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In altricial species, parents brood their chicks constantly before leaving them unattended sometimes for extended periods when they become thermally independent. During this second phase, there is sometimes important inter-individual differences in parental attendance and the fitness costs and benefits of parental strategies have previously been extensively investigated. However, the impact of parental presence on offspring behaviors and stress physiology has been overlooked. Here, we examined the influence of parental presence on offspring hormonal and behavioral stress sensitivities in snow petrel chicks. We demonstrated for the first time in a wild bird species that attended chicks had lower stress-induced corticosterone levels and a lower probability to show defensive behavior compared to the alone chicks. This reduced stress sensitivity is certainly explained by the well-known link between corticosterone and nutritional status, and by the recent delivery of meals to the attended chicks and the improvement of their nutritional status. It may also be explained by the parental protection against predators or inclement weather, or/and by the psychosocial comfort of parental presence for the offspring. Overall, these results suggest that the presence of a parent in the nest reduces offspring stress sensitivity in wild birds. Further studies would now be required to disentangle the impact of nutritional status and parental presence on stress sensitivity and to better understand the potential impact of parental presence and circulating corticosterone levels on growth and cognitive development in wild birds.Coastal environmental pollution is a global problem that has been growing for decades. For this reason, different approaches have been sought to address and detect its environmental implications. Some organisms are considered bioindicators or biomonitors of contamination, which provide information about environmental quality. Previous studies used the crab Neoelice granulata (Brachyura, Varunidae) as bioindicator of the presence of metals by the analysis of soft tissues to evaluate physiological and molecular markers. However, the contaminant levels accumulated in these soft tissues have shown to be affected by seasonal variations, suggesting that environmental assessments based on soft tissue samples may be unreliable. Within this framework, we aimed to describe the crab body (carapace) variations related to a known soil metal gradient in a Patagonian salt marsh and to evaluate the use of the body shape as an alternative biomarker for monitoring the quality of salt marsh systems. We studied the carapace shape variations using geometric morphometrics (GM) based on a 2D structure with object symmetry. We observed symmetric and asymmetric components of carapace shape variation. While the latter was not found associated with a gradient of contamination by metals, the symmetric component responded to environmental changes; therefore, it could be considered a stress biomarker related to metal contamination. Consequently, we recommended using GM analysis because it is inexpensive, faster and non-seasonal and could be used on living organisms, avoiding destroying individuals to measure the environmental stress.Graphene oxide (GO) with beneficial functional groups regulates the surface chemistry for catalytic applications. However, the low electrical conductivity of GO invokes further treatments that compromise the above-valued properties. We report an interfacial engineering of GO decorated with SnO2 quantum dots (QDs) for the visible-light-driven catalysis of dye degradation. Retention of beneficial functional features of GO and QDs in the GO-SnO2 composite is established by using TEM, FTIR, and Raman spectroscopy techniques. Further, investigations with EXAFS and lifetime-measurements provide the local structure and defects distributions in QDs which are correlated with the improved conductivity. PL and electrochemical impedance spectroscopic measurements help unraveling the charge-transfer across the interface of the GO-SnO2 composite. The unique ability of ∼94% degradation of MB using only 0.5 mg of GO-SnO2 catalyst within half an hour under the visible light is demonstrated for the first time with insights on the photocatalytic mechanism.This paper investigates the occurrence and removal of 60 organic micropollutants (OMPs) including pharmaceuticals, personal care products, pesticides and per- and polyfluoroalkyl substances in a drinking water treatment plant (DWTP) treating raw water from the Ebro River (NE Spain). The behaviour of the OMPs was evaluated in each treatment pre-ozonation, flocculation-coagulation-decantation-sand filtration, post-ozonation and granular activated carbon filtration. Thirty-one of the sixty OMPs studied were detected in source water with individual median concentrations below 10 ng L-1 for all the compounds except for caffeine (64.1 ng L-1). The highest concentration peaks in the source water were found for caffeine (124.5 ng L-1), terbuthylazine (52.0 ng L-1), imidacloprid (30.2 ng L-1) and paracetamol (25.6 ng L-1). Of the 31 compounds detected in the source water, 17 were also detected in the finished drinking water. Of these 17 compounds, 10 were PFASs, which indicated that this group of compounds had not been effectively removed throughout the drinking water treatments. The overall removal efficiencies of OMPs in the DWTP ranged from -50.9% to 100%. The most efficient removal technologies were ozonation and granular activated carbon.Silver ion (Ag+) is an important catalyst to improve chalcopyrite bio-dissolution, but its effects on initial adhesion behaviors and biofilm formation of acidophiles onto metal sulfide were still unknown. In this study, initial attachment behavior and adhesion force in the presence of Ag+ (0, 1, 2, 5, 10 and 20 mg/L) were comparatively analyzed for Acidianus manzaensis YN-25. Biofilm was observed by fluorescent images in the presence of 0, 1 and 2 mg/L Ag+. X-ray photoelectron spectroscopy (XPS) corroborated the catalytic mechanisms of Ag+ to biofilm formation. Results showed that Ag+ could significantly promote the attachment of cells on chalcopyrite, and the optimum concentration of Ag+ was 2 mg/L with the biggest percentage of attached cells (74%), followed by 5 mg/L (71%), whereas that for the control (0 mg/L) was only 61%. selleck chemicals Ag+ significantly increased the interaction force between A. manzaensis YN-25 and chalcopyrite. Compared with the control, larger coverage of biofilm (up to 40% versus 32%) and more corrosion pits were observed on chalcopyrite in the presence of 2 mg/L Ag+.

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