Postmullen5737

This reports recent advances on CO2 capturing methods, focusing on chemical looping combustion (CLC) as a promising technology to achieve this goal. check details Generally, there are three main methods to capture CO2 resulting from fossil fuel combustion post-combustion, oxy-combustion, and pre-combustion. In CLC, which is either classified as a pre-combustion method or as the fourth capturing method, the solid oxygen carrier provides the oxygen needed for combustion. This technique helps to avoid diluting the combustion effluent stream with the N2 released from air and therefore, minimizes the requirement of CO2 separation, a major cost of CO2 capture. In addition, it minimizes the formation of NOx that results when N2 comes in contact with oxygen and fuels at high temperatures. The desired properties of oxygen carrier candidates for CLC are high reduction and re-oxidation rates, high oxygen capacity, good stability and fludiziability at high temperatures, friendly to the environment, and low cost. Transition metal oxides are common candidates for CLC. Most investigations in this field have examined the reactivity and stability of oxygen carriers but few investigations have focused on their reduction and re-oxidation reaction mechanisms. Researchers have proposed two mechanisms for these reactions, the nucleation-nuclei growth and unreacted shrinking core models. Despite numerous investigations of CLC, there is still a lack of knowledge in some of its aspects such as the underlying surface chemistry and the economic impact. This work critically reviewed all capturing methods of CO2 with focusing on CLC process as a promising technology due to its ability to concentrate the resulted CO2 and minimizes the separation cost. This work provides essential insight information into CLC technology and highlights its status and needs.The occurrence of 209 PCB congeners was determined in a sediment core dated between 1930 and 2019 from Lake Biwa, a typical temperate monomictic lake in Japan. Concentrations of total PCBs ranged from 5.3 to 48 ng/g dry weight (dw), showing a highest peak at the 1960s to 1970s. The temporal trend of total PCBs in this sediment core generally matched with Japanese PCB production and emission pattern (i.e., increasing from the 1950s, peaking at 1970, and gradually decreasing since 1972). The vertical PCB profiles in our core were affected by physical mixing and bioturbation. By using a detailed and comprehensive analytical method, we have found elevated concentrations and special historical profiles of several congeners such as CB-7, -11, -47/48/75, -51, -68, and -209, which are still rarely included in routine PCB analysis. Some tetra-CB congeners like CB-47/48/75, -51, and -68 showed their concentration peaks at the early 2010s, which may be unintentionally produced during polymer manufacturing processes. PCB homolog- and congener-specific profiles in our sediment core samples have experienced weathering with higher proportions of penta- and hexa-CBs as compared to the Kanechlor usage pattern (i.e., dominated by tri- and tetra-CBs). Both intentional (i.e., technical mixtures) and unintentional (e.g., PCB-containing polymers and pigments) sources of PCBs were suggested from congener-specific analysis.Estimation of groundwater recharge is considered crucial for the management of groundwater resources. The groundwater level fluctuation (GLF) method is a widely used approach to estimate groundwater recharge due to its simplicity and ease of implementation. However, the main source of uncertainty is the specific yield for the GLF method. Although there have been a lot of methods for determining specific yield, the performance of specific yield on the estimation of recharge remains unclear. We set up three lysimeters with different water table depths in the Guanzhong Basin, China. Soil moisture content along with the soil profile, water table depths, and rainfall data were measured continuously. These data provide us with accurately observed recharge and allow us to analyze the performance of specific yields from different methods in estimating recharge. The main results are (1) The constant specific yield from the pumping tests, which is equal to the ultimate specific yield, significantly overestimated the observed recharge rates independent of water table depths. (2) The constant specific yield obtained from saturated soil moisture content minus field capacity tended to overestimate recharge under the shallow water table depths (less than 2 m), and vice versa; (3) The depth-dependent specific yield using the measured soil moisture content along with soil profile can obtain reliable recharge across all water table depths. (4) The accuracy of the depth-dependent specific yield obtained by the soil water retention curve relies on reliable parameters. The parameters α and n have to be taken into account carefully for determing the specific yield. Our results are important for the application of the GLF method to estimate recharge. More importantly, it is valuable for the sustainable management of groundwater recourses.The threat posed by invasive non-native species worldwide requires a global approach to identify which introduced species are likely to pose an elevated risk of impact to native species and ecosystems. To inform policy, stakeholders and management decisions on global threats to aquatic ecosystems, 195 assessors representing 120 risk assessment areas across all six inhabited continents screened 819 non-native species from 15 groups of aquatic organisms (freshwater, brackish, marine plants and animals) using the Aquatic Species Invasiveness Screening Kit. This multi-lingual decision-support tool for the risk screening of aquatic organisms provides assessors with risk scores for a species under current and future climate change conditions that, following a statistically based calibration, permits the accurate classification of species into high-, medium- and low-risk categories under current and predicted climate conditions. The 1730 screenings undertaken encompassed wide geographical areas (regions, political end/or sale as ornamental or aquarium/fishery enhancement.