Mcneilmacmillan0773

As for hydrochar with more O-containing functional groups than biochar, the dominated sorption mechanism would be surface complexation, due to higher sorption capacity of Aged-HC with richer O-containing functional groups. In binary-metal system, the competitive sorption of Cd(II) and Cu(II) on biochar was observed obviously but that on hydrochar was limited. Ageing could increase the sorption capacity of Cd(II) in binary-metal system, resulting in alleviating competitive adsorption. The total sorption amount of Cd(II) and Cu(II) by biochar was markedly greater than that of hydrochar before or after ageing, suggesting that biochar can be still more capable than hydrochar for handling Cd(II) and Cu(II) in single-metal or binary-metal. These findings suggest us to consider the long-term effect on immobilization of co-existing heavy metals and alleviating competitive adsorption of carbonized materials as alternative amendment for contaminated sites. With the exponential growth of nanomaterial production in the last years, nano copper (Cu)-based compounds are gaining more consideration in agriculture since they can work as pesticides or fertilizers. Chinese scallions (Allium fistulosum), which are characterized by their high content of the antioxidant allicin, were the chosen plants for this study. learn more Spectroscopic and microscopic techniques were used to evaluate the nutrient element, allicin content, and enzyme antioxidant properties of scallion plants. Plants were harvested after growing for 80 days at greenhouse conditions in soil amended with CuO particles [nano (nCuO) and bulk (bCuO)] and CuSO4 at 75-600 mg/kg]. Two-photon microscopy images demonstrated the particulate Cu uptake in nCuO and bCuO treated roots. In plants exposed to 150 mg/kg of the Cu-based compounds, root Cu content was higher in plants treated with nCuO compared with bCuO, CuSO4, and control (p ≤ 0.05). At 150 mg/kg, nCuO increased root Ca (86%), root Fe (71%), bulb Ca (74%), and bulb Mg (108%) content, compared with control (p ≤ 0.05). At the same concentration, bCuO reduced root Ca (67%) and root Mg (33%), compared with control (p ≤ 0.05). At all concentrations, nCuO and CuSO4 increased leaf allicin (56-187% and 42-90%, respectively), compared with control (p ≤ 0.05). The antioxidant enzymes were differentially affected by the Cu-based treatments. Overall, the data showed that nCuO enhances nutrient and allicin contents in scallion, which suggests they might be used as a nanofertilizer for onion production. Environmental pollution and scarcity of natural resources lead to an increased interest in developing more sustainable materials. For example, the traditional construction industry, which is largely based on the extraction of fossil fuels and raw materials, is called into question. A solution can be found in biologically augmented materials that are made by growing mycelium-forming fungal microorganisms on natural fibres rich in cellulose, hemicellulose and lignin. In this way, organic waste streams, such as agricultural waste, are valorised while creating a material that is biodegradable at the end of its life cycle - a process that fits in the spirit of circular economy. Mycelium-based materials have properties that are promising for a wide range of applications, including the use as construction materials. Despite this promise, the applicability and the practicality of these materials are largely unexplored and moreover, individual studies use a wide range of different experimental approaches and non-standardized procedures. In this review, we critically evaluate existing data on the composition of mycelium-based materials and process variables with the aim of providing a comprehensive framework of the production process. The framework illustrates the many input factors during the production that have an impact on the final characteristics of the material, and the unique potential to deploy more tuneable levels in the fabrications process that can serve to prototype a diversity of new unprecedented applications. Furthermore, we determine the applicability of existing data and identify knowledge gaps. This framework is valuable in identifying standardized approaches for future studies and in informing the design and process of new applications of mycelium-based materials. V.Irrigated dryland agroecosystems could become more sustainable if crop and soil management enhanced soil organic carbon (SOC). We hypothesized that combining high inputs from cover crops with no-tillage will increase long-term SOC stocks. Caatinga shrublands had been cleared in 1972 for arable crops and palm plantations before implementing field experiments on Mango and Melon systems (established in 2009 and 2012, respectively). Each of the two experiments were managed with no-till (NT) or conventional till (CT), and three types of cover cropping, either a plant mixture of 75% (PM1) or 25% (PM2) legumes, or spontaneous vegetation (SV). The RothC model was used with a daily timestep to simulate the soil moisture dynamics and C turnover for this dry climate. Carbon inputs were between 2.62 and 5.82 Mg C ha-1 year-1 and increased the depleted SOC stocks by 0.08 to 0.56 Mg C ha-1 year-1. Scenarios of continuous biomass inputs of ca. 5 Mg C ha-1 year-1 for 60 years are likely to increase SOC stocks in the mango NT beyond the original Caatinga SOC by between 19.2 and 20.5 Mg C ha-1. Under CT similar inputs would increase SOC stocks only marginally above depletion (2.75 to 2.47 Mg C ha-1). Under melon, annual carbon inputs are slightly greater (up to 5.5 Mg C ha-1 year-1) and SOC stocks would increase on average by another 8% to 22.3 to 20.6 Mg C ha-1 under NT and by 8 Mg C ha-1 under CT. These long-term simulations show that combining NT with high quality cover crops (PM1, PM2) would exceed SOC stocks of the initial Caatinga within 20 and 25 years under irrigated melon and mango cultivation, respectively. These results present a solution to reverse prior loss of SOC by replacing CT dryland agriculture with irrigated NT plus high input cover crops agroecosystems.