Christiansendamm7867

9% and 0.5% from rainfall and of 59.3% and 76.1% from snowmelt, and a decrease of 7.6% and 4.5% in total system discharge, but also generates an isotopic enrichment in groundwater discharge (δ18OGW) of 0.50‰ and 0.84‰, respectively. Moreover, from a long-term (2010-2100) perspective, the mean trend in δ18OGW is 0.7‰/100 yr and 1.2‰/100 yr for RCP4.5 and RCP8.5, respectively, resulting in easily measurable annual lapse rates with the current analytical methods.In the remediation of Cr(VI)-contaminated soils, the effectiveness and long-term stability are critical qualities for the selection of a reductant. In current engineering practices, iron-based materials and sulfides are the most prevalent reductants, and calcium polysulfide (CaS4) is considered as the one with the highest effectiveness and strongest long-term stabilization ability. But this opinion is questioned by the high interference ability of CaS4 to soil Cr(VI) analysis. This study provides a pretreatment method to eliminate the interference of residual ferrous and sulfides to soil Cr(VI) analysis. By this pretreatment method and comparing with FeSO4 and Na2S, the mechanisms of the false high effectiveness and strong long-term stabilization ability of CaS4 is revealed. In the remediation process, CaS4 produces much elemental sulfur (S0) which remains in the soils. During the alkaline digestion, the S0 generates polysulfide which reduces the extracted Cr(VI), inducing serious negative analysis bias. When this negative bias is eliminated by pretreatment method, analysis results show that CaS4 exhibits lowest effectiveness. The S0 cannot be leached away from soils and oxidized by oxygen under natural conditions, this makes CaS4 exhibit a persistent interference ability, which is mistaken for a strong long-term stabilization ability.Biochemical methane potential (BMP) assays are widely used to assess feedsocks in oder to control the process of biogas production. see more However, the continuous evaluation of feedstocks using a BMP assay is expensive, time-consuming and challenging. In this study, Fourier transform mid-infrared photoacoustic spectroscopy (FTIR-PAS) was used to predict the BMP values of 87 urban organic waste (UOW) samples derived from different sources in Denmark. The developed model of BMP prediction showed a coefficient of determination (R2) of 0.86 and a root mean square error (RMSE) of 59.3 mL CH4/g VS in prediction. The interpretation of the regression coefficients used in the calibration showed a positive correlation with BMP for relatively easily degradable compounds, such as aliphatics, most likely lipids and amides most likely in proteins, while a negative correlation was found with lignin and hemicellulose.Perfluoroalkyl acids (PFAAs) are a group of synthetic persistent chemicals with distinctive properties, such as a high thermal and chemical stability, that make them suitable for a wide range of applications. They have been produced since the 1950s, resulting in a global contamination of the environment and wildlife. They are resistant to biodegradation and have the tendency to bio-accumulate in organisms and bio-magnify in the food chain. However, little is known about the bioaccumulation of PFAAs in terrestrial invertebrates, including how they affect the physiology and particularly oxidative status. Therefore, we studied the bioaccumulation of PFAAs in snails that were exposed for 3 and 6 weeks along a distance gradient radiating from a well-known fluorochemical hotspot (3M). In addition, we examined the potential effects of PFAAs on the oxidative status of these snails. Finally, we tested for relationships between the concentrations of PFAAs in snails with those in soil and nettles they were feeding on and the influence of soil physicochemical properties on these relationships. Our results showed higher concentrations of PFOA and/or PFOS in almost every matrix at the 3M site, but no concentration gradient along the distance gradient. The PFOS concentrations in snails were related to those in the nettles and soil, and were affected by multiple soil properties. For PFOA, we observed no relationships between soil and biota concentrations. Short-chained PFAAs were dominant in nettles, whereas in soil and snails long-chained PFAAs were dominant. We found a significant positive correlation between peroxidase, catalase and peroxiredoxins and PFAA concentrations, suggesting that snails, in terms of oxidative stress (OS) response, are possibly susceptible to PFAAs pollution. CAPSULE We observed a positive correlation between the levels of PFAAs and the antioxidants peroxidase, catalase and peroxiredoxins in snails, exposed on nettles grown at contaminated sites.Wastewater-based epidemiology (WBE) approaches to detect SARS-CoV-2 in municipal wastewater can provide unique information on the incidence or prevalence of COVID-19 in community. However, there are several technical challenges coupled with sewage sampling for SARS-CoV-2, including intermittent shedding of viruses, sampling time, volume, and frequency. Sampling schemes thus may need to be tailored to reach out highly sensitive, accurate, and reliable results. Herein, we compared the accuracy and threshold cycle (Ct) profiles of SARS-CoV-2 in Moore swabs, composite (16-h), and grab samples taken from sewage manholes (n = 17) at the Middle Eastern city of Tehran, Iran, on two occasions (November 2020 and May 2021). Samples were concentrated by polyethylene glycol precipitation and the corresponding Ct values for CDC 'N' and 'ORF1ab' assays were derived by means of real time RT-qPCR. Overall, the Moore swabs performed equal to samples composited over 16 h for qualitative monitoring, and 34/34 (100%) were positive for SARS-CoV-2. The 'N' assay showed the highest detection frequency as compared to 'ORF1ab'. The mean Moore swab Ct profiles were more consistent with 16 h composite sampling as compared with corresponding grab samples, providing hints as to the best sampling protocol to adopt when planning a sewage monitoring campaign particularly under WBE. Furthermore, our analyses on local differences showed somewhat higher virus copy numbers in the southern areas. The experimental design of this study revealed that the Moore swab and composite samples are more sensitive than grab samples, suggesting that the collection of grab samples may be inappropriate for characterizing total number of viral RNA copies in sewage samples. Given the transiently presence of human host-restricted infections such as SARS-CoV-2 and the simplicity and affordability of Moore swab, the method is well suited for disease surveillance in resource poor regions struggling with limited capacity for clinical testing.This study sheds light on the occurrence of emerging pesticides and their transformation products (TPs) in an urban river in Beijing that is mainly supplemented with treated wastewater. To this end, suspect and non-target screening was conducted using a database of 557 commercial pesticides and over 1400 predicted TPs. Finally, 30 pesticides and 20 TPs were identified, with 12 pesticides and 10 TPs detected in all samples. Eleven pesticides and 17 TPs were detected in Beijing for the first time. Among these, 18 compounds were confirmed using authentic standards. Concentrations of the confirmed and suspected compounds were determined by quantification and semi-quantification, respectively, based on 18 authentic standards. Fungicides and their TPs constituted the largest group and exhibited the highest total concentration (26 compounds; 52.2 μg/L), followed by insecticides (14 compounds; 51.3 μg/L) and herbicides (10 compounds; 24.5 μg/L). DEET, carbendazim, prometryn, ω-carboxylic acid, 2-aminobenzimidazole, metolachlor TP, hexaconazole TP, metalaxyl TP, and azoxystrobin TP exhibited relatively high mean concentration (>100 ng/L). Among the 20 TPs, approximately 65% showed higher concentrations than their parent compounds. Correlation analysis revealed that 6 pesticides and 10 TPs in the river were mainly contributed by the discharge from a wastewater treatment plant. Although a majority of the emerging pesticides had low toxicity, 10 pesticides exhibited high risks to aquatic systems, especially invertebrates.Large quantities of strobilurin fungicides (SFs) are used worldwide, resulting in adverse effects on non-target organisms. SFs affect the reproduction and embryonic development of aquatic organisms, while the impact on soil organisms has been insufficiently researched. Therefore, we investigated the effects of three SFs (azoxystrobin (AZO), pyraclostrobin (PYR), and trifloxystrobin (TRI)) on the survival, reproduction, and hatching success of the non-target soil oligochaete Enchytraeus crypticus. The standard enchytraeid reproduction test (ERT) showed that, regarding survival, TRI (LC50 = 2.34 mg/kg) was the most toxic, followed by PYR (LC50 = 4.26 mg/kg) and AZO (LC50 ≥150 mg/kg). Reproduction was affected in the same order (TRI EC50 = 0.045 mg/kg, PYR EC50 = 1.85 mg/kg, and AZO EC50 = 93.10 mg/kg). Exposure to AZO and PYR showed a negative impact on hatching success with a significant increase in the number of unhatched cocoons. Prolonged hatching test was consequently carried out. As a result, a hatching delay was observed at lower AZO and PYR concentrations, while at higher concentrations hatching was completely stopped as the cocoons were no longer viable. Hence, hatching test enabled a discrimination between hatching delay and hatching impairment. Besides demonstrating the adverse effects of AZO, PYR, and TRI on the survival, reproduction, and hatching success of E. crypticus, the obtained results indicate the convenience of using several endpoints in reproduction tests. The usage of prolonged hatching tests and monitoring of hatching dynamics could fill the gap between standard reproduction tests and multigeneration tests and allow a better understanding of the adverse effects on reproduction.Environmental stress can affect sperm traits whose changes have been reported to be associated with extra-pair fertilization (EPF) level in natural animal populations. However, little is known regarding how exposure to environmental heavy metals influences sperm traits and EPF level in free-living bird populations. In a previous study, we found that a tree sparrow (Passer montanus) population that has been exposed to heavy metal pollution over 60 years (Baiyin, BY) exhibits increased sperm quality compared with a population from a relatively unpolluted area (Liujiaxia, LJX). The high sperm quality could be related to extra-pair mating rates. Therefore, the present study investigated EPF level (the ratio of extra-pair offspring) in tree sparrow populations from BY and LJX, and analyzed the relationship between sperm traits (morphology, velocity and quantity) and EPF success. EPF success of tree sparrows was significantly correlated with their sperm velocity (p = 0.048) and total sperm length (p = 0.045), indicating that these sperm traits were important for EPF success. Tree sparrows from the BY population produced longer sperm with lower head/flagellum ratio and faster swimming sperm and showed a significantly higher EPF level than conspecifics from LJX. Thus, adaptive variation of sperm characteristics was related to the high EPF level in tree sparrows under long-term environmental heavy metal pollution. The findings are of scientific significance for exploring the evolution of mating tactics in wild bird populations under environmental stress.