this study, we demonstrate a novel catalytic filtration membrane by coating MnOOH nanoparticles on nylon membrane (MnOOH@nylon) for improved removal of 2,4-DCP through a synergetic "trap-and-zap" process. In this hybrid membrane, the underlying nylon membrane provides high adsorption affinity for 2,4-DCP. While the immobilized MnOOH nanoparticles on the membrane surface provide catalytic property for peroxymonosulfate activation to produce reactive oxygen species (ROS), which migrate with the fluid to the underlying nylon membrane pore channels and react with the adsorbed 2,4-DCP with a much higher rate (0.9575 mg L-1 min-1) than that in the suspended MnOOH particle system (0.1493 mg L-1 min-1). The forced flow in the small voids of the MnOOH nanoparticle coating layer ( less then 200 nm) and channels of nylon membrane (~220 nm) is critical to improve the 2,4-DCP adsorption, ROS production, and 2,4-DCP degradation. The hybrid MnOOH@nylon membrane also improves the stability of the MnOOH nanoparticles and the resistibility to competitive anions, due to much higher concentration ratio of the adsorbed 2,4-DCP and produced ROS versus background competitive ions in the membrane phase. This study provides a generally applicable approach to achieve high removal of target contaminants in catalytic membrane processes.Intensive use of low-density polyethylene (LDPE) plastic films in agro-ecosystems has raised considerable concerns due to the increasing film residues in soils. It is unclear how the increased film residues affect soil properties and crop productivity and whether biodegradable (Bio) film can substitute LDPE. To address the issue, we designed a landfill experiment with different addition levels of plastic residue into soils of maize (Zea mays L.) field from 2018 to 2019. Six treatments were arranged as PMT1-T3/BioT1-T3, representing the low, medium, and high-level application of LDPE / Bio film fragments, with no residual film, applied as CK. Results show that, soil bulk density was significantly increased from 1.19 to 1.31 g/cm3 regardless of residue types. In contrast, soil porosity was lowered from 58.03% in CK to 57.36% in Bio and 56.12% in LDPE significantly (P less then 0.05). Increased residues improved soil nitrogen level and lowered the C/N ratio significantly. Also, it decreased microbial biomass C and N levels but with no change in C/N (P less then 0.05). Maize yield and WUE decreased, while soil water storage increased significantly. LDPE residues affected soil properties and productivity partly lower than Bio ones did, but the negative effects of them were similar in the maize field.The controlled release of pesticides based on nanoparticle platforms has emerged as a new technology for increasing the efficiency of pesticides and for reducing environmental pollution because of their size-dependent and target-modifying properties. In the present study, pH/cellulase dual stimuli-responsive controlled-release formulations (PYR-HMS-HPC) were designed by grafting hydroxypropyl cellulose onto pyraclostrobin-loaded hollow mesoporous silica nanoparticles via an ester linkage. The PYR-HMS-HPC formulations were characterized by Fourier transform infrared spectroscopy, thermogravimetric analyzer, transmission electron microscope and scanning electron microscope. The results demonstrated that PYR-HMS-HPC with a loading capacity of 12.1 wt% showed excellent pyraclostrobin release behaviors in response to acidic environments and the introduction of cellulase, could effectively prevented pyraclostrobin from photolysis. Compared with commercial pyraclostrobin formulations, the PYR-HMS-HPC formulations showed much stronger and statistically significant fungicidal activity against Magnaporthe oryzae from 7 to 21 days.