Bairdcarlsen6148

Sewage sludge contains various classes of organic pollutants, limiting its land application. Sludge composting can effectively remove some organic pollutants. This review summarizesrecent researches on concentration changes and dissipation of different organic pollutants including persistent organic pollutants during sludge composting, and discusses their dissipation pathways and the current understanding on dissipation mechanism. Some organic pollutants like PAHs and phthalates were removed mainly through biodegradation or mineralization, and their dissipation percentages were higher than those of PCDD/Fs and PCBs. Nevertheless, some recalcitrant organic pollutants could be sequestrated in organic fractions of sludge mixtures, and their levels and ARG abundance even increased after sludge composting in some studies, posing potential risks for land application. This review demonstrated that microbial community and their corresponding degradation for organic pollutants were influenced by different pollutants, bulking agents, composting methods and processes. Further research perspectives on removing organic pollutants during sludge composting were highlighted.This study focused on the nitrous oxide (N2O) generation from the biological nitrogen removal process under different pH levels. To explore a pH optimum, the online N2O emission and the bacterial composition and function in the anoxic-oxic process were investigated. The mean gaseous N2O emission accounted for 0.329%, 0.103%, 0.085%, and 0.793% of the influent total nitrogen at pH of 5, 6, 8, and 9, respectively. Incomplete oxidation in oxic tanks was the primary source of N2O, while N2O in the anoxic tank was mainly generated by nitrifier denitrification. No direct correlations were observed between N2O emission and potential nitrifiers and denitrifiers. The impacts of pH on N2O generation were more likely related to the response of bacterial enzymes and nitrogen compounds, rather than the feedback of bacterial community structure itself. Above all, an influent pH range of 6-8 is recommended for nitrogen removal and N2O mitigation in anoxic-oxic process.Construction of fluorescent probe for highly sensitive and selective detection of perfluorooctane sulfonate (PFOS) in water and biological samples is a very important strategy in related pollutant monitoring and environmental health risk appraisal. To overcome the drawback of low sensitivity caused by high-back ground signal of the conventional sensor, a molecularly imprinted near-infrared excitation ratiometric fluorescent probe was constructed and employed to determine PFOS. The sensing process was achieved through the selectively recognition of specific cavities in the probe surface with analyte, accompanied by fluorescence quenching due to the photoinduced electron transfer effect between upconversion materials and PFOS. Under optimized experimental conditions, the fluorescence quenching efficiency of the probe has good linearity against the concentrations of PFOS response divided into two segments within linear ranges of 0.001-0.1 nmol/L and 0.1-1 nmol/L, respectively, with low detection limit of 1 pmol/L. Selective experiment results indicate that the C-F chain length plays a dominant role in molecular recognition and high sensitively detection. The fabricated probe shows well detection performance in a wide pH range. Furthermore, real samples analyses indicate that such an efficient fluorescent probe has potentials in PFOS determination in surface water, human serum and egg extract sample analyses.Distinguishing toxic gases among the various volatile sulfur compounds (VSCs) is of significant practical value for atmospheric and environmental pollution monitoring, industrial monitoring, and even for medical diagnostics (where VSCs are indicators of diseases). The particular challenge lies in the detection and discrimination of sulfur-containing gases such as dimethyl disulfide (DMDS), methyl sulfide (DMS), hydrogen sulfide (H2S), and carbon disulfide (CS2) is of value. ATG-017 purchase Herein, single-phase perovskite-type LnFeO3 nanoparticles were prepared by the citrate sol-gel method. Their gas sensing characteristics regard to the four typical VSCs were investigated. We found that the gas response of the p-type semiconductor LnFeO3 gas sensors to the four typical VSCs are significantly different. In addition, the sensors offer high performance, good tolerance to environmental changes and long-term stability for detecting VSCs gas at an operating temperature of 210 °C. A new design of sensor array was realized by integrating a series of LnFeO3 materials, which revealed excellent recognition ability for various VSCs, showing promise for real time monitoring.The evolution of brown carbon (BrC) during atmospheric aging, including the changes in optical properties and chemical compositions, is still unclear. Light absorption and fluorescence of BrC fraction extracted from fresh and ozonized propane soot particles by methanol were systematically measured, which showed that (1) the mass absorption efficiencies (MAE) sharply decreased by ozone (O3) aging (e.g., 1.2 ± 0.3-0.8 ± 0.1 m2 g-1 for MAE365), but changed slowly with increased O3 concentration (e.g., from 0.7 ± 0.2-0.8 ± 0.1 m2 g-1 for MAE365); (2) the fluorescence emission peaks were blue shifted, implying a loss of conjugated structures; (3) excitation-emission matrix analysis suggested that humic-like substances, charge transfer complexes, and polycyclic aromatic hydrocarbon (PAH)-like substances were the main chromophores. The PAH loss, accompanied by the decline of surface C˭C content, contributed more to the change of optical properties than the oxygenated PAH formation, thereby leading to the decrease in light absorption and fluorescence with O3 aging. This research reveals the importance of identifying the components responsible for optical properties in investigating the evolution of BrC during atmospheric aging, and is benefit for improving the evaluation of BrC's radiative forcing.Heavy metal (HM) pollution of farmland is a serious problem worldwide and consumption of HM-contaminated food products poses significant public health risks. Phytoexclusion using low HM accumulating cultivars (LACs) is a promising and practical technology to mitigate the risk of HM contamination of agricultural products grown in polluted soils, and does not alter cultivation practices, is easy to apply, and is economical. This review provides an overview of the major scientific advances accomplished in the field of LACs worldwide. The LACs concept and identification criteria are presented, and the known LACs among currently cultivated grain crops and vegetables are re-evaluated. The low HM accumulation by LACs is affected by crop ecophysiological features and soil physicochemical characteristics. Taking low Cd accumulating cultivars as an example, it is known that they can efficiently exclude Cd from entering their edible parts in three ways 1) decrease in root Cd uptake by reducing organic acids secretion in the rhizosphere and transport protein production; 2) restriction of Cd translocation from roots to shoots via enhanced Cd retention in the cell wall and Cd sequestration in vacuoles; and 3) reduction in Cd translocation from shoots to grains by limiting Cd redirection and remobilization mediated through nodes.