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Particle irradiation is known to give rise to several majority carrier traps in the band gap of n-type 4H-SiC, in the 0.4-1.6 eV energy range below the conduction band edge (E C). Among these traps, the EH1 (E C-0.4 eV) and the EH3 (E C-0.7 eV) are the least thermally stable ones and not much is known on their microscopic origin. In order to understand the nature of EH1 and EH3, their annealing kinetics was studied by means of deep level transient spectroscopy and the results were interpreted by invoking the diffusion-limited theory. It is found that EH1 and EH3 are two different charge states of the same defect, labeled EH-center, that anneals out with an activation energy of ∼1.1 eV and whose nature is related to a carbon interstitial. Our study shows that the EH-center is not the same as the S-center defect which was reported by previous studies found in the literature.The freezing, melting and dynamics of supercooled water at different hydration of controlled porous glass with mean pore sizes 10 nm, 30 nm, 50 nm and 70 nm are studied using differential scanning calorimetry and deuteruim nuclear magnetic resonance (2H-NMR). For saturated samples, the melting temperature follows the Gibbs-Thomson relation despite a clear linear decrease of the melting enthalpy when the transition is shifted due to confinement. For partially filled porous glasses the crystallization and melting temperatures as well as enthalpies are lower than for the saturated samples. 2H-NMR confirms the existence of a non-crystallizable part of water adsorbed on the surface of pores. At room temperature, spin-lattice relaxation rate (1/T 1) is proportional to the inverse of the mean pore size indicating that the relaxation is governed by a surface limited process. At low temperature relaxation rate follows the Vogel-Fulcher-Tammann (VFT) relation.Patterned silver nanoparticle (NP)-poly[2-(methacryloyloxy)ethyl] trimethyl ammonium chloride (AgNP-polyMETAC) composites were prepared by electrochemical lithography, surface-initiated atom-transfer radical polymerization (SI-ATRP) and NP growth inside the polymer brushes. For this purpose, polymer brushes of poly[2-(methacryloyloxy)ethyl] trimethyl ammonium chloride (polyMETAC) were utilized as strong electrolyte brush system. These were introduced in form of patterned polymer brushes to create pH-responsive surface enhanced Raman scattering SERS substrates. It is well-known that the charges of strong polyelectrolyte chains are usually insensitive to pH changes, hence, rarely strong polyelectrolyte brushes have been utilized so far to study pH-responsive properties of such films. Here pH-insensitive polyMETAC brushes exhibit pH-sensitive properties and can be used as pH-responsive surfaces for SERS applications due to the embedding of AgNPs into the polymer brushes. When increasing the pH, the assembly of tis applications.In the article issues of state obligations to ensure the right of a doctor- entrepreneur providing primary medical care to such a type of business activity in the healthcare sector as general medical practice are under study. The attention is focused on the fact that the relevance of the research of this issue is challenged by the lack of comprehensive theoretical investigations, as well as practical necessity in the light of the transformation of the healthcare system of Ukraine. Attention is drawn to the fact that in 2018 the National Health Service of Ukraine was established as the central executive body. The having existed model for paying for every single place in the hospital in Ukraine is being replaced by a new model for financing the health system. The National Health Service of Ukraine being the Budget distributor implements basic principle of the medical reform "money goes after the patient". The commanding-administrative model of relations has been replaced by a contractual one The National Healthf business activity in the healthcare sector as general medical practice is determined. The legal and organizational mechanisms for ensuring this right are analyzed. The assessment of their effectiveness is given. Attention is paid on the practice of the European Court of Human Rights, which is the source of law for member-states of the European Council. The concepts of "legitimate anticipation" or "legitimate expectation" are analyzed, which often relate to government payments that depend on economic and social policies in each sphere. It is argued that the doctor-entrepreneur having become a partner of the Service, has a "legal anticipation" so that funds should be transferred to his bank account on the basis of declarations signed with patients to provide them with a package of primary medical care services guaranteed to these patients. Pracinostat concentration The state is obliged to provide such payments. If payments fail to be provided, the county's economic, social, or health policy cannot be an excuse for the state.Traditional methods of medical examination used during medical visits give little information about the adaptive capabilities of the body, which largely determine the body's ability to adapt to changing environmental conditions. Therefore, diagnosis of adaptive capacity of the body, which can be attributed to the form of prenosological diagnosis of the identified changes, is necessary for an objective assessment of health and improving the effectiveness of health measures. In our work we used the methodology of G. L. Apanasenko, E. A. Pirogova, Berseneva A. B. and Y. P. Suicine. The study involved 1010 people of the population of Astana and Northern regions of Kazakhstan. In all age categories, the higher level of physical condition was among women (64.15±1.95%), compared with men (20.83±2.04%). There were no significant differences in the values of adaptive capacity among men and women, but the number of women with high adaptive capacity (62.7±1.96%) was higher than that of men (55.99±2.5%). The index of physical condition and adaptive capacity were higher among the adolescent population (84.4±4.05%) and had a natural tendency to decrease with age. In 74.4±0.31% of cases it was caused by deterioration of functional parameters of cardiovascular and respiratory systems. Comparative analysis of the adaptive capacity of the population in the regions showed their unidirectional change with the index of physical condition. The lowest values of adaptive potential, indicating a high degree of adaptation, were residents of Astana (54.56±3.52%). The worst performance was observed among the villagers Zarja and Ubaganskoe. In our opinion, such differences may be due to differences in income levels, education, as well as the availability of sports and recreation facilities.