Molinawinkel5165

l exposure was mainly driven by traffic variables, while internal dose was mainly driven by personal characteristics and smoking habit.Since the 1940's, rapid shoreline and dunefield changes have been ongoing at Salmon Hole, an embayment situated near Beachport in the SE of South Australia. Storm induced erosion has nearly removed the entire dunefield and created a lagoon confined by a calcarenite reef. This study examines the progress, dynamics and causes of the erosion to determine why it has been so severe, using historical aerial imagery, wave reanalyses data, Digital Surface Models (DSM's) from drone surveys and through the volumetric analysis of topographic profiles. The results gained through analysing shoreline change at Salmon Hole are then discussed based on Phillips (2009) change assessment system. This study found that a combination of the formation of the 'lagoon' between the mainland/dune system and the offshore reef and the resultant breakthrough of the tombolo that have led to the acceleration of the erosion processes seen at Salmon Hole. The formation of the lagoon initiated a divergent evolution that continues in the form of a significant geologically controlled longshore current and terminal rip that enhances removal of sediment during and following erosion of the dunes. It appears that each time the lagoon widened post storm erosion it resulted in an increase in the efficiency of the current, resulting in a positively reinforcing feedback loop furthering the erosion level during each successive storm. Stem Cells antagonist The profiles taken from the drone survey DEM's reveal the processes involved in scarping and demonstrate how dune systems with zero sediment supply will respond to future climate and wave conditions. Coastal systems experiencing a deficit in sediment supply will not be able to translate landwards/upwards resulting in their removal. If the current rate of erosion at Salmon Hole is maintained into the future, the entire system is likely to be fully eroded within the next 30 years.Suspended particulate organic carbon (POC) and sedimentary total organic carbon (TOC) in coastal areas play critical roles in the global carbon cycle, yet sources and dynamics of coastal POC and TOC have been affected by various anthropogenic activities such as aquaculture, sewage discharge, dam construction and land reclamation. To better understand the anthropogenic impacts on coastal organic carbon, this study was carried out in a representative semi-enclosed bay, Dongshan Bay, Southeast China. Through analyses of stable isotopic compositions of both POC (δ13CPOC and δ15NPN) and TOC (δ13CTOC and δ15NTN), the ratio of total organic carbon vs. total nitrogen (C/N), grain size, Chl-a concentrations and hydrological parameters, our study led to the following main findings 1) During flood season, the distribution of δ13CPOC, δ13CTOC, δ15NPN and δ15NTN values within the bay did not follow the conventional land-sea transition pattern. This distribution pattern indicated more terrestrial organic matter input seaward, which contrasts with the conventional organic matter distribution along the estuarine gradient. 2) Using the organic δ13C, δ15N and C/N signatures of different endmembers, we found that the sources of organic matter deposited in the bay were strongly related to anthropogenic activities, including municipal wastewater discharge, aquaculture, land reclamation and sluice-dyke construction. Furthermore, 3) by applying the Grain Size Trend Analysis Model and the previously-estimated residual current directions, we suggested that human activities have not only altered the sources of organic matter to the semi-enclosed bays, but also significantly modified their transportation and deposition patterns, and might influence the ultimate fate of organic matter into and out of Dongshan Bay. The conclusions of this study should be applicable to similar coastal bays around the world.Antibiotic fermentation residue (AR) is composed of hazardous organic waste produced by the pharmaceutical industry. AR can be effectively converted into bio-oil by fast pyrolysis, but its high nitrogen content limits the prospect of bio-oil as a fuel resource. In order to further reduce the nitrogen content of AR bio-oil, we have examined the catalytic removal of N and O from penicillin fermentation residue (PR) bio-oil under fast pyrolysis conditions. We have used M/HZSM-5 (M = Fe, Co, Ni, Cu, Zn, Zr, Mo, Ag and Ce) metal catalysts, with a metal oxide content of 10%. Additionally, the effect of mixed and separated catalytic forms on catalytic upgrading were analyzed, and changes in the catalyst itself before and after pyrolysis under separated catalytic conditions were specifically investigated. Our results show that the metal elements in the fresh catalyst will exist in the form of oxides, ions and simple metals. In-situ reduction caused by pyrolysis gas in the catalytic pyrolysis process makes some ionic metals (e.g., Co2+, Cu2+ and Ag+) in the catalyst transform into oxides, and some metal oxides are reduced to simple metals or suboxides (including Fe, Ni, Cu and Mo). The N content in the mixed catalytic bio-oil decreased from 10.09 wt% to Zn/HZSM-5 (6.98 wt%), Co/HZSM-5 (7.1 wt%), Cu/HZSM-5 (7.18 wt%) and Ce/HZSM-5 (7.18 wt%). We also observed significant reduction in the O content (9.77 wt%) with Ag/HZSM-5 (3.75 wt%), Mo/HZSM-5 (6.86 wt%), Ce/HZSM-5 (8.39 wt%) and Fe/HZSM-5 (8.54 wt%) in the separated catalytic bio-oil. The Ni/HZSM-5 catalystcan reduce the organic acid content in bio-oil from 22.9% to 10.8%. The separated catalysis methodology also promoted an increase of hydrocarbons in the bio-oil Zn/HZSM-5, Ag/HZSM-5, Mo/HZSM-5, Zr/HZSM-5 and Ce/HZSM-5 reached 11.6%, 11.5%, 11.1%, 10.1%, and 8.8%, respectively. Carbon deposition formed by aromatic carbon/graphite carbon, pyrrole and pyridine compounds leads to deactivation of the catalyst.The photolysis of NO2 is an important driving force of tropospheric ozone. The intensity of this photolysis reaction affects atmospheric oxidation and photochemical pollution process. Photolysis rate of nitrogen dioxide (JNO2) is affected by aerosols, temperature, solar zenith angle (SZA), clouds, and so on. Among them, aerosol is an important influencing factor because of its complicated and irregular change; aerosol quantitative effect on JNO2 is constructive for the coordinated control of O3 and particulate matter. In order to quantitatively assess the impact of aerosols on JNO2 in the long-term, the reconstructed JNO2 data in a suburban site in North China from 2005 to 2019 are used. We found that JNO2 and aerosol optical depth (AOD) presented logarithmic relations under different solar zenith angle (SZA) levels, the aerosol attenuation effect on JNO2 decreased as AOD increased. Two main influencing factors of JNO2, SZA, and AOD, were fitted into a quadratic polynomial to quantify the AOD effect on JNO2. The results showed that the average annual AOD effect on JNO2 in Xianghe from 2005 to 2019 was -28.