Dorseygreve4273

Although the field of natural product extraction with ionic liquids (ILs) is already a crowded one, the guiding rules regarding the selection of suitable ILs for extraction are still lacking. In this study, the extraction capacity of 32 ILs was investigated using Puerariae lobatae as a testing material, namely, 11 [BMIM]-based, 9 [CMIM]-based, 8 [C n MIM][Br] and 8 [C n MIM][BF4] ILs (n = 2, 4, 6, 8, 10, 12, 14, 16) were studied. Three series of concentrations (0.02, 0.50, 2.00 M) were investigated, and the results demonstrated that the extraction capacity increased with the rising IL concentrations except for 1-butyl-3-methyl-imidazolium tosylate ([BMIM][Tos]). Generally, all the 0.50 and 2.00 M ILs led to the best extraction results. At low concentrations, the IL extraction capacity is strongly dependent on the anions and cations. However, the relationship between extraction capacity and anions or cations gradually becomes weak as increasing IL concentrations. Finally, the solution of ILs was prepared in aqueous or 60% methanol depending on the solubility. The pH can vary from strong acid to weak alkaline. Extraction capacity of 32 ILs varying in concentrations has a good negative correlation with the pH, except for five [BMIM]-ILs. Copyright © 2020 American Chemical Society.According to the importance of polyanion cathode materials in intercalation batteries, they may play a significant role in energy-storage systems. Here, evaluations of LiMBO3 and NaMBO3 (M = Mn, Fe, Co, Ni) as cathode materials of Li-ion and Na-ion batteries, respectively, are performed in the density functional theory (DFT) framework. The structural properties, structural stability after deintercalation, cell voltage, electrical conductivity, and rate capability of the cathodes are assessed. As a result, Li compounds have more structural stability and energy density than Na compounds in the C2/c frame structure. Cell voltage is increased by increasing the atomic number of the transition metal (TM). Adenosine Receptor antagonist A noble approach is used to evaluate electrical conductivity and rate capability. M = Fe compounds exhibit the lowest band gaps (BGs), and M = Mn compounds exhibit almost the highest one. The best electrical rate-capable compounds are estimated to be M = Mn ones and the worst are M = Ni ones. As far as cell potential is not the concern, AMnBO3, ACoBO3-AFeBO3, and ANiBO3 are the best to the worst considered cathode materials. Copyright © 2020 American Chemical Society.Recently, multiplexed ratiometric fluorescence sensors for detecting several analytes have received much interest because of their multifunctionality. Here, we fabricate a novel trinity fluorescent nanoprobe in which one small-molecule fluorophore, blue-emissive dityrosine (diTyr) residues, and two nanomaterial fluorophores, green-emissive CdS quantum dots (CdSQDs) and red-emissive gold nanoclusters (AuNCs), are cocaged in a bovine serum albumin (BSA) molecule. The large differences of Stokes shifts among diTyr residues, CdSQDs, and AuNCs ensure their emission at a single excitation wavelength. The nanoprobes can be facilely integrated using two-step synthetic reactions. DiTyr residues and AuNCs are formed and bound to the protein cage through the redox reaction between Au3+ and tyrosine residues of BSA, and the CdSQDs are followed to be conjugated to the modified BSA cage-templated CdS combination reaction. With established benign biocompatibility, the nanoprobes can ratiometrically detect intracellular glutathione by significantly enhancing the green emission of the conjugated CdSQDs. Likewise, the ratiometric sensing of solution alkalinity and tris(2-carboxyethyl)phosphine can be achieved using blue-emitted diTyr residues and red-emitted AuNCs as the responsive units, respectively, and the corresponding other two fluorophores as the reference signals. This study addresses a concept of trinity fluorescence ratiometric sensing system with multiple targets and optional references, which should be a promising pathway to meet the challenges from complexing biochemical environments and multivariate analysis. Copyright © 2020 American Chemical Society.Overall performance of composite calcium silicate boards (CCSBs) was investigated to further promote their application. The alkali activators were used to fully hydrate the calcium and silicon raw materials, which further improved the comprehensive performance of the CCSBs made of four pure industrial solid wastes. Within the range of dosage in this study, single doping of different proportions of the alkali activator improved the flexural strength of the CCSB. Based on this, the mechanical properties of the CCSB were further improved as the compounded alkali activator was optimized. Flexural strength is improved when the average pore diameter was refined. The freeze-thaw cycle test shows that a compound-doped alkali activator can effectively reduce the mass loss and strength loss, thereby improving the frost resistance of this material. This research discussed an economically affordable approach to prepare the CCSB material made of industrial solid waste. Copyright © 2020 American Chemical Society.Developing a photocatalyst system to generate hydrogen from water is a topic of great interest for fundamental and practical importance. In this study, we develop a new Z-scheme photocatalytic system for overall water splitting that consists of Rh/K4Nb6O8 for H2 evolution, Pt/BiVO4 for O2 evolution, and I-/IO3 - for an electron mediator under UV light irradiation. The oxygen evolution photocatalyst BiVO4 was prepared by the microwave-assisted hydrothermal method. The method is fast and simple, as compared to conventional hydrothermal synthesis. The catalysts were characterized by powder X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and UV-visible spectroscopy. The photocatalytic water splitting is investigated in (i) aqueous AgNO3 as sacrificial electron scavengers and (ii) a Z-scheme photocatalytic water splitting system. The BiVO4 photocatalysts prepared by the microwave-assisted hydrothermal method not only showed a very high oxygen evolution rate (2622 μmol g-1 h-1) of water splitting reaction in an aqueous AgNO3 solution but also achieved a high H2 evolution rate (340 μmol g-1 h-1) and O2 evolution rate (172 μmol g-1 h-1) in a Z-scheme overall water splitting system.