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We use machine optimization to develop a quantum sensing scheme that achieves significantly better sensitivity than traditional schemes with the same quantum resources. Utilizing one-axis twisting dynamics to generate quantum entanglement, we find that, rather than dividing the temporal resources into separate "state-preparation" and "interrogation" stages, a complicated machine-designed sequence of rotations allows for the generation of metrologically useful entanglement while the parameter is interrogated. This provides much higher sensitivities for a given total time compared to states generated via traditional one-axis twisting schemes. This approach could be applied to other methods of generating quantum-enhanced states, allowing for atomic clocks, magnetometers, and inertial sensors with increased sensitivities.We investigate the microscopic mechanisms of ultralow lattice thermal conductivity (κ_l) in Tl_3VSe_4 by combining a first principles density functional theory based framework of anharmonic lattice dynamics with the Peierls-Boltzmann transport equation for phonons. We include contributions of the three- and four-phonon scattering processes to the phonon lifetimes as well as the temperature dependent anharmonic renormalization of phonon energies arising from an unusually strong quartic anharmonicity in Tl_3VSe_4. In contrast to a recent report by Mukhopadhyay et al. [Science 360, 1455 (2018)SCIEAS0036-807510.1126/science.aar8072] which suggested that a significant contribution to κ_l arises from random walks among uncorrelated oscillators, we show that particlelike propagation of phonon excitations can successfully explain the experimentally observed ultralow κ_l. GSK1059615 cell line Our findings are further supported by explicit calculations of the off-diagonal terms of the heat current operator, which are found to be small and indicate that wavelike tunneling of heat carrying vibrations is of minor importance. Our results (i) resolve the discrepancy between the theoretical and experimental κ_l, (ii) offer new insights into the minimum κ_l achievable in Tl_3VSe_4, and (iii) highlight the importance of high order anharmonicity in low-κ_l systems. The methodology demonstrated here may be used to resolve the discrepancies between the experimentally measured and the theoretically calculated κ_l in skutterides and perovskites, as well as to understand the glasslike κ_l in complex crystals with strong anharmonicity, leading towards the goal of rational design of new materials.We study the quantum fluctuations in a one-dimensional Bose-Einstein condensate realizing an analogous acoustic black hole. The taking into account of evanescent channels and of zero modes makes it possible to accurately reproduce recent experimental measurements of the density correlation function. We discuss the determination of Hawking temperature and show that in our model the analogous radiation presents some significant departure from thermality.Graphite is known to transform into diamond under dynamic compression or under combined high pressure and high temperature, either by a concerted mechanism or by a nucleation mechanism. However, these mechanisms fail to explain the recently reported discovery of diamond formation during ambient temperature compression combined with shear stress. Here we report a new transition pathway for graphite to diamond under compression combined with shear, based on results from both theoretical simulations and advanced experiments. In contrast to the known model for thermally activated diamond formation under pressure, the shear-induced diamond formation takes place during the decompression process via structural transitions. At a high pressure with large shear, graphite transforms into ultrastrong sp^3 phases whose structures depend on the degree of shear stress. These metastable sp^3 phases transform into either diamond or graphite upon decompression. Our results explain several recent experimental observations of low-temperature diamond formation. They also emphasize the importance of shear stress for diamond formation, providing new insight into the graphite-diamond transformation mechanism.Polar molecules in superpositions of rotational states exhibit long-range dipolar interactions, but maintaining their coherence in a trapped sample is a challenge. We present calculations that show many laser-coolable molecules have convenient rotational transitions that are exceptionally insensitive to magnetic fields. We verify this experimentally for CaF where we find a transition with sensitivity below 5  Hz G^-1 and use it to demonstrate a rotational coherence time of 6.4(8) ms in a magnetic trap. Simulations suggest it is feasible to extend this to more than 1 s using a smaller cloud in a biased magnetic trap.It is well established that the ground states of a two-dimensional electron gas with half-filled high (N≥2) Landau levels are compressible charge-ordered states, known as quantum Hall stripe (QHS) phases. The generic features of QHSs are a maximum (minimum) in a longitudinal resistance R_xx (R_yy) and a nonquantized Hall resistance R_H. Here, we report on emergent minima (maxima) in R_xx (R_yy) and plateaulike features in R_H in half-filled N≥3 Landau levels. Remarkably, these unexpected features develop at temperatures considerably lower than the onset temperature of QHSs, suggestive of a new ground state.Balancing nonlinear gain and loss automatically generates sub-Poissonian light, through negative feedback, when the gain is significantly reduced (increased) by the addition (subtraction) of a single photon. We show that micromaser trapping states can provide the necessary feedback in the presence of photon loss and, with the addition of external parametric control, realize a photon number on the order of 100 and a Mandel Q parameter of -0.998, i.e., number squeezing of 27 dB.The so-called stellar formalism allows us to represent the non-Gaussian properties of single-mode quantum states by the distribution of the zeros of their Husimi Q function in phase space. We use this representation in order to derive an infinite hierarchy of single-mode states based on the number of zeros of the Husimi Q function the stellar hierarchy. We give an operational characterization of the states in this hierarchy with the minimal number of single-photon additions needed to engineer them, and derive equivalence classes under Gaussian unitary operations. We study in detail the topological properties of this hierarchy with respect to the trace norm, and discuss implications for non-Gaussian state engineering, and continuous variable quantum computing.

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