Mirandabattle9301

22E-03, 3.89E-04 and 2.64E-04, respectively. Two side production chains (grapeseed oil and tartrate production) were included and circular patterns were designed and introduced in the traditional production chain with the aim of valorising the winery residues and improving the overall environmental performance. By implementing the circular approach, environmental impacts in the global warming, freshwater eutrophication and mineral resource scarcity impact categories, in particular, resulted three times lower than in the linear system. The results achieved demonstrated that closing the loops in the wine industry, through the reuse of bio-based residues alternatively to fossil-based inputs within the production process, and integrating the traditional production system with new side production chains led to an upgrade of the wineries to biorefineries, towards more sustainable production patterns.Forest soils in the warm-humid tropics significantly contribute to the regional greenhouse gas (GHG) budgets. However, spatial heterogeneity of GHG fluxes is often overlooked. Here, we present a study of N2O and CH4 fluxes over 1.5 years, along a topographic gradient in a rainforest catchment in Xishuangbanna, SW China. From the upper hillslope to the foot of the hillslope, and further to the flat groundwater discharge zone, we observed a decrease of N2O emission associated with an increase of soil water-filled-pore-space (WFPS), which we tentatively attribute to more complete denitrification to N2 at larger WFPS. In the well-drained soils on the hillslope, denitrification at anaerobic microsites or under transient water-saturation was the potential N2O source. Negative CH4 fluxes across the catchment indicated a net soil CH4 sink. As the oxidation of atmospheric CH4 is diffusion-limited, soil CH4 consumption rates were negatively related to WFPS, reflecting the topographic control. Our observations also suggest that during dry seasons N2O emission was significantly dampened ( less then 10 μg N2O-N m-2 h-1) and CH4 uptake was strongly enhanced (83 μg CH4-C m-2 h-1) relative to wet seasons (17 μg N2O-N m-2 h-1 and 56 μg CH4-C m-2 h-1). In a post-drought period, several rain episodes induced exceptionally high N2O emissions (450 μg N2O-N m-2 h-1) in the groundwater discharge zone, likely driven by flushing of labile organic carbon accumulated during drought. Considering the global warming potential associated with both GHGs, we found that N2O emissions largely offset the C sink contributed by CH4 uptake in soils (more significant in the groundwater discharge zone). Our study illustrates important topographic controls on N2O and CH4 fluxes in forest soils. With projected climate change in the tropics, weather extremes may interact with these controls in regulating forest GHG fluxes, which should be accounted for in future studies.Arsenic (As) contamination in mangrove wetlands has become a major concern. However, the impact of As on mangroves and the rhizospheric mechanism remains unclarified. In this study, various properties and responses of mangrove seedlings were investigated after exposure to arsenite (As3+). The results indicate that low-level As promoted the secretion of Low-molecular-weight organic acids (LMWOA, 4.5-6.59 mg/kg root in dry weight) and Fe plaque formation in their rhizospheres. Citric, oxalic, and malic acid were the three main components (84.3%-86.8%). Low-level As (5 and 10 μmol/L) also inhibited the rate of radial oxygen loss (ROL) but increased the accumulation of plant As (stem > leaf > root) and plaque As (0.23-1.13 mg/kg root in dry weight). We selected model LMWOAs to further examine As migration and speciation over time in As-enriched sediments (0, 20 and 40 mg/kg). The results reveal that LMWOAs promoted sediment As mobilisation and followed the order of citric acid > malic acid > oxalic acid. The hydrolysis and precipitation of Fe3+ and the complexation with organic ligand led to aqueous As and Fe sedimentation and, conversely, increased solution pH and re-translocated free As. The tolerance mechanisms include lowering ROL, translocating As and releasing LMWOAs to reduce its toxicity, and facilitating the fixation in sediment of oxidised As. The present study highlights the fact that mangroves are potentially favourable for As phytoextraction, removal and detoxification.Exposure to household air pollution from solid fuels (HAP) is associated with stroke. However, few studies have assessed stroke burden attributable to HAP globally and made comparisons across countries. We aimed to estimate the spatiotemporal trends in stroke burden and mortality attributable to household air pollution from solid fuels (HAP) in 204 countries and territories from 1990 to 2019. Data on stroke burden and mortality attributable to HAP from 1990 to 2019 were obtained from Global Burden of Disease Study 2019. We estimated the numbers and age-standardized rates (ASRs) of stroke disability-adjusted life years (DALYs) and mortality (ASDR and ASMR) by sex, age, and subtype, at global, regional, and national levels. Estimated annual percentage change (EAPC) was calculated to evaluate the temporal trends in ASDR and ASMR from 1990 to 2019. In 2019, globally, 14.7 million DALYs and 0.6 million deaths were caused by stroke attributable to HAP. The corresponding ASDR and ASMR increased with age, were highesries, continued efforts on HAP control are needed to reduce related stroke burden, especially in those countries with increased trends.Karst groundwater is crucial, but particularly vulnerable to contaminants. Anthropologically derived pollutants on the surface-environment in karst areas could easily and rapidly enter groundwater through highly developed transmissible structures and threaten water safety. learn more To investigate such transport, we analyzed 24 organochlorine pesticides (OCPs) in the multimedia environment from the Zigui karst area of China, where agriculture is the predominant human activity. OCPs were frequently detected with the total OCP concentrations ranged from 228 to 7970 pg/g, 300 to 32,200 pg/L, 318 to 2250 pg/L, 149 to 2760 pg/g, and 752 to 12,000 pg/g in the soil, spring water, river water, spring sediment, and river sediment, respectively. HCB and p,p'-DDT were the most dominant OCP species. Isomeric and metabolic ratios indicated fresh inputs of Lindane, technical DDT, and Aldrin, although they have been banned in China. The spatial distributions, correlation analysis, and regression analysis suggested rapid OCP transport from the soil to the spring water, and from the soil and spring water to river water.