Cahillconner3801

Further important policy implications for the 10 countries with the highest military expenses are provided at the end of the paper.This study focuses on the preparation of sodium alginate-coated iron-carbon granules (FeCGs) and their capacity to remove ibuprofen (IBU) by combining Fenton and ultrasound technologies. The preferred preparation conditions are as follows 2% (w/v) sodium alginate, 10% (w/v) iron fillings and biochar, and used CaCl2 as the cross-linking agent. 74.72% of IBU was removed by ultrasound/FeCG under 10 g/L FeCG and 250 W ultrasound power. Fenton/FeCG could remove 92.41% of IBU under 10 g/L FeCG and 2 mM H2O2. Under the above experimental conditions, ultrasound/FeCG has higher reaction speed (9.44 × 10-3 min-1) than Fenton/FeCG (4.95 × 10-3 min-1). However, Fenton/FeCG could remove more TOC than ultrasound/FeCG. During the reaction using the Fenton/FeCG system, 11 degradation intermediates were detected, but only 7 intermediates were produced by the ultrasound/FeCG system. A common single-chain product C5H10O3 formed by IBU degradation was detected in the reaction products during Fenton/FeCG reaction, which benzene ring structure was destroyed; however, the minimum molecular weight of the product detected using the ultrasound/FeCG system was that of C8H10O; the benzene ring structure of IBU is not destroyed. This study provides guidance in the preparation of sodium alginate-coated FeCGs, evaluating the applicability of Fenton/FeCG and ultrasound/FeCG, which was meaningful for organic pollution wastewater treatment.The big data revolution has created data center sustainability problems, whose solutions require the consideration of environmental factors. The purpose of this study is to establish a big data center sustainability evaluation index and provide guidance for sustainable data center construction. This research formulated a big data center sustainability evaluation model that integrates multiple-criteria decision-making methods based on the analytic network process and fuzzy technique for order preference by similarity to an ideal solution (TOPSIS). Furthermore, a case study was used to examine the proposed model. The refrigeration system, layout and ventilation, data center location, data volume, and server power consumption are the five most crucial factors in determining the sustainability level of a big data center. The areas that require further development are the balancing of tasks on different IT equipment, renewable energy use, and waste heat utilization. This research provides a method or guide that can be used by managers when they build new big data centers or upgrade and optimize existing big data centers to make them more sustainable. This study is the first to assess the sustainability of a big data center according to multiple criteria decision-making methods, in which fuzzy theory is applied to evaluate the imprecise and subjective judgments of decision-makers. This study provides a systematic evaluation framework that is based on qualitative and quantitative criteria and comprises the four factors of big data level, equipment level, room level, and data center level. Big data is new oil, but it is not clean oil. It is both a vital driver of economic growth and a source of environmental damage. We need to ensure that big data centers are run in a sustainable way.Coal-based mercury pollution from power plants has received increasing attention. In a previous study, high iron and calcium coal ash (HICCA) was found as a promising oxygen carrier (OC) for chemical looping combustion (CLC). The purpose of this study was to investigate the catalytic effect of HICCA on Hg0 removal as well as the impacts of several gas impurities, such as HCl, SO2, and NO. Experiments on Hg0 removal efficiencies for different atmospheres were performed in the fixed-bed reactor at 850 °C. Based upon the characterization of BET, SEM, XRD, XPS, and EDS of reaction products, the reaction mechanisms of different gases with the HICCA samples were established. The mechanisms were further explained using the thermodynamic equilibrium calculations. The experimental results showed that the Hg0 removal efficiency using HICCA was 11.60%, while the corresponding value in the presence of 50 ppm HCl was 90.46%. Hg0 removal by HICCA involving HCl is mainly attributed to homogeneous reaction between Hg0 and HCl as well as the formation of reactive species (Cl, Cl2, Cl2O, O, S, and SCl2) through the reactions of HCl with Fe2O3 and CaSO4 in HICCA. The formation of C-Cl bond is not the main pathway for the promotional effect of HCl on Hg0 removal. GDC-0449 concentration SO2 played a negative role in Hg0 removal by HICCA. The inhibition of SO2 may be attributed to its effect on the reduction of Fe2O3 and its bonding with C-O, COOH, and C(O)-O-C. NO enhanced Hg0 removal by HICCA primarily through the homogeneous reactions of Hg0 with N2O and O. In addition, NO also interacted with HICCA and promoted the heterogeneous oxidation of Hg0 by producing more C-O, C=O, and COOH/C(O)-O-C on HICCA surface. This study proved the effectiveness of HICCA on Hg0 removal in iG-CLC and revealed the mechanisms of the interaction between HCl/SO2/NO and MxOy/CaSO4 as well as carbon-oxygen groups.Eutrophication is one of the environmental problems arising from the increase of essential nutrient concentrations, mainly phosphorus and nitrogen. In contrast to excess phosphorus, the depletion of phosphate rock deposits used for the production of fertilizers compromises the food supply. Therefore, the development of technologies that propose the recovery of the phosphorus contained in eutrophic environments for its later use for agricultural fertilization purposes is very important to ensure global food security. This work aimed to evaluate the toxic potential of the sawdust (biosorbent previously used for phosphorus adsorption) in order to enable its application in agriculture. For this, toxicity experiments with Lactuca sativa (lettuce) and Allium cepa (onion) seeds were performed. The phytotoxic potential was assessed by means of the seed germination index and physiological parameters such as radicle and hypocotyl growth. Cytotoxicity, genotoxicity, and mutagenicity tests were also performed on onion seeds.