Gustafssonholck1910

The widespread deterioration of our water systems requires new wastewater treatment technologies to ensure environmental protection. Conventional wastewater treatments were not designed for, and are therefore ineffective, at removing contaminants of emerging concern (CECs) such as pharmaceuticals, personal care products, pesticides, and industrial chemicals. Furthermore, treatment processes capable of breaking down CECs may produce toxic transformation products more harmful than the parent chemicals. Heterogeneous photocatalytic ozonation provides a promising option with high degradation and mineralization of organic compounds. The aim of the present paper is to review ecotoxicity reduction in water treated by heterogeneous photocatalytic ozonation as a measure of process viability. The discussion investigates changes in toxicity based on a variety of toxicity tests performed to evaluate potential effects on ecosystems, the types of catalysts and radiation sources used, the nature of the target contaminants, investigate immobilized catalysts and energy efficient radiation sources (i.e. solar and LEDs) for industrial applications.The increasing concern over bisphenol A (BPA) has directed much attention toward bisphenol F (BPF) and bisphenol S (BPS) as BPA alternatives for the development of "BPA-free" products. PACAP 1-38 Consequently, BPS and BPF were frequently detected in surface water, sediment, sewage effluent, indoor dust, and even in food and biological fluids in humans. Thus, environmental researches start to focus on the potential environmental risks of BPA alternatives. While the estrogenically active metabolites and the specific estrogenically active structure are still unknown. In this study, the MTT assay on acute cytotoxicity and the recombinant transactivation assay were carried out to determine whether BPF and BPS are suitable alternatives to BPA. Our results show that the cytotoxic and estrogenic activities of BPS and BPF are lower than those of BPA. However, after the addition of a rat liver homogenate to simulate mammal metabolism, BPF exhibited higher estrogenic activity than BPA. To identify the chemical structures and estrogen receptor binding affinities of active estrogenic metabolites, LC-MS, MetaPrint2D(-React), and VirtualToxLab were integrated. The observed results indicated that the para-hydroxylated BPF and BPF-OCH3 might have strong ER binding affinities. These results demonstrate that metabolization is important to consider upon investigating endocrine disruption of chemicals getting into contact with humans, such as in dental sealing or food packaging. Alternatives to potentially hazardous substances should be thoroughly tested prior to use.Tropical climate generally causes long-period of high temperature, relative humidity, and frequent monsoon rainfalls. In combination with airborne salinity, tropical countries usually experience severe corrosion of steel structure. Chloride is a major marine aerosol accelerating corrosion. A study on chloride distribution within 0-5 km from the sea was conducted at three coastal regions in Thailand upper Gulf of Thailand, southern Gulf of Thailand, and Andaman coasts. It is revealed that chloride deposition rates are exponentially decaying functions of distance from the sea. The chloride deposition rate at the coast is ranked from low to high as upper Gulf of Thailand less then less then Andaman less then southern Gulf of Thailand. Sea wind also contributes to chloride deposition rate based on run of wind (ROW) parameter. In this work, both correlative functions of chloride deposition rate with either sea wind speed during prevailing sea wind period or annual monthly ROW are compared. Furthermore, corrosion map constructed from chloride raster layer is presented and validated. A web application of Thailand corrosion map from this work is launched for public access to corrosion rate of carbon steel (SS400) and weathering steel (Corten-B). The chloride distribution model based on run of wind parameter can be applied to coastal regions with varying seasonal wind characteristic for example California, Florida, Italy, Malaysia, and South Korea.Soil erosion affects agricultural landscapes worldwide, threatening food security and ecosystem viability. In arable environments, soil loss is primarily caused by short, intense rainstorms, typically characterized by high spatiotemporal variability. The complexity of erosive events challenges modeling efforts and explicit inclusion of extreme events in long-term risk assessment is missing. This study is intended to bridge this gap by quantifying the discrete and cumulative impacts of rainstorms on plot-scale soil erosion and providing storm-scale erosion risk analyses for a cropland region in northern Israel. Central to our analyses is the coupling of (1) a stochastic rainfall generator able to reproduce extremes down to 5-minute temporal resolutions; (2) a processes-based event-scale cropland erosion model (Dynamic WEPP, DWEPP); and, (3) a state-of-the-art frequency analysis method that explicitly accounts for rainstorms occurrence and properties. To our knowledge, this is the first study in which DWEPP runoff and soil loss are calibrated at the plot-scale on cropland (NSE is 0.82 and 0.79 for event runoff and sediment, respectively). We generated 300-year stochastic simulations of event runoff and sediment yield based on synthetic precipitation time series. Based on this data, the mean annual soil erosion in the study site is 0.1 kg m-2 [1.1 t ha-1]. Results of the risk analysis indicate that individual extreme rainstorms (>50 return period), characterized by high rainfall intensities (30-minute maximal intensity > ~60 mm h-1) and high rainfall depth (>~200 mm), can trigger soil losses even one order of magnitude higher than the annual mean. The erosion efficiency of these rainstorms is mainly controlled by the short-duration (≤30 min) maximal intensities. The results demonstrate the importance of incorporating the impact of extreme events into soil conservation and management tools. We expect our methodology to be valuable for investigating future changes in soil erosion with changing climate.