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A new denaturation agent is the mixture of 4,5-dihydroxy-1,3-bis(methoxymethyl)imidazolidin-2-one (m-DMDHEU)/choline chloride (CC) introduced to modify three kinds of lignocellulosic materials containing different lignin contents in the following order cotton used in medicine less then sawdust from acacia auriculiformis wood less then powder from the coconut shell. The modification process is carried out through two main steps 0.2 N NaOH solution with 70% v/v ethanol and 30% v/v water was applied to remove lignin and activate the initial raw materials, and then delignified materials were modified with m-DMDHEU/CC by using a parched heat supply method after chemical impregnation. Structural characterictics and physicochemical properties of modified materials were tested and dissected by scanning electron microscopy, Fourier transform infrared spectroscopy, solid-state 13C nuclear magnetic resonance spectroscopy (solid-state 13C CP-MAS NMR), specific surface area, and pH at the point of zero charge (pHPZC). The ability to adsorb and exchange anions of modified materials was referred and examined by using aqueous solutions containing CrO42-, NO3-, and H2AsO4- anions in different conditions. The results revealed that anionite lignocellulosic materials could separate these anions with very good efficiency and better than strong anion exchange resin (GA-13) in the same conditions; outlet water could meet the permissible drinking and living water standards; and the m-DMDHEU cross-link bridge also was a good bridge to connect CC to cellulose chain beside other common urea cross-link bridges.Acyclic diene metathesis (ADMET) polymerization of biobased α,ω-dienes of bis(undec-10-enoate) with diols (1,4-butanediol, isosorbide, isomannide, and 1,4-cyclohexanedimethanol) afforded high-molecular weight unsaturated polyesters, and subsequent tandem hydrogenation (H2 1.0 MPa, 50 °C, 3 h) gave the saturated polymers upon addition of a small amount of Al2O3 (1.0-1.7 wt %). Subsequent reaction of the unsaturated polymers with ethylene afforded the oligomers (by depolymerization and degradation).Graphite-based dual-ion batteries are a promising alternative to the lithium-ion batteries for energy storage because of its potentially lower cost, higher voltage, and better safety. Among the most important materials in the dual-ion battery are the graphite and graphite intercalation compounds (GICs), whose properties determine the performance of electrodes. The GICs are formed at both anode and the cathode sides during the charging process in which the graphene sheets and the intercalants are arranged in an ordered way called the staging of GICs. Staging is one of the important structural features of GICs related to the volume expansion of the electrodes, the charging rate, and the capacity of the battery. However, the details of the staging mechanism, such as the structural properties, the electronic structure, and the voltage dependence on the stages are still poorly understood. In this regard, we perform density functional theory studies to explore these issues in GICs. Using staging models, we examine the stability of GICs at different stages of intercalation with a range of species (i.e., Li, Na, K, PF6, BF4, TFSI, AlCl4, and ClO4). We then study the contribution of intercalants to the electronic band structures in GICs. In addition, the voltage profiles of the dual-ion batteries with different intercalation species, intercalation stages, and battery capacities are also analyzed. The present work is important for the better understanding of graphite-based dual-ion batteries and helpful in development of novel energy storage systems.A one-pot route for the synthesis of spiro-isobenzofuran compounds was developed via the condensation reaction of ninhydrin with 4-amino-1,2-naphthoquinones or 2-amino-1,4-naphthoquinones in acetic acid followed by the oxidative cleavage of the corresponding vicinal diols at room temperature. Various derivatives of spiro[benzo[g]indole-2,1'-isobenzofuran]-3,3',4,5(1H) tetraones and spiro[benzo[f]pyrrolo[2,3-h]quinoxaline-2,1'-isobenzofuran]-3,3'(1H)-diones were synthesized in good to high yields. Moreover, further condensation of spiro[benzo[g]indole-2,1'-isobenzofuran]-3,3',4,5(1H)-tetraones with 1,2-diamines resulted in the new spiro-isobenzofuran compounds having phenazine rings in high yields.Threatened by the energy crisis and environmental pollution, most countries in the world are vigorously developing new energy vehicles to promote low-carbon environmental protection and boost a green transportation system. Based on the intelligent manufacturing standard system, this study constructed a new energy vehicle intelligent manufacturing development-influencing factor model. this website Taking the intelligent manufacturing development ability as the dependent variable, taking external environment factors, commonalities among the new energy vehicle enterprises, and industry progress as independent variables, five hypotheses are proposed. This study used a structural equation model to test the hypotheses and reveal the mechanism of how factors influence the new energy vehicle intelligent manufacturing. The results show that external environment factors and industry progress directly and positively affect the development capability of intelligent manufacturing of new energy vehicles, while the commonalities among the NEV enterprises have an indirect effect through industry progress on intelligent manufacturing of new energy vehicles. Based on the analysis, this study puts forward some suggestions for better development of new energy vehicle intelligent manufacturing.To solve the problem of thermal runaway is one of the necessary conditions for the commercialization of lithium-ion batteries. In order to further explore the reaction mechanism of thermal runaway of lithium-ion batteries, a thermal model is built by using a variety of side reactions to further study the inhibition of temperature on thermal runaway. The results show that thermal runaway is triggered by the heat generation of negative material reaction when it is heated to 473.15 K; lower heat dissipation temperature (273.15 K) cannot effectively inhibit the occurrence of thermal runaway.

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