Vestpilegaard8521

In addition, histological lesions were found in the liver, intestine, and gill of the exposed fish. The severity of lesions showed a size and dose-dependent pattern. Polystyrene induced the antioxidant system of exposed fish through elevating the levels of SOD and CAT activity and significant difference in expression of antioxidant related genes (CAT, SOD and HSP70). In conclusion, the results of the present study confirmed the toxic effects of microplastic, polystyrene on goldfish.In this study, the adsorption of cesium (Cs) on biotite and dissolution of Cs from Cs-bearing biotite using a siderophore were investigated aiming to contribute to the elucidation of radiocesium migration mechanisms in the soil environment. Thus, a siderophore was extracted and purified from the culture medium of Pseudomonas sp., and the purified siderophore was used in five consecutive dissolution experiments of biotite samples. Prior to the dissolution experiments, Cs was adsorbed on a hardly weathered biotite powder sample. The major components of the biotite (Al, Fe, and Mg) were dissolved almost stoichiometrically, strongly suggesting that the siderophore selectively dissolves the broken edges of the biotite. The amount of the dissolved Cs decreased by increasing the repetition times of the dissolution experiment. Therefore, the Cs adsorbed on the broken edges was dissolved rapidly as the siderophore dissolved the broken edges, and then, the Cs adsorbed on the outer planar surface of the biotite particles was slowly dissolved because the siderophore did not directly dissolve the outer planar surface of the biotite but dissolved the surface edge.The usual treatment for Cr(VI)-contaminated wastewater primarily included reduction, adsorption, and the subsequent separation of the Cr-laden adsorbent. Among these factors, the adsorbent is the most critical factor in determining Cr removal efficiency. In this study, a novel melamine-formaldehyde-thiourea (MFT) chelating resin/mesoporous silica composite material (MFT/SBA-15) was synthesized via a co-condensation method and used for the reduction and fixation of Cr(VI)-contaminated water. Cr(VI) adsorption onto MFT/SBA-15 obeyed the pseudo-second-order model, and the chemical adsorption was the rate-limiting step in the adsorption process. Also it followed the Langmuir adsorption model, with single molecular layer adsorption characteristics. The organic components within MFT/SBA-15 were the core functional groups for Cr(VI) adsorption, and the formation of a coordination bond (CS→Cr) between the lone electron pairs of the S atom and Cr during the adsorption process led to the synchronous reduction-fixation processes of Cr(VI). These synchronous effects were further demonstrated for other reducible heavy metals, including As(V) and Cu(II), but negligibly observed in chemically stable elements, such as Zn(II), Ni(II), Pb(II), Cd(II), and As(III). The novel mesoporous MFT/SBA-15 materials combine the advantages of the chelating resin and mesoporous silica and have excellent potential for the wastewater treatment of reducible heavy metals through synchronous reduction-fixation.Bisphenol analogues (BPs) are widely applied in varying consumer products. Many studies have reported their presence in indoor dust samples from China. However, the differences in occurrence and concentration profiles of BPs in indoor dust between rural and urban areas are still not well characterized. In this study, eight BPs were measured in 60 indoor dust samples collected from rural and urban districts of Hangzhou, China. Bisphenol A (BPA; mean 1.8 μg/g, range 0.20-7.2 μg/g) was the predominant BP in indoor dust samples, accounting for mean 57% of the total BP (∑BP) concentration, followed by bisphenol S (BPS; 0.58 μg/g, less then LOD-2.4 μg/g) and bisphenol AF (0.43 μg/g, less then LOD-2.6 μg/g). Indoor dust samples from the urban areas (n = 27) contained significantly (p less then 0.05) higher levels of ∑BPs, BPA, and BPS than that from the rural areas (n = 33). Comparatively, bisphenol F and bisphenol AP were more frequently detected in urban indoor dust samples. Daily intakes (DIs) of BPs through the indoor dust inhalation were estimated for infants, children, and adults. Infants had much higher (p less then 0.01) DIs of BPs than children and adults, mainly owing to their lower body weights and higher indoor dust ingestion rates. To our knowledge, this is one of the first studies examining the regional differences of BP concentrations in indoor dust from China, which could contribute to the more accurate evaluation of human BP exposure through indoor dust intake.Biosorbent from pods of Arachis hypogaea (AhP) were inducted with sulphuric acid treatment and then the activated materials were employed to sequester a sulphonated textile dye; Reactive Orange 16 (RO16) from water system. The characteristic features of the surface functionalized AhP (Ct-AhP) were analysed using instrumentation techniques. The biosorption influencing variables like operating pH, agitating time, initial RO16 concentration and temperature effects were investigated. One-factor optimization revealed that 0.5 g Ct-AhP was sufficient to achieve maximum removal of RO16 (20-120 mg/L) within 180 min agitation at 150 rpm. The isotherm data were applied to non-linear isotherms viz., Freundlich, Langmuir and Temkin models as well as rate limiting steps were elucidated using kinetic models. Freundlich isotherm showed good fit and pseudo-second order kinetic data explained RO16 removal by Ct-AhP followed chemisorption. The outcome of thermodynamic parametric values infer that RO16 biosorption was spontaneous, feasible and involved exothermic type of heat. Elovich and intraparticle diffusion revealed the biosorption mechanisms. The maximum RO16 biosorption (56.48 mg/g) by 0.5 g Ct-AhP were witnessed in the system containing 120 mg/L RO16 agitated at 150 rpm operating at pH 7.0, 303 K for a span of 180 min. Thus, the Ct-AhP is considered to be a promising biosorbent which can be employed in treating the textile effluents.Metabolomics represents a powerful tool for measuring environmental exposures and biological responses to unveil potential mechanisms. Few studies have investigated the effects of exposure to fine particulate matter (PM2.5) longitudinally on serum metabolomics in regions with high-level PM2.5. Therefore, we examined the changes of serum metabolomics corresponding to individual PM2.5 exposure levels in spring and autumn among 63 healthy college students in Baoding city, Hebei, China. The metabolic profiling was determined by ultra-performance liquid chromatography coupled to quadrupole time-of-flight mass spectrometry. selleck chemicals llc The average level of individual PM2.5 in the spring was 1.82-fold higher than in the autumn (240 μg/m3 vs 132 μg/m3). Males were exposed to a higher level of PM2.5 than females in the spring. Metabolic profiling was clearly separated by orthogonal partial least square-discriminant analysis in males but not in females. In the analysis of the associations between the metabolome and PM2.5 of the two seasons, the changes of 14 serum metabolites were significantly associated with PM2.