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35 to 15.93 GPa and from 19.66 to 60.94 GPa at 1100 °C and 1200 °C respectively. The environmental study of the incorporation of GMR in ceramic matrix, rich in heavy metals (Fe, Zn, Ni), was evaluated by leaching tests of the fired products. The results indicated a successful immobilization of the heavy metals. These results suggested the use of gold mining reject in the ceramic field, as a substituent of feldspar, and might be an alternative and reliable method for the disposal of this reject.Wheat is the second most important food crop worldwide, which is prone to accumulate cadmium (Cd). Accumulation of Cd in wheat grains depends not only on wheat genotype, but also largely on the availability of soil Cd and its internal distribution. In this study, several experiments were used to achieve low-grain Cd content a field trial for wheat genotype screening, a soil incubation experiment to test passivation effect of bamboo biochar on soil Cd, and a soil pot experiment to examine bamboo biochar effect on wheat grain accumulation. The results showed that of the 243 wheat cultivars tested, the variation range of grain Cd content was 0.365-1.243 mg/kg, in a field with soil Cd of 3 mg/kg. The application of bamboo biochar reduced soil Cd availability, among which 5.0% bamboo biochar treatment had the greatest effect. The content of available Cd in soil treated with 5.0% bamboo biochar decreased by 0.32 mg/kg compared with the control in a 120-day incubation experiment. Effect of bamboo biochar (0, 0.1%, 1.0%, and 5.0%) on reducing grain Cd content in two wheat genotypes (Mianyou-1 and 1279-9) was investigated. The application of bamboo biochar decreased Cd uptake by plants, while distribution of Cd in different wheat plant parts was more controlled by the plant genetic characteristics. Compared with the control, Cd content in roots, straw, and grains was decreased by 34.06% (P  less then  0.05), 21.57%, and 23.33%, respectively, in low-grain Cd wheat cultivar 1279-9 by 5% bamboo biochar application. Overall, the combination of low-grain Cd accumulation wheat and bamboo biochar may be a feasible strategy to lessen grain Cd accumulation in Cd-contaminated soils.Tourism activities have brought overexploitation of natural ecotourism resources and ecological pressure challenge though it exactly contributes to the economic prosperity of a region. Research on tourism ecological safety is of great importance for tourist destinations to balance the relationship between environmental protection and tourism development. Qilian Mountains National Park (QMNP) has a prominent ecological status and is a vital ecological barrier in the northwest of China, which attracts large numbers of tourists every year for its rich tourism resources in the Zhangye (ZY) region. However, there is still a lack of systematic research on the environmental impact of tourism activities and on achieving sustainable development of ecotourism in national parks. We took QMNP-ZY as the study object, establishing the system of indicators based on the PSR model for the comprehensive evaluation of tourism ecological safety and the diagnosis of the main obstacles. Moreover, the autoregressive integrated moving average (ARIMA) model was introduced to forecast the evolutionary trends of tourism ecological security in QMNP-ZY. The results showed that (1) The tourism ecological security composite values of the QMNP-ZY exhibited a "U"-type evolution of "first fall-then rise" feature, and the pressure layer gradually became the dominant factor. (2) For the main barrier factors, there had been a shift from response factors. (3)The output of the ARIMA model demonstrated that the level of tourism ecological security would rise in a short period and then decline a few years later. Especially, the contribution degree of economic to the tourism eco-security development will weaken with the region's economy growing.Vapour-liquid equilibrium (VLE) of CO2 in aqueous dipropylenetriamine (DPTA) is investigated experimentally using a stirred equilibrium cell setup. Equilibrium solubility of CO2 is measured in the temperature and pressure range of (313-333) K and (1-100) kPa respectively. Composition of aqueous DPTA solvent used for the absorption study is in the range of (5-15) mass%. Experimental data shows higher CO2 loading capacity of this solvent compared to conventional solvents like monoethanolamine (MEA), 2-amino-2-methyl-1-propanol (AMP), and N-methyldiethanolamine (MDEA) as well as recently developed polyamine solvents like aminoethylethanolamine (AEEA), piperazine (PZ), and hexamethylenediamine (HMDA). Experimental VLE data is then correlated using the electrolyte non-random two-liquid (e-NRTL) theory which is an activity coefficient-based model for the electrolyte system. Data regression system (DRS) in Aspen Plus® (V8.8) is employed to fit the e-NRTL model equation with the experimental data by regressing the model parameters. Model-predicted data is found to be in good agreement with the experimental VLE data with an average absolute deviation of 22.3%. read more Performance of aqueous DPTA solvent is also analysed by predicting solvent capacity, equilibrium liquid-phase speciation, and heat of CO2 absorption using the newly developed e-NRTL model for the investigated system.Fly ash, a result of coal burning in thermal power plants, is sustainably used in agriculture and has been regarded as a problematic solid waste worldwide. The presence of some desired nutrients (macro and micro) and its porosity makes it a marvelous soil amendment for plant growth and development. The present study was done to evaluate the effect of different fly ash levels on pumpkin crop (Cucurbita moschata). Pot experiment in randomized block design was conducted with different fly ash supplement treatments to analyze the impact of fly ash on growth, chlorophyll, carotenoid, biochemical parameters, and pumpkin crop yield. The results show variation in soil's physical and chemical properties after the application of fly ash (30 and 50%). Also, the lower levels (10-30%) of fly ash amended soil significantly (P ≤ 0.05) enhanced the growth (plant height, plant fresh and dry biomass, no. of leaves, and average area of the leaf), chlorophyll content, and biochemical contents (protein, carbohydrate, mineral, and leaf water content) in pumpkin crop.

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