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Several studies show that the elemental content of honey entirely depends on the botanical and geographical origin, but the information is incomplete regarding its time-dependent composition changes. Twenty-six acacia and three honey samples with unknown botanical origin were collected between 1958 and 2018 and analysed for elemental composition by Microwave Plasma Atomic Emission Spectrometry (MP-AES). The elemental analysis was coupled with independent dating method by Accelerator Mass Spectrometry (AMS) to confirm the calendar age of the honey samples and test the possibility of radiocarbon based dating of bee products, which has not been applied before. Selleck Ertugliflozin According to the analytical measurements and statistical analysis, we can conclude that the elemental composition shows change with time in the acacia honey during the last five decades. We have proven that honey preserves carbon isotopic and elemental information of its production time and thus can be applied as an environmental indicator (e.g. trace urban pollutants, precipitation, local industrial or agricultural emission) in reconstruction studies by analysing the non-degradable mineral content. Our results further show that acacia honey is a suitable material for radiocarbon dating, proved by the results compared to the atmospheric radiocarbon bomb-peak. The new approach presented for investigation of honey by radiocarbon-based age determination coupled with elemental analysis can be used in biological, dietary, archaeological or other multidisciplinary studies as well. Some samples show slightly depleted radiocarbon content. This could be an indication of local fossil CO2 emission. Based on these depleted 14C results, honey could be used for atmospheric monitoring of fossil CO2 urban or industrial hot-spots.MHC-1 is a halogenated natural product (HNP) produced by the red seaweed Plocamium cartilagineum. MHC-1 concentrations of 550-2700 μg/g dry weight were found in Plocamium collected by divers at Heligoland (Germany). Compared to that MHC-1 concentrations were much lower in samples collected on beaches in Ireland and Portugal. Exposure of leaves of Plocamium to sunlight showed that MHC-1 was readily transformed by hydrodebromination. At Heligoland in March, MHC-1 (δ13C value -45.2‰) was lighter in carbon by ~15‰ compared to the bulk δ13C value (‰) of Plocamium (-30.7‰). Collected at the same time and location at Heligoland, samples of Halichondria and Mastocarpus sp. were richer in carbon (by ~10‰) as Plocamium. However, the δ13C value of MHC-1 in Halichondria (-44.6‰) and Mastocarpus sp. (-42.1‰) was as negative as in Plocamium. This was indirect proof that MHC-1 was produced by Plocamium and then released into the water phase from where it then was bioconcentrated by Halichondria and Mastocarpus sp. In agreement with that, concentrations of MHC-1 in Halichondria and Mastocarpus sp. were much lower than in Plocamium. In addition, a potential isomer of MHC-1 (compound X) was detected in all samples from Heligoland at ~2% of the MHC-1 level.There is growing evidence that river temperatures are increasing under climate change, which is expected to be exacerbated by increased abstractions to satisfy human water demands. Water temperature research has experienced crucial advances, both in terms of developing new monitoring and modelling tools, as well as understanding the mechanisms of temperature feedbacks with biogeochemical and ecological processes. However, water practitioners and regulators are challenged with translating the widespread and complex technological, modelling and conceptual advances made in river temperature research into improvements in management practice. This critical review provides a comprehensive overview of recent advances in the state-of-the-art monitoring and modelling tools available to inform ecological research and practice. In so doing, we identify pressing research gaps and suggest paths forward to address practical research and management challenges. The proposed research directions aim to provide new insights into spatio-temporal stream temperature dynamics and unravel drivers and controls of thermal river regimes, including the impacts of changing temperature on metabolism and aquatic biogeochemistry, as well as aquatic organisms. The findings of this review inform future research into ecosystem resilience in the face of thermal degradation and support the development of new management strategies cutting across spatial and temporal scales.The nitritation step is essential when the anammox process is focused, and alternative technologies to achieve partial nitritation-anammox are required. Rotating Biological Contactors (RBCs) are a promising and cost-effective technology, allowing the development of aerobic and anoxic zones in the biofilm, coupled to low energy consumption. This study evaluated nitritation in a RBC with two discs rotation strategies continuous and intermittent. Continuous rotation resulted in high dissolved oxygen (DO) concentrations and was not favorable for achieving stable nitritation. However, intermittent rotation, coupled with a nitrogen load of 1000 g N·m-3·d-1 and a HRT of 12 h, decreased DO by 77.8% and resulted in nitritation efficiencies of 45.3%. FISH analyses suggested that simultaneous partial nitritation/anammox (PN/A) could also be favored. These results indicated that intermittent rotation may be a core strategy for producing an anammox-suitable effluent or even to promote PN/A in RBCs, upgrading their applicability for wastewater treatment.Portmán Bay is one of the most contaminated and chronically impacted coastal marine areas of the world. Here, from the 1957 to 1990, about 60 million tons of mine tailings from the processing of sulfide ores were dumped directly at the shoreline. The resulting deposit provides a unique opportunity to assess the impact of mine tailings on coastal marine ecosystems after ca 30 years since the discharge has ceased. We investigated meiofaunal abundance, biomass and biodiversity along a gradient of metal concentration that overlaps with a bathymetric gradient from 30 to 60 m depth. Despite the localized presence of extremely high concentration of metals, the bay was not a biological desert, but, nevertheless, was characterized by evident signs of impact on benthic diversity. Meiofaunal variables increased significantly with decreasing metal contamination, eventually reaching values comparable to other uncontaminated coastal sediments. Our results show that mine tailings influenced the spatial distribution of meiofaunal taxa and nematode species composition.

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