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88877 at p less then 0.01. Therefore, citrate had a systemic radiative effect on every aspect of the SRB‒citrate system model for Cr(Ⅵ) removal. In addition to the reduction in the former simple model, an integrative effect (including adsorption, sedimentation, and metabolism) was combined with NaFeS2 for Cr removal, which was regulated by the SRB‒citrate system. Exploration and understanding of these mechanisms promote SRB‒citrate methods to be wider implications in practice.Phytoremediation of copper contaminated soil poses particular difficulties because of the low Cu mobility in the soil. Although several plant species, such as willows or Brassicaceae, have been used in the phytomanagement of abandoned brownfields, certain trace elements, such as copper often remain difficult to treat or remove from contaminated soils. An experiment was conducted under semi-controlled conditions to test the phytoremediation potential of co-planting two crop species, Brassica napus L. and Salix nigra 'S05', in soil spiked with two concentrations of Cu (500 mg kg-1 and 800 mg kg-1). Particular attention was given to the potential of 1) the co-plantation design and 2) uprooting, to efficiently mimic the remediation of a Cu-contaminated soil. Results showed that most Cu was found in plant roots and that the polyculture treatment produced the most overall biomass and maximum stabilization and extraction of Cu of the three treatments tested, regardless of contamination level.Clean water, the elixir of life, is of tremendous importance in achieving environmental sustainability and the balanced functioning of our ecosystem. Coupled with population growth, several anthropogenic activities and environmental catastrophes have together contributed to an alarming increase in the concentration of toxic pollutants in water bodies. Diversified physiochemical conditions of water matrices, ranging from mining drainage to seawater, is the critical challenge in designing adsorbents. MXenes, a new class of 2D layered materials, are transition metal nitrides, carbides, carbonitrides or borides formed through selective etching process. MXenes are known to have high surface area and activity with biological compatibility and chemical stability and therefore are promising adsorbents and have been explored for a broad range of contaminants. This review starts with a brief about environmental contaminants followed by synthesis and modifications of MXenes. It then revolves around their so far explored adsorbing and degradation properties for different contaminants ranging from toxic metals, inorganic ions, and radionuclides to various organic pollutants, including dyes, pharmaceuticals, aromatic hydrocarbons, and pesticides, etc. Finally, we have discussed associated toxicity, secondary contamination, future trends, and challenges in ascertaining scalability and wide-range applicability of MXenes in natural environmental conditions to make them a warrior of water sustainability.High concentrations of mercury (Hg) have been documented in deep-water fish species from some Norwegian fjords. In this study, tusk (Brosme brosme) was sampled from four locations in the innermost parts of Sognefjorden in Western Norway. Total Hg and methylmercury (MeHg) levels were measured in liver tissue. To search for potential sublethal effects of Hg, we characterized the hepatic transcriptome in tusk with high and low levels of Hg bioaccumulation using global transcriptomics analysis (RNA-seq). The results showed that there was a significant correlation between fish weight and accumulated concentrations of MeHg but not total Hg. MeHg accounted for 30-40% of total Hg in liver of most of the fish, although at concentrations above 2-3 mg Hg/kg wet weight the percentage of MeHg dropped considerably. Transcriptome analysis resulted in hundreds of differentially expressed genes in the liver of tusk with high Hg levels. Functional enrichment analysis suggested that the top affected pathways are associated with protein folding, adipogenesis, notch signaling, and lipid metabolism (beta-oxidation and phospholipids). Based on transcriptional responses pointing to well-known effects of Hg compounds in fish, the study suggests that tusk in Sognefjorden could be negatively impacted by Hg bioaccumulation.A novel porous loofah-sponge-like ternary heterojunction g-C3N4/Bi2WO6/MoS2 (CN-BM) was prepared via a facile method. The introduction of binary Bi2WO6/MoS2 into g-C3N4 could be qualified for constructing reasonable heterostructure while regulating photocatalysts morphology. Benefiting from the unique structure, the ternary heterojunction composites not only inhibited the agglomeration but also exhibited the prominent visible-light harvest capacity and abundant active sites, which could accelerate the photogenerated carriers separation and preserve the robust redox ability. The results showed that the optimized sample (CN-BM2) displayed the excellent degradation efficiency of sulfamethoxazole (SMX) under visible-light irradiation (over 99% within 60 min), and the fitted pseudo-first-order kinetic rate constant reached to 0.089 min-1, where it was 3.17 times than that of pure CN. Additionally, the radical scavenger experiments and electron spin resonance experiments indicated that the active species super-oxide radical and hole played a major role in the degradation experiment. NF-κB inhibitor The charge transfer mechanism was proposed and the main intermediates indicated that the active radicals attacked on the benzene ring and isoxazole ring in SMX, and further mineralized to inorganic molecules eventually.A collection of six commercially available, 3D printer filaments were analyzed with respect to their gas-phase emissions, specifically volatile organic compounds (VOCs), during simulated fused filament fabrication (FFF). Filaments were chosen because they were advertised to contain metal particles or carbon nanotubes. During experimentation, some were found to contain other non-advertised additives that greatly influenced gas-phase emissions. Three polylactic acid (PLA) filaments containing either copper, bronze, or stainless steel particles were studied along in addition to three carbon nanotube (CNT) filaments made from PLA, acrylonitrile-butadiene-styrene (ABS), and polycarbonate (PC). The metal-additive PLA filaments were found to emit primarily lactide, acetaldehyde, and 1-chlorododecane. The presence of metal particles in the PLA is a possible cause of the increased total emissions, which were higher than any other PLA filament reported in the literature. In addition, the filament with stainless steel particles had a threefold increase in total VOCs compared to the copper and bronze particles.

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