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Controlling dynamical fluctuations in open quantum systems is essential both for our comprehension of quantum nonequilibrium behavior and for its possible application in near-term quantum technologies. However, understanding these fluctuations is extremely challenging due, to a large extent, to a lack of efficient important sampling methods for quantum systems. Here, we devise a unified framework-based on population-dynamics methods-for the evaluation of the full probability distribution of generic time-integrated observables in Markovian quantum jump processes. These include quantities carrying information about genuine quantum features, such as quantum superposition or entanglement, not accessible with existing numerical techniques. The algorithm we propose provides dynamical free-energy and entropy functionals which, akin to their equilibrium counterpart, permit one to unveil intriguing phase-transition behavior in quantum trajectories. We discuss some applications and further disclose coexistence and hysteresis, between a highly entangled phase and a low entangled one, in large fluctuations of a strongly interacting few-body system.The outcomes of fuel drop impact on heated walls will affect the fuel-air mixture distribution and the subsequent combustion and emissions in internal combustion engines. Existing numerical models for drop-wall interactions are mainly validated for conditions at atmospheric pressures. In this work, a numerical method, based on smoothed particle hydrodynamics, was developed to simulate the drop impact on a heated wall at high pressures. The effects of high temperature and high pressure on the evaporation of the drop were considered. The impact regimes under various wall temperatures and ambient pressures were identified, including deposit, contact splash, film splash, and rebound. Numerical predictions were validated by experimental observations. The present method predicted the increase in the critical temperature above which the drop would rebound as the ambient pressure increased. For example, for n-heptane drop impact on a 200 °C wall at We=50, the drop rebounds at 1 bar but deposits at 20 bars ambient pressure. The present method is able to capture the shift in the Leidenfrost point with the change in ambient pressure. The ability to predict such effects of the ambient pressure on drop-wall interactions is important in simulating spray impingement at realistic engine conditions.Spiral waves of excitation are common in many physical, chemical, and biological systems. In physiological systems like the heart, such waves can lead to cardiac arrhythmias and need to be eliminated. Spiral waves anchor to heterogeneities in the excitable medium, and to eliminate them they need to be unpinned first. Several groups focused on developing strategies to unpin such pinned waves using electric shocks, pulsed electric fields, and recently, circularly polarized electric fields (CPEF). It was shown that in many situations, CPEF is more efficient at unpinning the wave compared to other existing methods. Here, we study how the circularly polarized field acts on the pinned spiral waves and unpins it. We show that the termination always happens within the first rotation of the electric field. For a given obstacle size, there exists a threshold time period of the CPEF below which the spiral can always be terminated. Our analytical formulation accurately predicts this threshold and explains the absence of the traditional unpinning window with the CPEF. We hope our theoretical work will stimulate further experimental studies about CPEF and low energy methods to eliminate spiral waves.We investigate coarsening dynamics in the two-dimensional, incompressible Toner-Tu equation. We show that coarsening proceeds via vortex merger events, and the dynamics crucially depend on the Reynolds number Re. For low Re, the coarsening process has similarities to Ginzburg-Landau dynamics. On the other hand, for high Re, coarsening shows signatures of turbulence. In particular, we show the presence of an enstrophy cascade from the intervortex separation scale to the dissipation scale.Recently, the importance of higher-order interactions in the physics of quantum systems and nanoparticle assemblies has prompted the exploration of new classes of networks that grow through geometrically constrained simplex aggregation. Based on the model of chemically tunable self-assembly of simplexes [Šuvakov et al., Sci. Rep. 8, 1987 (2018)2045-232210.1038/s41598-018-20398-x], here we extend the model to allow the presence of a defect edge per simplex. Using a wide distribution of simplex sizes (from edges, triangles, tetrahedrons, etc., up to 10-cliques) and various chemical affinity parameters, we investigate the magnitude of the impact of defects on the self-assembly process and the emerging higher-order networks. Their essential characteristics are treelike patterns of defect bonds, hyperbolic geometry, and simplicial complexes, which are described using the algebraic topology method. Furthermore, we demonstrate how the presence of patterned defects can be used to alter the structure of the assembly after the growth process is complete. In the assemblies grown under different chemical affinities, we consider the removal of defect bonds and analyze the progressive changes in the hierarchical architecture of simplicial complexes and the hyperbolicity parameters of the underlying graphs. https://www.selleckchem.com/products/ff-10101.html Within the framework of cooperative self-assembly of nanonetworks, these results shed light on the use of defects in the design of complex materials. They also provide a different perspective on the understanding of extended connectivity beyond pairwise interactions in many complex systems.Intuition tells us that a rolling or spinning sphere will eventually stop due to the presence of friction and other dissipative interactions. The resistance to rolling and spinning or twisting torque that stops a sphere also changes the microstructure of a granular packing of frictional spheres by increasing the number of constraints on the degrees of freedom of motion. We perform discrete element modeling simulations to construct sphere packings implementing a range of frictional constraints under a pressure-controlled protocol. Mechanically stable packings are achievable at volume fractions and average coordination numbers as low as 0.53 and 2.5, respectively, when the particles experience high resistance to sliding, rolling, and twisting. Only when the particle model includes rolling and twisting friction were experimental volume fractions reproduced.

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