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Geogenic arsenic contamination typically occurs in groundwater as opposed to surface water supplies. Groundwater is a major source for many community water systems (CWSs) in the United States (US). Although the US Environmental Protection Agency sets the maximum contaminant level (MCL enforceable since 2006 10 μg/L) for arsenic in CWSs, private wells are not federally regulated. We evaluated county-level associations between modeled values of the probability of private well arsenic exceeding 10 μg/L and CWS arsenic concentrations for 2231 counties in the conterminous US, using time invariant private well arsenic estimates and CWS arsenic estimates for two time periods. Nationwide, county-level CWS arsenic concentrations increased by 8.4 μg/L per 100% increase in the probability of private well arsenic exceeding 10 μg/L for 2006-2008 (the initial compliance monitoring period after MCL implementation), and by 7.3 μg/L for 2009-2011 (the second monitoring period following MCL implementation) (1.1 μg/L mean decline over time). Apoptosis inhibitor Regional differences in this temporal decline suggest that interventions to implement the MCL were more pronounced in regions served primarily by groundwater. The strong association between private well and CWS arsenic in Rural, American Indian, and Semi Urban, Hispanic counties suggests that future research and regulatory support are needed to reduce water arsenic exposures in these vulnerable subpopulations. This comparison of arsenic exposure values from major private and public drinking water sources nationwide is critical to future assessments of drinking water arsenic exposure and health outcomes.Limited information is available on the spatiotemporal occurrence and ecological risks of organophosphate esters (OPEs) in coastal environments. 175 water samples were collected in Laizhou Bay (LZB) and its rivers and estuaries during spring and summer for the determination of 12 targeted OPEs. Total concentration of OPEs ranged from 234.4 to 2892.1 ng L-1 in the river and estuarine water and 87.6 to 969.4 ng L-1 in the bay water, with medians of 1015.8 and 296.8 ng L-1, respectively, showing that riverine inputs were the major sources of OPEs in the bay. Tris (2-chloroisopropyl) phosphate (TCIPP) and triethyl phosphate (TEP) were the most abundant OPEs, with median contributions of 47% and 36% in the bay water, respectively. The total concentration of OPEs was higher in the estuarine area of the Yellow River and the southwestern coast of the LZB under the influence of riverine OPE inputs and ocean currents. In addition, the concentrations of dominant OPE species were significantly higher in the surface water than in the bottom water. The concentrations of dominant OPE species were found to be significantly lower in summer than in spring, mainly due to both precipitation and seawater dilution effects. However, the concentrations of three minor OPE species were significantly higher in summer than in spring, probably because of their high usage in summer. TCIPP and TEP concentrations were significantly negatively correlated with salinity. The targeted OPEs posed low ecological risk in the bay and moderate ecological risk in the rivers and estuaries, which was mostly ascribed to the toxicity of tris (2-chloroethyl) phosphate (TCEP) and resorcinol-bis (diphenyl) phosphate (RDP) to algae. Priority should be given to TCIPP, TEP, TCEP, and RDP in the LZB due to their high concentrations and/or toxicity.Isoflucypram belongs to the new generation of succinate dehydrogenase inhibitor (SDHI) fungicides that are commonly used in crop fungal disease control. Evidence indicates that isoflucypram poses a potential risk to aquatic organisms. However, the effects of isoflucypram during early embryogenesis are not fully understood. In the present study, zebrafish embryos were exposed to 0.025, 0.25, or 2.5 μM isoflucypram for three days. Isoflucypram caused severe developmental abnormalities (yolk sac edema, pericardial edema, and blood clotting clustering), hatching delay, and decreased heart rates in zebrafish. The expression levels of cardiac-specific genes (nkx2.5, myh7, myl7, and myh6) and erythropoiesis-related genes (gata1a, hbbe1, hbbe2, and alas2) were disrupted after isoflucypram exposure. Furthermore, enrichment analysis indicated that most of the differentially expressed genes (DEGs) were enriched in heart development or hemopoiesis processes. Overall, these findings suggest that exposure to isoflucypram is associated with developmental and cardiovascular toxicity in zebrafish.Geographical indications (GIs) are increasingly seen as a tool to support sustainable local development. This study focuses on how geographical indications can contribute to a territorial public system, and how this can be threatened by several market failures. Starting from the economic literature on public goods, this document highlights how geographical indications, and their legal protection, can guarantee a sustainable development model. This article aims to illustrate and develop new economic arguments that support a more comprehensive political approach to the contribution that Geographical indications make to sustainable development. The research is focused in Sicily on the production of Pachino Tomatoes with Geographical Indication. This production has an ancient tradition and is located in the center of the Mediterranean. Because of that, it is appreciated in food markets. The study, carried out through the application of the "successful entrepreneurial formula" model, was implemented through a telephone survey of the actors in the production system. The results of the study highlight how territorial public goods based on cohesion represent the vector for the resilience of the agricultural landscape and the growth of the entire region in which the agri-food product is developed. An important aspect, as demonstrated in the paper, is the role of information on the product and the territory. Nowadays, dominance at the competitive system level and social cohesion do not guarantee the success of agri-food production. The study shows that the success of GIs depends on the role of communication that conveys information. This study is new compared to previous ones on the subject, as it applies the business economic approach of the successful entrepreneurial formula to a problem of business competitiveness and, in general, of the territory.