Barefootreddy4009
Leakage accidents often occur during the production, transportation, and use of petroleum products, which is a common and serious environmental issue. It is of great significance and challenge to develop efficient materials for oil-water separation. This article introduces a simple and feasible method to prepare high-performance 3D graphene foam (GF) oil-absorbing material. Gold nanoparticles (Au NPs) are loaded on the surface of graphene foam by ion sputtering and then modified with 1H, 1H, 2H, 2H-perfluorodecanethiol (PFDT). The prepared graphene sponge is porous with a large specific surface area and excellent water repellency (water contact angle exceeding 150°). The superhydrophobicity of the materials is due to the interaction between the rough structure of gold nanoparticles and the reduction of surface energy by PFDT. These outstanding properties make the functionalized graphene foam have excellent oil absorption capacity, which can even be as high as 25.8 g/g, and it can still maintain high separation performance after 10 cycles of recycling. It is worth noting that the preparation of the material is simple and reusable. Therefore, the prepared graphene foam has the potential as a promising absorbent for oil spill purification.Environmental heterogeneity in resource availability affects invasive plant reproductive strategies and resource allocation to reproduction. Here, we conducted two field surveys to examine the effect of wetland and terrestrial habitats on inflorescence production and resource allocation to inflorescence of the amphibious invasive plant Alternanthera philoxeroides in its invasive range (China). We also specifically examined the effects of water availability, fertilizer application, and plant density (space) in a greenhouse experiment. In field surveys, inflorescence biomass, normal monoclinous flowers and ratio of inflorescences to shoots of plants from wetlands were about 2.4-, 0.8- and 1.3-fold higher than those from terrestrial habitats, respectively. In greenhouse experiment, plants with higher fertilizer application and lower competition conditions produced more inflorescences, and had a lower ratio of roots to shoots and a comparable ratio of inflorescences to shoot and root. Furthermore, water availability had a significant interactive effect when combined with fertilizer level or plant density on inflorescence production and resource allocation. Together, our results indicate that high resources, such as those found in wetland habitats, favor both vegetative growth and sexual trait in A. philoxeroides. However, in terrestrial habitats where resources are relatively poor, the invader can adapt to the environment by allocating more resources to vegetative growth for clonal reproduction and less resources for sexual trait. This phenotypic plasticity in resource allocation likely facilitates the plant to invade heterogeneous wetlands and terrestrial environments.To assess terrestrial ecosystems damages from acidification, life cycle impact assessment (LCIA) can be applied using characterisation factors, which integrate the quantification of adverse effects via effect factors (EFs), linking decreasing soil pH to declines in species richness. With a species coverage of 0.6%, the currently-existing EFs defined for 14 biomes carry important uncertainties and lack the appropriate spatial resolution to capture the effects of terrestrial acidification. In our study, we thus used georeferenced observational data with 113 million data points to develop a comprehensive, global inventory covering 189,185 vascular plant species, which is nearly 100 times more species than existing inventories used in LCIA (raising the species coverage to 49%). selleck chemical EFs were then calculated for 825 ecoregions. Great spatial variability is observed between ecoregions within a same biome spanning up to 3 orders of magnitude, and EFs developed at biome level tend to underestimate acidification effects. We find up to 2 orders of magnitude differences between our EFs and the ones currently recommended for use in LCIA. These results call for updating current LCIA practice to assess acidification impacts with our more differentiated and environmentally representative EFs and to implement our approach to other site-dependent environmental impacts where large georeferenced datasets exist.This study reports a novel adsorbent structure and shows the satisfactory removal performance of Pb(II) and Ni(II). The fabric structure increases the strength of the hydrogel. The hydrogel plays a major role in the composite structure as a matrix, while the fabric bears the applied load and protects the structure from mechanical damage. The double-network composite hydrogel is reinforced by plasma grafted polylactic acid melt-blown non-woven fabric and polyethylene glycol dimaleate, and its compressive strength reaches 40.6 kPa at 60% strain. The interface substantially improves the compression strength by 42.9%. Through the adsorption isotherm model, the adsorption capacity of the hydrogel for Pb(II) and Ni(II) reaches 233.12 and 165.06 mg/g, respectively, and the removal rate of heavy metal ions in water at low concentrations exceeds 95%, showing the excellent removal rate of heavy metals. Even after the fifth cycle, the removal efficiency barely declines, indicating the feasibility of repeatedly use. Cost analysis reveals that the adsorbent is relatively low cost, solving the problems of difficult recovery, low strength, and easy damage of hydrogel adsorbents, and promoting the industrial application of hydrogels as adsorbents.Considerable portions of the total mobile inventory of soil seepage are the diverse colloidal and larger suspended materials that essentially contribute to pedogenesis, soil functioning, and nutritional supply of subsurface ecosystems. However, the size- and material-spectra of the total mobile inventory, and field-scale factors controlling its long-term seasonal and episodic dynamics in undisturbed soil, are scarcely investigated so far. In a 4.5-year field-scale study, we utilized automated tension-controlled lysimeters optimized for in situ-sampling of total mobile inventory. Covering different land uses in a low-mountain groundwater recharge area in central Germany, seepage of top- and subsoil was collected at least biweekly and analyzed by hydrochemical and spectromicroscopic techniques (SEM/EDX, nanoparticle tracking analysis). In undisturbed soil, diverse mineral-, mineral-organic, organic, and bioparticles (microbial cells, biotic detritus) up to 75 μm was mobile. Atmospheric forcing was the major factor that governed transport of the total mobile inventory, causing considerable seasonality in seepage pH and certain solutes (e.