Freemansejersen6154

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Results We observed a moderate log-linear association between viticulture density and the incidence of AL, with a 3% increase in SIR for a 10% increase in viticulture density (SIRR = 1.03; 95%CI [1.00-1.06]). The association remained for lymphoblastic AL but not for myeloid AL. The association was stable after stratification by geographic area, age and period, and after adjustment on UV radiation and a French deprivation index. No consistent association was observed for other crop types. Discussion This nationwide study shows a moderate increase in incidence of childhood AL in municipalities where viticulture is common. Future individual studies are needed to know whether this observation is confirmed and related to particular use of pesticides.Concentration, composition and sources of polycyclic aromatic hydrocarbons (PAHs) in kitchen depositions from different sampling categories such as restaurants, university mess and houses were investigated, and associated human exposure risk through dietary intake, inhalation and dermal contact was determined. The PAHs in the samples were extracted by supramolecular solvent based microextraction (SUPRAS) method and the concentrations were determined by high pressure liquid chromatography (HPLC) with fluorescence detection. The mean of Σ16PAHs concentration was found to be the highest (386.09 ± 413.17 mg kg-1) for restaurants followed by mess (80.91 ± 92.81 mg kg-1) and houses (24.65 ± 10.52 mg kg-1). Traffic sources were found to be predominant contributors of PAHs in restaurants while cooking activities were the sources for mess and houses. Three- and five-ring PAHs were prominent in restaurants and mess samples while two- and three-ring PAHs contributed the most in houses samples. Non-cancer risk (hazard index) from exposure to these PAHs was found to be within safe limits i.e. 2.70E-09 to 7.46E-08. Estimated lifetime cancer risk was found to range from 2.46E-06 to 7.81E-04 from exposure to these PAHs and indicates significant risk due to exceeding the guideline value of 10-6.In this work, a novel cascade system (i.e., SnTCPP/g-C3N4/Bi2WO6) is successfully constructed using stannum (II) meso-tetra (4-carboxyphenyl) porphyrin (SnTCPP) as the key photovoltaic agent for the first time. Visible light driven photocatalytic experiments indicated that wt. MEDICA16 molecular weight 12% SnTCPP and 30% Bi2WO6 codecorated g-C3N4 demonstrates the highest photodecomposition capabilities for levofloxacin and rhodamine B, achieving 85.64% and 93.64% degradation rates, respectively. The dramatically enhanced photocatalytic performance mainly raised from the synergetic co-effects among SnTCPP, g-C3N4 and Bi2WO6, including i) the incorporation of SnTCPP extends the visible light response of the binary Bi2WO6/g-C3N4 heterojunctions, resulting in the highly efficient visible light harvesting; ii) we find that the g-C3N4 not only serves as a promising supporter to trap electrons from Bi2WO6, but also as an interfacial electron-hole pairs transfer moderator, like "volleyball setter" to facilitate the charges transfer between Bi2WO6 and SnTCPP. The presence of the "setter" endows a cascade system for boosting the photodegradation efficiency of levofloxacin and rhodamine B. This study provides a promising design strategy to construct efficient g-C3N4 based heterojunctions suitable for removing pharmaceutical antibiotics and hazardous dyes from various real wastewaters.Sewers may affect the characteristics and bacterial communities of wastewater, and need be studied as they may impact treatment facilities and recycling operations. In this study, the wastewater characteristics and bacterial communities from the inflow and outflow of two sewers (sewage and greywater) were analyzed. The chemical oxygen demand was significantly reduced in the sewage and greywater sewer and the greywater sewer generated less sulfide and methane. Proteobacteria, Bacteroidetes, and Firmicutes as the major phyla in sewage and greywater and sewer biofilms. Sewer conveyance caused changes in the distribution and community interaction of suspended bacteria. Greywater contained abundant water-related pathogenic bacteria (WPB) and some WPB (e.g. Aeromonas, Klebsiella and Shigella) number in greywater were not lower than sewage. Sewers could increase the number of Shigella in sewage and decrease the number of Acinetobacter in greywater. Further treatment or disinfection of greywater collected by sewers was necessary and directly reuse of greywater without treatment should be avoided.Emerging industrial hubs have resulted in soil and dust pollution by trace elements, being a potential source and pathway for human exposure to nearby cities. The aim of this study was to determine the spatial distribution, levels, sources and health risk assessment of metals and arsenic in soils of Arak industrial area, Iran. A total of 235 topsoil (0-5 cm) samples were collected from the vicinity of Arak, and the concentrations of As, Zn, Ni, Pb, Cu and Cd were 152, 104, 93, 38, 14 and 1.2 mg kg-1, respectively, and exceeded the background values, with the exception of Cu. Values of pollution indexes revealed that most of the soils are especially enriched by As and Cd. Multivariate statistical analysis showed that Pb and Zn originated from common anthropogenic sources related to industrialization and mining, whereas Cu and Ni are probably associated with geological sources. Cd was mainly derived from the input of agricultural and industrial activities, and As should be attributed to residues in mining. Spatial risk maps showed the high risk of trace elements pollution in the order of As (100%) > Cd (62%) > Ni (12%) > Pb (5%) > Zn (4%) > Cu (0%). The results of the noncarcinogenic risk assessment showed that chronic daily intake in children and adults for ingestion pathway was higher than for dermal contact and inhalation. Values of hazard index (HI) for trace elements were below the safe level (HI ≤ 1), indicating that no noncarcinogenic risk threaten children and adults. Likewise, the total carcinogenic risk of Cd in both groups is less than the EPA threshold (1 × 10-6), indicating a low carcinogenic risk, however As (1 × 10-6 to 1 × 10-4) indicates an acceptable risk.

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