Bellstrauss3645

Social media data are increasingly utilised as a low-cost alternative to visitor surveys in characterising nature-based recreation. However, the information available on individual users is limited and typically does not include provenance, restricting the potential applications and impact of the data. Here we investigate a methodology to estimate social media visitors' home locations at various spatial scales and apply it to the entire network of national parks in Germany. We compare predicted visitor provenance to representative onsite survey data and explore group-specific spatial and temporal patterns of recreation as characterised by users' geotagged photographs. Results show that photograph metadata can be used to assign home locations with accuracies between 62 and 89% depending on spatial scale implemented. Said social media-based predictions are reasonably well representative of the surveyed visitor structure in German national parks with Flickr visitor-days composed of 19% local, 62% non-local German and 19% international visits.Drinking water containing excess fluoride is a major health concern across the globe. buy TG101348 The present study reports the feasibility of zirconium impregnated hybrid anion exchange resin (HAIX-Zr) for treating fluoride contaminated groundwater. The HAIX-Zr resin was prepared by impregnating ZrO2 nanoparticles on polymeric anion exchanger resin. Fluoride uptake by HAIX-Zr was quite rapid, 60% removal was obtained within 30 min. Kinetics of fluoride uptake by HAIX-Zr resin followed the pseudo-second-order kinetic model and adsorption data fitted best to Freundlich adsorption isotherm model. Maximum fluoride uptake capacity was observed as 12.0 mg/g. The defluoridation capacity of the resin decreases with increase in solution pH. The co-existing anions like chloride, phosphate, bicarbonate, nitrate, and sulphate at 100 mg/L concentration significantly affected fluoride removal and bicarbonate showed the highest interference. Continuous flow packed bed experiments were performed with real groundwater. To maintain a lower pH, weak acid cation exchange resin (INDION-236) was used before HAIX-Zr. It was observed that reducing the pH of the sample water to 4-4.5, increased the number of treated bed volumes fifteen times. Regeneration of fluoride-containing resin was done by passing 3% NaOH and 3% NaCl solution through an exhausted resin bed. The results revealed that HAIX-Zr can effectively remove fluoride from groundwater.Degradation of ecosystems and the related loss of ecosystem services have called for new policies to achieve no net loss (NNL) of or even net gain between detrimental environmental impacts and restoration or preservation measures. While biodiversity offsetting has a long tradition, soils have rarely been considered in the accounting. Considering the crucial role of soil for ecosystem functioning and biodiversity and the increasing pressure on soil resources, we investigate how a NNL strategy building on a soil-based ecosystem services index can help steer sustainable spatial development. An ecosystem services' soil quality index allows to explicitly address the interests of a broad range of stakeholder on soil uses. Using a market-driven spatial planning instrument based on a land price fee linked to the soil quality index, we demonstrate how soil quality loss and related ecosystem services could be reduced by up to 60% compared to current practice in a case study in Switzerland. More importantly, the suggested instrument allows to account for the spatial variability of the supply of the ecosystem services and the diversity of stakeholder demands for various soil qualities. We close with a discussion on the consequences of implementing a soil-based NNL strategy for spatial development and its generic application for steering settlement development.In this study, we prepared Ti4O7 porous electrodes with continuous layered structures characterized by different layer-to-layer distance (from 2 to 10 μm) but the same total void fraction (88-90%), to modulate the electrodes' permeability and the volumetric electrochemical surface area (from 90 to 840 cm2 cm-3). These platforms were evaluated as anodes in the electro-oxidation (EO) of bentazon in a three-electrode cell under galvanostatic conditions, operated both in traditional batch (TB) or batch recycle flow-through (BRFT) modes. The performance was significantly enhanced when the liquid was recirculated through the lamellar structure of the electrodes. In BRFT mode, the electrode interlayer gap was found to be a key factor to control the bentazon and total organic carbon (TOC) conversions. For the best conditions evaluated (BRFT, 10 μm-interlayered Ti4O7 electrodes with a volumetric surface area of 90 cm2 cm-3), the effect of the applied current (1 or 3 mA) and liquid flow rate (10, 12 or 14 mL. min-1) was investigated. Specific energy consumption (SEC) values were estimated to reveal the performance of each of the EO treatments from an energetic point of view. The use of 10 μm-interlayered Ti4O7 electrodes at 1 mA in BRFT mode at a flow rate of 14 mL min-1 showed the best results, yielding 85% bentazon removal, 57% mineralization and SEC values of 0.006 kWh.gTOC-1 after 6 h of treatment. This contribution highlights the use of layered Ti4O7 electrodes as a promising strategy for intensifying EO processes, pointing to a trade-off between the accessibility to the internal electrode structure and the volumetric electrode surface area to enhance the contact between the target molecules and the hydroxyl radicals physisorbed on the electrode surface, while minimizing simultaneously the energy requirements.One of the main drawbacks of upflow anaerobic sludge blanket (UASB) reactors that treat low-strength sewage at room temperature is related to the low quality of their effluents in terms of dissolved methane, organic matter, and nitrogen content. The present study aims to evaluate the feasibility of using an integrated fixed-film activated sludge (IFAS) system as an alternative post-treatment technology to mitigate the environmental impact of such effluents. For this purpose, a pilot plant composed of a UASB (120 L) followed by an IFAS (66 L) system was operated for 407 days. Special attention was paid to the suspended biomass retention capacity and the dissolved methane and nitrogen removal potential of the IFAS post-treatment system. Furthermore, the role of carriers on denitrification and nitrification processes and the microbial communities present in the biofilm were also analyzed. Average total chemical oxygen demand (CODT) and ammonium removal efficiencies of 92 ± 3% and around 57 ± 16% were attained throughout the entire operation, respectively.