Akhtarpennington7244

We determined trophic magnification factors (TMFs) for contaminants that had a 50% or greater detection frequency in all biota samples and compared these terrestrial TMFs to those observed in aquatic systems. TMFs in this terrestrial food web ranged between 1.2 (0.21 SE) and 15 (4.0 SE), indicating that the majority of these POPs are biomagnifying. TMFs of the legacy POPs investigated in this terrestrial food web increased in a statistically significant relationship with both the logarithm of the octanol-air (log KOA) and octanal-water partition (log KOW) coefficients of the POPs. POPs with a log KOA >6 or a log KOW >5 exhibited biomagnification potential in this terrestrial food web. Crown V. All rights reserved.Veterinary antibiotics have been detected as contaminants of emerging concern in soil environment worldwide. Animal manure is frequently applied to agricultural fields to improve soil fertility, which can result in introducing large amount of antibiotics into soil environment. However, few attempts have been made to identify the spatial and temporal dynamics of veterinary antibiotics in soil at the hillslope scale with different land uses. This study was performed to explore the pattern and variability of veterinary antibiotics in the soil in response to rainfall events. Results showed that higher concentrations of veterinary antibiotics were generally found in cropland (292.6 ± 280.1 ng/g) and orchard (228.1 ± 230.5 ng/g) than in forestland (13.5 ± 9.9 ng/g). After rainfall events, antibiotics accumulated in the soil at the positions where manure was applied, especially under high-intensity rainfall conditions. However, the antibiotic concentration in soil slightly increased from the top to the bottom of hills, thus indicating the restricted contribution of runoff to antibiotic transport, especially under low-intensity rainfall conditions. In addition, most antibiotics were sequestered in the surface soil (0-10 cm), and higher antibiotic concentrations were observed in deep soil (20-40 cm) in cropland than orchard. P22077 mouse The soil aggregate, organic matter, and clay content played important roles in antibiotic sequestration along the hillslope subject to low-, medium-, and large-amount rainfall events, respectively. This study identified that land use, rainfall conditions, and soil structures jointly affect the spatial and temporal variability of antibiotics in soils on hillslopes. This work reports the use of an iron ore tailings from waste dam as a catalyst and support for carbon nanotubes synthesis and their application in the adsorption of the 17α-ethinylestradiol hormone. The synthesis was carried out by Chemical Vapor Deposition (CVD) in a Fluidized Bed system using ethylene at temperatures of 500, 600 and 700 °C, and acetonitrile at 500, 600, 700, 800 and 900 °C. The transmission electron microscopy (TEM) results showed that the two higher temperatures in each case favored the formation of nanostructures like carbon nanotubes (CNTs), with good yields. The ethylene source generated classic tubular structures of multiple walls. On the other hand, acetonitrile provided the formation of tubes with less organization, known as bamboo like. This morphology was caused by the insertion of nitrogen into the graphite structure (doping), which originates from the carbon source. The adsorptive capacity of the materials for 17α-Ethinylestradiol removal ranging from 9.2 mg g-1 to 22.3 mg g-1. The kinetic and adsorption isotherm studies were also performed for the systems. As for kinetics, all of them presented pseudo-second order behavior. In relation to the type of isotherm, the systems showed Freundlich behavior, that is, the adsorption occurs in multiple layers. Finally, it was concluded that the use of an iron ore tail as a catalyst in the production of CNTs by CVD is feasible. The materials synthesized still had good adsorptive capacity for an emerging contaminant, thus this study allowed the investigation of two environmental problems. Halogenated flame retardants (HFRs) are ubiquitous in the environment, but little information is available about the bioaccumulation of HFRs in mangrove plants. In this study, three mangrove plant species were collected from Futian National Nature Reserve of Shenzhen City, South China to investigate the bioaccumulation of polybrominated diphenyl ethers (PBDEs) and several alternative halogenated flame retardants (AHFRs), including decabromodiphenyl ethane (DBDPE), 1,2-bis(2,4,6-tribromophenoxy)ethane (BTBPE), hexabromobenzene (HBB), pentabromotoluene (PBT), tetrabromop-xylene (pTBX), pentabromoethylbenzene (PBEB) and dechlorane plus (DP). The mean concentrations of PBDEs, DBDPE, BTBPE, pTBX, PBT, PBEB, HBB and DP in mangrove plant species were 2010, 1870, 36.2, 18.7, 40.1, 17.8, 9.68 and 120 pg g-1 dry weight, respectively. PBDEs were the dominant HFRs in mangrove plant tissues, followed by DBDPE. The relative abundance of BDE 209 in three mangrove plant tissues were much lower than those in sediments. Significant negative relationships between log root bioaccumulation factors and log Kow, and between log TFr-s (from root to stem) and log Kow were observed, indicating that HFRs with low hydrophobicity were easily absorbed by mangrove roots and stems. A positive correlation between log TFs-l (from stem to leaf) and log Kow were found, suggesting that air-leaf exchange may occur in mangrove plants. This study highlights the uptake of HFRs by mangrove plants, which can be used as remediation for HFRs contamination in the environment. Ice and sediment cores, peat bogs and tree rings are useful proxy records for reconstructing historical air pollution events. However, these indirect measurements are subject to interferences caused by environmental perturbations including global climate change. Therefore, using multiple proxy records has advantages in constraining the analytical findings. In this study, we utilized the chronological record of atmospheric deposition preserved in vegetation succession ecosystems in the deglaciated region for reconstructing historical pollution events. The rate of Cd accumulation in the forest chronosequence zone was investigated in a deglaciated area of the Tibetan Plateau. The results obtained through this novel approach are consistent with the variations of Cd concentration recorded in tree-ring, showing a 4-7 times increase of atmospheric Cd deposition from the 1890s to the early 1970s followed by a decrease from the mid-1970s-2000s. The Cd pollution record indicates that elevated atmospheric Cd release occurred in regions of Southwest China and South Asia due to the rapid industrial development until 1970 followed by coordinated efforts in controlling air emissions after mid-1970s.