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Liquid manipulation on solid surfaces has attracted a lot of attention for liquid collection and droplet-based microfluidics. However, manipulation strategies mainly depend on chemical modification and artificial structures. Here, we demonstrate a feasible and general strategy based on the self-shrinkage of the droplet induced via specific vapors to efficiently collect liquids and flexibly carry out droplet-based reactions. The vapor-induced self-shrinkage is driven by Marangoni flow originating from molecular adsorption and diffusion. Under a specific vapor environment, the self-shrinking droplet exhibits unique features including reversible responsiveness, high mobility, and autocoalescence. Accordingly, by building a specific vapor environment, the thin liquid films and random liquid films on superlyophilic substrates can be recovered with a collection rate of more than 95%. Moreover, the vapor system can be used to construct a high-efficiency chemical reaction device. https://www.selleckchem.com/products/semaxanib-su5416.html The findings and profound understandings are significant for the development of the liquid collection and droplet-based microfluidics.Understanding the sources, impacts, and fate of microplastics in the environment is critical for assessing the potential risks of these anthropogenic particles. However, our ability to quantify and identify microplastics in aquatic ecosystems is limited by the lack of rapid techniques that do not require visual sorting or preprocessing. Here, we demonstrate the use of impedance spectroscopy for high-throughput flow-through microplastic quantification, with the goal of rapid measurement of microplastic concentration and size. Impedance spectroscopy characterizes the electrical properties of individual particles directly in the flow of water, allowing for simultaneous sizing and material identification. To demonstrate the technique, spike and recovery experiments were conducted in tap water with 212-1000 μm polyethylene beads in six size ranges and a variety of similarly sized biological materials. Microplastics were reliably detected, sized, and differentiated from biological materials via their electrical properties at an average flow rate of 103 ± 8 mL/min. The recovery rate was ≥90% for microplastics in the 300-1000 μm size range, and the false positive rate for the misidentification of the biological material as plastic was 1%. Impedance spectroscopy allowed for the identification of microplastics directly in water without visual sorting or filtration, demonstrating its use for flow-through sensing.The functionalization of the internal surface of macroporous carriers with glyoxyl groups has proven to highly stabilize a large variety of enzymes through multipoint covalent immobilization. In this work, we have translated the surface chemistry developed for the fabrication of glyoxyl-agarose carriers to macroporous cellulose (CEL). To that aim, CEL-based microbeads were functionalized with glyoxyl groups through a stepwise alkoxylation (or alkylation)/oxidation synthetic scheme. This functionalization sequence was analyzed by solid-state NMR, while the scanning electron miscroscopy of CEL microbeads reveals that the mild oxidation conditions negligibly affect the morphological properties of the material. Through the optimal functionalization protocol using rac-glycidol, we introduce up to 200 μmols of aldehyde groups per gram of wet CEL, a similar density to the one obtained for the benchmarked agarose-glyoxyl carrier. This novel CEL-based carrier succeeds to immobilize and stabilize industrially relevant enzymes such as d-amino acid oxidase from Trigonopsis variabilis and xylanases from Trichoderma reseei. Remarkably, the xylanases immobilized on the optimal CEL-based materials present a half-life time of 51 h at 60 °C and convert up to 90% of the xylan after four operation cycles for the synthesis of xylooligosaccharides.The digital nucleic acid assay is a precise, sensitive, and reproducible method for determining the presence of individual target molecules separated in designated partitions; thus, this technique can be used for the nucleic acid detection. Here, we propose a multifunctional micropattern array capable of isolating individual target molecules into partitions and simultaneous on-site cell lysis to achieve a direct DNA extraction and digitized quantification thereof. The multifunctional micropattern array is fabricated by the deposition of a copolymer film, poly(2-dimethylaminomethyl styrene-co-hydroxyethyl methacrylate) (pDH), directly on a microfluidic chip surface via the photoinitiated chemical vapor deposition process, followed by hydrophobic microcontact printing (μCP) to define each partition for the nucleic acid isolation. The pDH layer is a positively charged surface, which is desirable for the bacterial lysis and DNA capture, while showing exceptional water stability for more than 24 h. The hydrophobictalization method for rapid, simple, and accurate digital nucleic acid assays.The feasibility study of utilizing sunflower oil as renewable biomass source to develop highly effective inhibitors for mild steel corrosion (MS) in the 15% HCl medium was done by weight loss, potentiodynamic polarization (PDP), dynamic electrochemical impedance spectroscopy (DEIS), and electrochemical impedance spectroscopy (EIS), supported with energy-dispersive X-ray (EDX), atomic force microscopy (AFM), and field-emission scanning electron microscope (FESEM) techniques. Moreover, a complementary theoretical investigation was carried out to clarify the inhibition mechanism of inhibitors by density functional theory (DFT), density functional based tight-binding (DFTB), and molecular dynamics (MD) simulation approaches. The obtained results confirm that sunflower-oil-based corrosion inhibitor (SFOCI) has a significant anticorrosion property toward the dissolution of MS in 15% HCl solution in the temperature range 20-80 °C. In addition, the results show that SFOCI could provide an inhibition efficiency of 98 and 93% at 60 and 80 °C, respectively. The inhibition mechanism of SFOCIs was mixed-type and their adsorption on the surface of MS was mainly chemisorption. The FESEM and EDX studies proved the presence of SFOCI molecules on the surface of MS. In addition, the adsorption energy of SFOCI indicated an intense interaction between the inhibitor and surface of Fe. The results of this study could open a new window for the design and development of scalable and effective eco-friendly vegetable-oil-based corrosion inhibitors for highly corrosive solutions at high temperatures.