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655 kWh m-3). This study provides new insights into the direct single electron activating PDS to produce non-radical H*/1O2 via core-shell catalytic MnFe3O4@PZS, and displays a promising application in wastewater treatment.Fly ash and arsenic species have been regarded as contaminants that pollute the environment. Herein, low alumina fly ash (LAFA) was utilized to fabricate the As(V) and As(III) adsorbent via combining the routes of alkali fusion and incipient-wetness impregnation. The characterization results suggested that the grafted ferric citrate was coordinated to LAFA by substituting a Si4+ to a Fe3+, and the compound monosodium citrate was observed. Based on the XPS analysis, the C-O and -COO- groups of monosodium citrate played the significant role in uptaking As(V) and As(III) species by chemical complexation, the FeOOH adsorbed As(V) and As(III) species via ion-exchange, and the Fe2O3 oxidize As(III) into As(V). Additionally, it was observed that the As(V) removal performance by adsorbent prepared with different modifiers was in the order of FeC6H5O7 (ca. 93.7%) > C6H8O7 (84%) > HCl (73%). And then, the optimal adsorbent synthesis condition for As(V) uptake was explored at ferric citrate loaded LAFA with 11 mass ratio (fly ash to NaOH) under temperature 923 K. The maximum monolayer adsorption capacities of the optimal adsorbent were 2725.0 μgAs(V)/g and 2281.9 μgAs(III)/g, and the removal efficiency of As(V) and As(III) was near 100% for their initial concentrations below 500 ppb, where the residual arsenic concentration met the required standard in drinking water (lower than 10 ppb).Increasing amounts of municipal solid waste (MSW) has gained widely concern on reduction, utilization and minimizing environmental impacts associated with waste management. Life cycle assessment (LCA) has been used to evaluate total environmental impact of municipal waste management (MSWM) options in strategy-planning and decision-making process. The exiting LCA studies have covered a large range of detailed focus from waste treatment technology to applied modelling methods in LCA of MSWM, yet an important concern for stakeholders, the relationship between practical management strategies and their LCA results, has not been comprehensively summarized. Pimicotinib in vitro This paper reviews recent LCA studies focusing on MSWM system in 45 cases from both developing and developed regions to promote evolution of the MSWM system through modification of waste management strategies. Selected literatures conducted LCA with system boundary covering the whole MSWM system rather than single treatment process or specific type of waste. Thisimitation, environmental concern, management chain and comprehensive impact, providing useful strategies on improving MSWM with generalization results of LCA studies.The provision of sanitation services for fast-growing urban populations is one of the world's urgent challenges. Hutong neighborhoods in Beijing, capital of China, cannot be rebuilt due to the protection of historical heritage, while residents still need to keep the habit of defecating in public toilets. One hundred public toilets with non-sewered sanitation in the Hutong neighborhoods of Beijing were visited to investigate the actual operating status in response to the "toilet revolution" campaign. The fault tree approach was used to identify the barriers toward a decent and environment-friendly public toilet and evaluate potential risks from the malfunction of various components. Four subsystems are defined and elaborated to calculate the fault possibility. These subsystems are environment- and user-friendly, regarded as ancillary facilities, and used for fecal sludge (FS) management. Statistical analysis of targeted cases indicated that fault probabilities of environmental considerations, user-friendly considerations, ancillary facilities, FS management are calculated as 0.79, 0.96, 0.96, and 0, respectively. The subsystems were weighted using a Delphi method concept. Results showed that the well operation ratio of Beijing Hutong public toilets is only 32%, and the sanitation service value chain can be further optimized. This study also provides references for other countries, which are dedicated to promoting urban sanitation and public health.Urban runoff is a diffuse source of pollution contributing to the poor ecological and chemical status of surface waters. Whilst the EU Priority Hazardous Substances Directive now identifies environmental quality standards for selected metals in relation to the bioavailable metal fraction the relationship between analytically determined metal size fractions transported by urban runoff and the often variably defined concept of bioavailability has not been thoroughly evaluated. This paper provides a review of the terminology used within urban runoff studies to characterise metal fractions and behaviour. Measured dissolved and truly dissolved (determined by ultrafiltration; less then 3000 molecular weight cutoff) Cu, Ni, and Zn concentrations are also compared to the bioavailable metal fraction (as predicted using Bio-met, a simplified biotic ligand model) in snowmelt and rainfall derived runoff samples from three urban catchments. The study shows that predicted bioavailable concentrations were significantly lower than truly dissolved concentrations for all metals and discusses current bioavailability modelling parameters in relation to rainfall and snowmelt runoff data sets. Statistical analysis of relationships between field and predicted bioavailable data sets indicate that the bioavailable fractions originate from both colloidal and truly dissolved fractions.The purpose of this paper is to adjust the measure of eco-efficiency to account for specific sustainability targets at farm level. We assess eco-efficiency and adjust the scores according to a target of absolute levels of greenhouse gas (GHG) emissions, using Data Envelopment Analysis (DEA) and data from Swedish dairy farms as an illustrative example. In particular, the Swedish target of net-zero emissions in 2045 and vision of a fossil free economy are used to specify the GHG emission target used for assessing the adjusted eco-efficiency scores. We test for possible factors associated with the adjusted and unadjusted eco-efficiency using OLS-regression analysis. The study is based on data from the farm accounting data network (FADN) in year 2016 and considers the environmental pressures nutrients and contribution to global warming. Adjusted as well as unadjusted eco-efficiency scores suggest that Swedish dairy farms are highly inefficient, and that economic value added could increase by 64% (adj) or 67% (unadj) for conventional farms and by 42% (adj) or 41% (unadj) for organic farms at the same level of environmental pressure.