Hendrixbreen9889

A meta-analysis of 94 published studies was conducted to explore the impacts of farmland application of antibiotic-contaminated manures on antibiotic concentrations and ARG abundances in manure-amended soil. Forty-nine antibiotics were reported, in which chlortetracycline, oxytetracycline, doxycycline, tetracycline, enrofloxacin, ciprofloxacin and norfloxacin were the most prevalent and had relatively high concentrations. The responses of ARG and mobile genetic element (MGE) abundances to farmland application of antibiotic-contaminated manures varied considerably under different management strategies and environmental settings. On average, compared to unamended treatments, farmland application of antibiotic-contaminated manures significantly increased the total ARG and MGE abundances by 591% and 351%, respectively (P less then 0.05). Of all the included ARG classes, the largest increase was found for sulfonamide resistance genes (1121%), followed by aminoglycoside (852%) and tetracycline (763%) resistance genes. Correlation analysis suggested that soil organic carbon (SOC) was significantly negatively correlated with antibiotic concentrations in manured soil (P less then 0.05) due to the formation of covalent bonds and nonextractable residues. Soil silt content was significantly positively correlated with antibiotic concentration (P less then 0.05), which was attributed to greater sorption capacities. The ARG abundances were significantly positively correlated with soil silt content, antibiotic concentrations, mean annual temperature, SOC, MGEs and soil pH (P less then 0.05), suggesting that changes in these factors may shape the ARG profiles. Collectively, these findings advanced our understanding of the occurrence of antibiotics and ARGs in manure-amended soil and potential factors affecting them and will contribute to better management of these contaminants in future agricultural production.Facilitating reactive oxygen species (ROS) generation is an effective way to promote the heterogeneous catalytic efficiency for organics removal. However, the metal leaching in metal-based catalysts and the low activity of non-metallic materials restrict ROS production. In this work, the purpose was achieved by loading a small amount of spinel CuFe2O4 onto porous carbon nitride substrate. The synthesized CuFe2O4@O-CN composite first to activate peroxymonosulfate (PMS), which produce a plenty of ROS (•OH, SO4•- and 1O2) for organics removal, leading to highly oxidation for diverse organics. Through the comparative analysis of the surface composition before and after reaction, we found that the interface multi-electron transfer routs, including surface Cu(II)/Cu(I), Fe(III)/Fe(II) and their cross interaction, participated in the redox cycle, giving rise to the rapid and massive production of ROS, so that DMPO and TEMP were instantly oxidized in electron paramagnetic resonance (ESR) detection. Importantly, the carrier of porous O-CN, which acted as the electron transfer mediator, not only favors PMS adsorption via surface -OH, but also facilitates the conversion between different metal species. As a result, the CuFe2O4@O-CN/PMS system can remove 99.1% BPA and achieve 52.6% mineralization under optimized conditions. Thus, this study not only sheds light on the tailored design of heterogeneous catalyst for organics removal and elucidates the interfacial catalytic mechanisms for PMS activation.Hydrophobic organic pollutants (HOCs) in the complex groundwater and soil pose serious technical challenges for sustainable remediation. Herein, an asymmetric membrane (PCAM), inspired by the plant cuticle, was comprised of a top polydimethylsiloxane layer being selectively penetrable to HOCs from complex solution with humic acid, followed by transfer and catalyst layers with biochar pyrolyzed by 300 °C (BC300) and 700 °C (BC700). The PCAM triggered the advanced oxidation of the coming pollutant. The graphitized biochar layer of the PCAM acted as catalysts that induced HOC removal through a non-radical oxidation pathway. Compared to one type biochar membrane, the sequential multi-biochar composite membrane had a faster removal efficiency. The greater uptake and transport performance of multi-biochar composite membrane could be due to the larger pore size and distribution properties of PCAM physicochemical properties and oxidative degradation of peroxymonosulfate. The developed PCAM technology benefits from selective adsorption and catalytic oxidation and has the potential to be applied in complex environmental restoration.Boron (B) is an inimitable plant micronutrient, predominantly distinguished by super-narrow range between its deficiency and toxicity concentrations, which depends upon boron speciation in the growth media and form of living organisms. Moreover, the significant variations in its mobility amid different species, and distinctive inter and intra-species responses to extreme concentrations. Therefore, it is necessary to screen the bioavailability, speciation, biogeochemical cycling and exposure pathways of boron in the environment. The genes involved in the tolerance mechanism of boron in different plants were discussed in the current review paper. The functions related to scarcity and excess of boron concentration are assessed. The diverse plants implicated in phytoremediation of boron contaminated sites that restrict boron accumulation in food crops and health risks associated with soils containing deficit or surplus boron concentration were appraised. Ultimately, a summary of numerous strategies involved in the recovery and repair of boron-contaminated soils have been reviewed.Volatile organic compounds (VOCs) contamination may occur in subsurface soil due to various reasons and pose great threat to people. Petroleum hydrocarbon compound (PHC) is a typical kind of VOC, which can readily biodegrade in an aerobic environment. The biodegradation of vapor-phase PHC in the vadose zone consumes oxygen in the soil, which leads to the change in aerobic and anaerobic zones but has not been studied by the existing analytical models. In this study, a one-dimensional analytical model is developed to simulate the transient diffusion and oxygen-limited biodegradation of PHC vapor in homogeneous soil. Laplace transformation and Laplace inversion of the Talbot method are adopted to derive the solution. At any given time, the thickness of aerobic zone is determined by the dichotomy method. The analytical model is verified against numerical simulation and experimental results first and parametric study is then conducted. The transient migration of PHC vapor can be divided into three stages including the pure aerobic zone stage (Stage I), aerobic-anaerobic zones co-existence stage (Stage II), and steady-state stage (Stage III). The proposed analytical model should be adopted to accommodate scenarios where the transient effect is significant (Stage II), including high source concentration, deep contaminant source, high biodegradation capacity, and high water saturation. The applicability of this model to determine the breakthrough time for better vapor intrusion assessment is also evaluated. Lower first-order biodegradation rate, higher source concentration, and shallower source depth all lead to smaller breakthrough time.This study evaluated the synthesis of novel binary functionaladsorbent based on sporopollenin, magnetic nanoparticles, and polyaniline to produce MSP-PANI. find more The MSP-PANI was applied to enhance uptake of lead ions (Pb2+) from wastewater samples. The functionalities, surface morphology, magnetic properties, and elemental composition of the newly synthesized nanocomposite were investigated using Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FE-SEM), vibration sample magnetometer (VSM), and energy-dispersive X-ray spectroscopy (EDX), respectively. The experimental condition for the adsorption process was MSP/PANI ratio 11, pH ∼6, adsorbent dosage 40 mg, and contact time 90 min at room temperature. Under the proposed condition, lead ions removal were obtained as 83%, 88% and 95% for MSPE, PANI, and MSP/PANI, respectively. Based on the experimental and predicted data, the adsorption was corresponded to the psudo-second-order (R2 = 0.999) kinetics model, and the adsorption equilibrium corresponded to the Langmuir model (R2 = 0.996). Langmuir isotherm showed the maximum adsorption capacity of MSP-PANI for lead ions was 163 mg/g and followed the monolayer pattern. Hence, thermodynamic model under Van't Hoff equation suggested that the adsorption mechanism was physio-sorption with endothermic nature. Therefore, this research can help the researchers to use magnetic nanoparticles for lead removal in highly polluted areas.The use of biological processes for the treatment of asbestos cement waste (ACW) has gained interest in recent years. Nevertheless, this methodology is not yet consolidated because of the incomplete ACW conversion during the biological treatment and the consequent need for further treatments that generally require a high amount of energy and chemicals. In this study, the efficiency of both mesophilic and thermophilic dark fermentation (DF) fed with glucose in fed-batch conditions was assessed for ACW biological treatment. Both thermophilic and mesophilic DF of glucose resulted in a partial conversion of glucose into organic acids that successfully degraded all the asbestos fibers contained in an ACW sample. A hydrogen-rich biogas was produced as well at the end of the mesophilic DF treatment 0.14 LH2 gglucose-1 were obtained. In addition, the anaerobic digestion (AD) of the DF supernatants led to the production of 0.38 LCH4 gCOD-1.The per- and polyfluoroalkyl substances (PFASs) are substantially produced and applied in industrial and domestic products, which have recently aroused great public concern for their potential toxicity to humans. In the present study, raw milk (n = 107) and cow feed samples (n = 70) were collected across nine Chinese provinces, in order to investigate the occurrence of PFASs in milk and feed, and the human exposure risk to milk. The concentrations of PFASs are in the range of 0.05). However, feeds collected around fluorination production area show relatively higher PFAS levels than those from other areas, which also increase PFAS levels in milk. Risk assessment of PFASs through milk consumption is carried out according to evolving reference doses (RfDs). The hazard quotient is more than one for both adults and children when the strictest RfDs are applied. The Monte Carlo Simulation shows that children face higher PFAS exposure risk than adults.Most drinking water treatment residuals (DWTRs) with rich metal resources are landfilled directly without treatment, which results in wasted Al/Fe resources. This work proposes a new method of preparing Mg-Al-Fe Hydrotalcite-like compounds (MAF-HTCLs) by recycling DWTRs as the raw material to selectively adsorb anions in the waste water. In this study, MAF-HTCLs were prepared by the coprecipitation method with recycled DWTRs. The characterizations and adsorption of MAF-HTCLs were studied for the selective adsorption of P, Cr, F, and Br. The adsorption capacity was increasing as the value of pH decreased. For kinetic adsorption, the pseudo-second-order model fit better, and two isotherm models (the Langmuir and Freundlich models) described the isotherm results well. According to the Langmuir model, the maximum adsorption capacities of P, Cr, F, and Br were 55.2, 34.9, 16.84, and 13.9 mg/g, respectively. Based on the results of characterizations before and after adsorption, adsorption mechanisms of Cr, F, and Br were proposed, including physicochemical adsorption, surface complexation, and ion exchange, in which ion exchange was dominant.