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When adolescents encounter problems, many prefer to seek help from a friend or a parent and some are reluctant to seek help from anyone. Yet information is sparse about how youth who choose each of these options differ from one another, including the proportions who select each help option consistently across personal and interpersonal problems or the extent to which they endorse characteristics related to help seeking. To address this gap, the proportions of adolescents who selected a friend, a parent, or no one as their first choice for help with one personal problem (feeling depressed) and three interpersonal problems (problems with a parent, a good friend, and a boyfriend/girlfriend) and the proportions who selected each help option consistently across these problems were examined. Youth in the three groups for each problem were also compared on characteristics linked to help seeking (gender, self-concealment, self-disclosure, perceived support, and school community). Participants were 488 Canadian adolescents (56% girls; Grades 9-12) who completed a survey at school. A majority of youth chose a friend for help with each problem and a substantial minority chose one help option consistently across problems. For each problem, adolescents in the Friend group and those in the Parent group differed on composites of specific characteristics, and adolescents in the No One group differed from those in the other groups on multiple characteristics. The results highlight the complexity associated with adolescents choosing a help option and draw attention to specific groups of youth who merit further examination.Chromium is an essential element that is required for the normal physiology but can be toxic to humans above a certain level. In spite of growing interest in research on chromium exposure to human health consensus about its effect on human, semen quality has not been achieved. The aim of the present study is to evaluate the impact of chromium exposure on semen parameters. A total of 760 males attending andrology laboratory of Tongji Hospital, Wuhan, for routine semen analysis were enrolled and requested to provide semen and urine samples. The urine level of chromium was evaluated using inductively coupled plasma mass spectrometry (ICP-MS), and computer-assisted semen analysis (CASA) was applied to examine semen parameters. Associations between semen parameters and urinary chromium were analyzed by means of multivariate linear regression analysis. Multivariate analysis showed a negative association between the urinary concentrations of chromium and progressive motility (β = - 0.014, p = 0.040) and total motility (β = - 1.077, p = 0.048), while other semen parameters did not show any statistically significant changes. Urinary chromium could influence semen quality parameters and impair male fecundity.In the present study, fermentative production of bacterial nanocellulose (BNC) by using Komagataeibacter xylinus strain SGP8 and characterization of nanocellulose is presented. The bacterium was able to produce 1.82 g L-1 of cellulose in the form of pellicle in standard Hestrin-Schramn (HS) medium. The morpho-structural characterization of the BNC using scanning electron microscopy (SEM) and X-ray diffraction (XRD) studies, respectively revealed nanofibrillar structure and high crystallinity index (~86%). Captisol The thermogravimetric analysis (TGA) showed the stability of BNC up to 280 °C, further rise in temperature to 350 °C results in depolymerization of the sample. In order to show the applicability of produced BNC, it was modified first using calcite (CaCO3) and thereafter characterized using SEM, XRD, FTIR, and TGA studies. The BNC-CaCO3 composites as a sorbent resulted in >99% removal of initial 10 mg L-1 of Cd (II) at pH 5, 7 and 9 after 12 h of treatment. Moreover, the composite was also found to be competent in removing high concentrations of Cd (25 and 50 mg L-1) from the solution (69-70%). Overall, the above results suggest that cellulose produced by K. xylinus strain SGP8 showed excellent material properties, and modified BNC (BNC-CaCO3 composite) could effectively be used for remediation of toxic levels of Cd from the contaminated system.Over the last 10 years, there has been a plethora of experimental studies estimating the potential of microplastic particles (MPs) to exert toxic effects in the environment, many specifically focusing on their postulated capacity to enhance the transfer of environmental pollutants into organisms after ingestion. Obviously, there is little to no consensus on appropriate experimental design, which is mainly owing to the novelty, the interdisciplinarity of the subject, and the complexity of parameters involved. This results in fundamental discrepancies regarding the materials applied, the approach for spiking MPs with pollutants, and the exact exposure scenario. Aiming for a non-chemist audience and providing illustrative, representative, and comparative examples, this review first outlines the theoretical essentials of processes involved in sorption. Also, it discusses the implications for designing experimental approaches using MPs and interpreting the results obtained under consideration of their relevance for environmental conditions. It may help to improve the interpretation of studies on MP toxicity already published, while also calling experimenters' attention to various aspects important to consider when designing and performing environmentally relevant experiments with MPs.In this study, the mud-phosphorus slurry was used to simultaneously remove SO2 and NOx. The technology proposed new avenues for the purification and utilization of remove SO2 and NOx in flue gas. The effects of reaction temperature, solid-liquid ratio, and oxygen content on the efficiency of desulfurization and denitrification were studied experimentally. Results show that the parameters were solid-liquid ratio of 5.0 g/40 mL, T = 60 °C, φ (O2) = 20%, Q = 300 mL/min under the best experimental conditions. The maximum amount of ozone generated was 563.8 mg/m3. The reaction time with desulfurization rate ≥ 99% was 340 min; the reaction time with denitrification rate ≥ 99% was 160 min. Response surface analysis method was used to perform a three-factor three-level response surface experiment. Results show that the oxygen content had a highly significant effect on the desulfurization and denitrification efficiency, and the relationship between the desulfurization and denitrification efficiency was oxygen content > mud-phosphorus slurry liquid-solid ratio > reaction temperature. The process is simple, the solid waste is used to treat the flue gas, and the removal effect is good, which is convenient for popularization.The present study explored an efficient technoeconomic method for treating intensely colored dyeing effluents from a commercial source. Firstly, the adsorption efficacy of jute fiber (JF) was enhanced through grafting with tannin, a natural polyphenol, via incorporation of active epoxy groups by epichlorohydrin onto fiber surface. The effect of different experimental parameters (e.g., initial pH, adsorbent dose, temperature, and contact time) on extent of color removal was evaluated performing batch studies. A full factorial central composite design (CCD) in response surface methodology (RSM) was applied to optimize the decolorization process for achieving maximum color removal (99.5%) at pH 4.9, adsorbent dose 11.8 g/L, temperature 30 °C, and time of contact 117.8 min. The isotherm and kinetic studies of the process revealed that Langmuir model and pseudo-second-order model provided best fit, yielding high correlation coefficients (R2 > 0.997). Significant desorption (76%) of the spent adsorbent by 0.1 M NaOH solution suggested that this tannin-modified JF can find a prospective practical application as a novel, inexpensive, and potential bioadsorbent to treat the dyeing effluent.Air pollution assessment in the Tropical Andes requires a multidisciplinary approach. This can be supported from the understanding of the underlying biological dynamics and atmospheric behavior, to the mathematical approach for the proper use of all available information. This review paper touches on several aspects in which mathematical models can help to solve challenging problems regarding air pollution in reviewing the state-of-the-art at the global level and assessing the corresponding state of development as applied to the Tropical Andes. We address the complexities and challenges that modelling atmospheric dynamics in a mega-diverse region with abrupt topography entails. Understanding the relevance of monitoring and facing the problems of data scarcity, we call attention to the usefulness of data assimilation for uncertainty reduction, and how these techniques could help tackle the scarcity of regional monitoring networks to accelerate the implementation and development of modelling systems for air quality in the Tropical Andes. Finally, we suggest a cyberphysical framework for decision-making processes based on the data assimilation of chemical transport models, the forecast of scenarios, and their use in regulation and policy making.Polluted sterilization condensate discharged from palm oil mill may contain polyphenols that are rich in the antioxidant property. Emulsion liquid membrane (ELM) process is a promising method for polyphenol recovery due to its several attractive features such as high selectivity, simple operation, and low energy consumption. In this study, the condensate was characterized to determine its total phenolic content (TPC), ionic elements, and pH. ELM formulation containing tributylphosphate (TBP) as a carrier, kerosene as a diluent, sorbitan monooleate (Span 80) as a surfactant, and sodium hydroxide (NaOH) as a stripping agent was developed. The results show that sterilization condensate contains 700-1500 mg GAE/L of TPC. During the ELM process, more than 91% of extraction with 83% recovery and 8.3 enrichment were achieved at the favorable condition of 0.1 M TBP, external phase pH 5, 1 M NaOH, 15 treat ratio, 5% v/v of octanol as a modifier, and 100 mg GAE/L external phase concentrations. Thus, ELM offers a potential alternative technology to extract and recover polyphenols from palm oil mill sterilization condensate while contributing to sustainable production. Graphical abstract Extraction of polyphenols from palm oil mill sterilization condensate using ELM process.India is an agrarian country producing a large amount of rice straw as an agricultural residue. These residues are burnt openly leading to severe environmental pollution and health hazards. Among several options available, anaerobic digestion of rice straw into biomethane gas and digestate is a promising technology. The current paper reviews the characteristics, principles of rice straw and the process variables (temperature, volatile fatty acids, and pH, carbon to nitrogen ratio, metal elements and organic loading rate) that affect the performance of the rice straw digestion and process strategies which may alleviate the barriers and may improve the biomethane yield. Co-digestion of rice straw with nitrogen-rich substrates is proven to be an effective way to balance the carbon to nitrogen ratio, in turn, leads to nutrient balance and enhance the biomethane yields of anaerobic co-digestion system. Moreover, pretreatment is another effective strategy; physical, chemical and biological pretreatments are reviewed in the article which improved the performance of digester.

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