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N. muscorum invested more in antioxidants induction, i.e., induced ascorbate and glutathione cycle, however, these antioxidants increments in A. laxa were less pronounced. Overall, this study provides more in-deep insights into the PY toxicity and the role of N. muscorum as a promising PY remediator.Study of hazardous microplastics in the natural water resources is minimal compared to the sea salt, seafood and even packaged water. We presented results of the first baseline research of microplastics in groundwater and surface water from the coastal south India (Tamil Nadu state) and evaluated the heavy metal adsorption capacities of different polymers. The microplastics (up to 19.9 particles/L) were of relatively larger size in surface water (0.34-4.30 mm) compared to the groundwater (0.12-2.50 mm). Polyamide (nylon), polyester, polypropylene, polyethylene, polyvinyl chloride and cellulose were the common polymers and all of them showed different capacities of heavy metal adsorption. In two different experimental sites, the polypropylene showed higher capacity of adsorption compared to other polymers in the following orders (i) cadmium > manganese > lead > arsenic and (ii) manganese > zinc > arsenic > lead > copper. The polyamide, however, exhibited better adsorption only for manganese. Similar to other recent findings, our results associate microplastics as a major vector to transport heavy metals in the water system. Formulation of strategies to reduce the environmental risks of particulate plastics as a potent vector for transportation of the toxic trace elements and subsequent, impact on human health through the OSPRC framework (Origins, Sources, Pathways, Receptors and Consequence) in the study area would require future research.Tris(1,3-dichloro-2-propyl) phosphate (TDCPP), a widely used chlorinated organophosphorus flame retardant, is an increasingly widespread contaminant of aquatic environment. In this study, time-dependent effect of TDCPP on the freshwater green-algae Chlorella pyrenoidosa was investigated and its underlying mechanisms were explored. We show that TDCPP lower than 10 ppm caused a reversible inhibition of algal growth, with complete inhibition occurring at 15 ppm. This inhibition was not caused by damage from reactive oxygen species, but rather resulted from the impairment of photosynthetic function, with PSII reaction center as the primary target, as indicated by Chl a fluorescence induction, QA- reoxidation, S-state distribution and immunoblot analysis. The reversal of damage caused by TDCPP concentrations under 10 ppm might be attributable to the repair of photosynthetic function by de novo protein biosynthesis in the chloroplast, with the most likely explanation being the replacement of the damaged PSII D1 protein. The results provide novel insights into mechanisms of TDCPP toxicity toward freshwater microalgae and better understanding of ecological consequences of TDCPP in the environment.In this study, we intended to investigate the responses of rhizospheric bacterial communities of Populus cathayana to excess Zn under different planting patterns. The results suggested that intersexual and intrasexual interactions strongly affect plant growth and Zn extraction in both sexes, as well as rhizosphere-associated bacterial community structures. Females had a higher capacity of Zn accumulation and translocation than males under all planting patterns. Males had lower Zn accumulation and translocation under intersexual than under intrasexual interaction; the contrary was true for females. Females harbored abundant Streptomyces and Nocardioides in their rhizosphere, similarly to males under intersexual interaction, but differed from single-sex males under excess Zn. Conversely, intersexual interaction increased the abundance of key taxa Actinomycetales and Betaproteobacteria in both sexes exposed to excess Zn. Males improved the female rhizospheric microenvironment by increasing the abundance of some key tolerance taxa of Chloroflexi, Proteobacteria and Actinobacteria in both sexes under excess Zn in intersexual interaction. https://www.selleckchem.com/products/way-309236-a.html These results indicated that the sex of neighboring plants affected sexual differences in the choice of specific bacterial colonizations for phytoextraction and tolerance to Zn-contaminated soils, which might regulate the spatial segregation and phytoremediation potential of P. cathayana females and males under heavy metal contaminated soils.A rapid and ultrasensitive method for colourimetric/photothermal dual-readout detection was developed using an 808 nm NIR laser and a thermal imaging app on mobile phone. Norfloxacin was used as a model contaminant to demonstrate this universal rapid detection method. It is innovatively, to use the advanced two-dimensional material black phosphorus as a colourimetric/photothermal reagent for the first time. The samples were added to the strip, and the analytes were selectively captured on the conjugate pad by monoclonal antibody-modified magnetic/upconversion nanocomposites. The samples flowed through the strips by capillary action until reaching the control line, where immune complex formation occurred due to the presence of secondary antibody. The added black phosphorus could be captured by the the antigens which were directly exposed to the test line and a brown band could be observed by naked eye. Upon illumination by NIR light for 1 min, the real-time temperature is obtained for quantitative analysis through the thermal imaging performed by mobile phone camera. This method can achieve the detection of norfloxacin in water samples within 20 min, and the detection limits of colorimetric and photothermal readout can reach 45 pg mL-1. Compared with conventional strips, this method provided an increased sensitivity by about two orders of magnitude, with a integrated portable laser and a mobile phone. It is a valuable method for rapid detection and can be applied to other environmental contaminants as well.To improve the visible-light photocatalytic activity of graphitic carbon nitrate (g-C3N4) for practical application, a Gd2O3-cluster decorated O-doping g-C3N4 was fabricated via an ethanol assisted solvothermal-polycondensation method. The as-prepared photocatalysts, including bulk g-C3N4 (CN), O-doping g-C3N4 (HECN) and Gd2O3-cluster decorated O-doping g-C3N4 (HECN-xGd), were characterized and the paralleled experiments were conducted to evaluate the photocatalytic activity, mineralization capacity and mineralization mechanism, where sulfamerazine (SMR) was employed as the target pollutant. Furthermore, the quenching tests with scavengers were executed to analyze the contributions of the dominant active species, where the O2- was identified as a major role, and h+ as the minor role in the photodegradation of SMR. Results from the paralleled experiments suggested that the HECN-xGd possesses superior photocatalytic activity to HECN and CN, besides the feasible reusability through five cycles and impressive total organic carbon (TOC) removal about 60%.

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