Kjerjohannesen4151

Just as expected, NUC-25 exhibits greatly high catalytic activity for the cycloaddition reaction of epoxides with CO2 into alkyl cyclic carbonates under bland solvent-free conditions, which should be ascribed to the polarity of nitrogen-containing pyridine heterocycles as Lewis base sites on the inner surface of nano-caged voids except for recognized Lewis acid sites of rare earth cations. Moreover, the excellent pore-size-dependent catalytic property for Knoevenagel condensation reactions confirms that NUC-25 can be viewed as a recyclable bifunctional heterogeneous catalyst. Therefore, these results strongly demonstrate that microporous MOFs assembled from pre-designed polycarboxyl-heterocyclic ligands display better catalytic performance not only for chemical CO2 fixation but also for Knoevenagel condensation reactions.Although the water-triggered bending behavior of bilayer films has been a wide concerned, there are few reports on wettability-controlled directional actuators with visible color changes. Using photonic crystals as carriers, bilayer directional bending structural color actuators were prepared based on the hydrophilic difference. Top inverse opal with strong hydrophilicity can promote water penetration and strengthen the effect of swelling. While, bottom inverse opal with weak hydrophilicity can inhibit water penetration and weaken the effect of swelling. When the bilayer structure is immersed in water, its wettability differences will produce different optical responses for visualization and will bring different swelling performances, resulting in directional bending. Infiltration differences are visualized as structural color red shifts or transparency. The mechanism of the design involves optical diffractions in the fabricated periodic nanostructures, differences in the surface wettability and swelling rate, uses the infiltration and capillary evaporation of water to realize the spectral diversity of reflectance, and the enhancement of bending by gradient infiltration. This work deeply analyzes the improvement of the photonic crystal structure on the optical and bending performance of the wettability-controlled actuator, provides a basic model for the design of bionic components, and opens an idea for the combination of bilayer photonic crystals and actuators.ConspectusHeterogeneous catalysis is an area of great importance not only in chemical industries but also in energy conversion and environmental technologies. It is well-established that the specific surface morphology and structure of solid catalysts exert remarkable effects on catalytic performances, since most physical and chemical processes take place on the surface during catalytic reactions. Different from the widely studied faceted metallic nanoparticles, metal oxides give more complicated structures and surface features. Great progress has been achieved in controlling the shape and exposed facets of transition metal oxides during nanocrystal growth, usually by using surface-directing agents (SDAs). However, the effects of exposed facets remain controversial among researchers. It should be noted that high-energetic facets, especially polar facets, tend to lower their surface energy via different relaxation processes, such as surface reconstruction, redox change, adsorption of countercharged species, et hydroxides are also briefly discussed with regard to their application in facet-dependent catalysis studies.Nature has been inspiring scientists to fabricate impact protective materials for applications in various aspects. However, it is still challenging to integrate flexible, stiffness-changeable, and protective properties into a single polymer, although these merits are of great interest in many burgeoning areas. Herein, we report an impact-protective supramolecular polymeric material (SPM) with unique impact-hardening and reversible stiffness-switching characteristics by mimicking sea cucumber dermis. The emergence of softness-stiffness switchability and subsequent protective properties relies on the dynamic aggregation of the nanoscale hard segments in soft transient polymeric networks modulated by quadruple H-bonding. As such, we demonstrate that our SPM could efficiently reduce the impact force and increase the buffer time of the impact. Importantly, we elucidate the underlying mechanism behind the impact hardening and energy dissipation in our SPM. Based on these findings, we fabricate impact- and puncture-resistant demos to show the potential of our SPM for protective applications.Water provides an ideal source for the production of protons and electrons required for generation of renewable fuels. Among the most-prominent electrocatalysts capable of water oxidation at low overpotentials are Ru(bda)L 2 -type catalysts. Although many studies were dedicated to the investigation of the influence of structural variations, the true implication of the bda backbone on catalysis remains mostly unclarified. In this work, we further investigated if electronic effects are contributing to catalysis by Ru(bda)(pic) 2 or if the intrinsic catalytic activity mainly originates from the structural features of the ligand. Afatinib supplier Through introduction of pyrazines in the bda backbone, forming Ru(N 1 -bda)(pic) 2 and Ru(N 2 -bda)(pic) 2 , electronic differences were maximized while minimizing changes in the geometry and other intermolecular interactions. Through a combination of electrochemical analysis, chemical oxygen evolution, and density functional theory calculations, we reveal that the catalytic activity is unaffected by the electronic features of the backbone and that the unique bimolecular reactivity of the Ru(bda)L 2 family of catalysts thus purely depends on the spatial geometry of the ligand.The extracellular matrix (ECM) comprises a meshwork of biomacromolecules whose composition, architecture, and macroscopic properties, such as mechanics, instruct cell fate decisions during development and disease progression. Current methods implemented in mechanotransduction studies either fail to capture real-time mechanical dynamics or utilize synthetic polymers that lack the fibrillar nature of their natural counterparts. Here we present an optogenetic-inspired tool to construct light-responsive ECM mimetic hydrogels comprised exclusively of natural ECM proteins. Optogenetic tools offer seconds temporal resolution and submicron spatial resolution, permitting researchers to probe cell signaling dynamics with unprecedented precision. Here we demonstrated our approach of using SNAP-tag and its thiol-targeted substrate, benzylguanine-maleimide, to covalently attach blue-light-responsive proteins to collagen hydrogels. The resulting material (OptoGel), in addition to encompassing the native biological activity of collagen, stiffens upon exposure to blue light and softens in the dark.