Shoremaldonado8688

e power is 3.5 times of that of single-stage hydrocylone FX100. Comprehensive consideration of the processing capacity per unit time and operating power, the hydrocylone FX100 was more suitable for actual operation.In this study, binary and ternary mixed metal oxide anodes of Ti/RuO2-Sb2O4 and Ti/RuO2-Sb2O4-TiO2 were prepared using two different heating methods conventional furnace and alternative CO2 laser heating. The produced anodes were physically and electrochemically characterized by using different techniques. The main difference found in the laser-made anodes was their more compact morphology, without the common deep cracks found in anodes made by typical thermal decomposition, which showed an important correlation with the prolonged accelerated service life. The correlation between the physicochemical properties of the anodes with their performance towards the 4-nitrophenol oxidations is discussed. The results demonstrated that the ternary anode (Ti/RuO2-Sb2O4-TiO2) is very promising, presenting a kinetic 5.7 times faster than the respective binary anode and the highest removal efficiency when compared with conventionally made anodes. Also, the lowest energy consumption per unit of mass of contaminant removed is seen for the laser-made Ti/RuO2-Sb2O4-TiO2 anode, which evidences the excellent cost-benefit of this anode material. Finally, some by-products were identified, and a degradation route is proposed. Graphical abstract.Act Force Gold®, Butaforce®, and Atraforce® are among the most commonly used pesticides in Nigeria. The lethal concentrations and the respective toxic units for the three pesticides were determined. The genotoxic effects of the three pesticides were investigated in the red blood cells of Clarias gariepinus using micronucleus (MN) assay. The 96 h LC50 was 4.75, 4.84, and 54.74 mg L-1 for Act Force Gold®, Butaforce®, and Atraforce®, respectively. The toxic units in ascending order of toxicity were 1.83, 20.66, and 21.05 for Act Force Gold®, Butaforce®, and Atraforce® respectively. The estimated safe levels based on NAS/NAE varied from 4.75 × 10-1-4.75 × 10-5 in Act Force Gold® through 4.64 × 10-1-4.85 × 10-5 in Butaforce® to 5.74-5.74 × 10-5 in Atraforce®. Fish specimens were exposed to the pesticides and sampling was done at regular intervals at days 1, 7, 14, and 21 and after another 7-day recovery period. The results obtained indicated concentration- and duration-dependent increase in % MN formation with maximum values of 3.40 ± 0.25 for Act Force Gold® on day 14 and 3.05 ± 0.36 and 2.35 ± 0.14 for Butaforce® and Atraforce® respectively on day 7 of exposure. The 7-day recovery period could not reverse the trend as the % MN values obtained were significantly different from the control. The results further support the use of MN assay in assessing the toxicity of aquatic pollutants and can be used in the monitoring of aquatic ecosystems.The wastes from the macro-fungus Agaricus bisporus were used as an eco-friendly and low-cost adsorbent for the treatment of colored effluents containing the recalcitrant dyes, acid red 97 (AR97) and crystal violet (CV). The macro-fungal waste presented an amorphous structure, composed of particles with different sizes and shapes. Also, it presents typical functional chemical groups of proteins and carbohydrates with a point of zero charge of 4.6. The optimum conditions for the dosage were found to be as follows 0.5 g L-1 with an initial pH at 2.0 for the AR97 and 8.0 for the CV. From the kinetic test, it was found that it took 210 min and an adsorption capacity of 165 mg g-1 for the AR97. Concerning the CV kinetics, it took 120 min to reach the equilibrium and it achieved an adsorption capacity of 165.9 mg g-1. The Elovich model was the most proper model for describing the experimental data, achieving an R2 ≥ 0.997 and MSE ≤ 36.98 (mg g-1)2. The isotherm curves were best represented by the Langmuir model, predicting maximum adsorption capacity of 372.69 and 228.74 mg g-1 for the AR97 and CV, respectively. The process was spontaneous and favorable for both dyes. The ∆H0 values were 9.53 and 10.69 kJ mol-1 for AR97 and CV, respectively, indicating physical and endothermic adsorption. Overall, the wastes from Agaricus bisporus have the potential to adsorb cationic and anionic dyes, thus solving environmental problems related to water quality and residue disposal.Ambient air pollution is one of the most significant environmental problems, and many individuals around the world die each year prematurely from diseases caused by this type of pollution. PM2.5 can transpire deep to the lungs and induce some dangerous health effects in humans. In this study, the health effects of long-term PM2.5 were estimated on expected life remaining (ELR) and years of life lost (YLL) indices in Ahvaz city during the years 2008-2017 using the AirQ+ software developed by WHO. Values obtained from the PM2.5 averaging, ELR, and YLL data were processed for the whole population in the age range of 0-64 and over 64. These values were entered into AirQ+ software. The mean annual concentration of PM2.5 was highly variable, with the highest concentration being 70.72 μg/m3 in 2010 and the lowest 41.97 μg/m3 in 2014. In all studied years, the concentration of PM2.5 with the variations between 4.2 to 7.07 times was higher than the WHO standard (10 μg/m3). Ahvaz city also did not experience any clean day during the 10-year period, and in 2010, there were 47 very unhealthy days and 27 dangerous days, i.e., the highest number of very unhealthy and dangerous days during the period. Selleckchem Dorsomorphin The results estimated that the highest and lowest YLL in the next 10 years for all ages groups would be 137,760.49 (2010) and 5035.52 (2014), respectively. Also, the ELR index was lower than the Iranian standard and EPA which was significantly correlated with the concentration of PM2.5.This article is devoted to the study of physicochemical parameters and the assessment of the accumulation and distribution of metals in peat deposits from the North European part of Russia (Arkhangelsk region). Peat profiles were selected both in the area with a high anthropogenic load and in a bog remote from industrial pollution. The determination of metals was carried out by using the methods X-ray fluorescence analysis and atomic absorption spectroscopy. It was determined that the studied bogs can be attributed to the low ash type, and the recorded pH and mineralisation values make it possible to attribute these deposits to the acid-oxidising facies of oligotrophic peatlands, characteristic of taiga landscapes. Assessment of metal accumulation showed a high content of titanium, chromium, lead, nickel, vanadium, cobalt, aluminium, silicon, and copper in peat, mainly caused by the burning of fossil fuels and industrial production, as well as the burning of urban and industrial waste. The peat profiles are characterised by significant fluctuations in the content of elements in different horizons.