Fitzsimmonsfyhn4205

13, 0.35 and 0.13. According to Pearson correlation coefficients, soil exchangeable Cd concentration has significantly (P less then 0.05) negative correlation with soil pH and EC, but has significantly (P less then 0.05) positive correlation with soil Eh. The Cd concentration of rice grain has significantly (P less then 0.05) positive correlation with Cd of leaf, and negative correlation with Cd of husk. It is concluded that organic fertilizer combined with continuous flooding was most effective management strategy for Cd remediation in paddy soil.The control of interfacial microbial pollution is of great significance for water safety. Herein, the tribo-catalysis ability of zinc oxide (ZnO) has been investigated, which can realize the control of tightly-bound extracellular polymeric substances (T-EPS) in water under dark environment. The DFT calculation proves the Fe doping introduces the impurity level and decreases the work function from 5.071 eV to 5.045 eV, improves the charge separation of ZnO, and eventually enhances the catalytic reaction efficiency. Characterizing the catalytic reaction process by three-dimensional fluorescence (3D EEM) and fluorescence regional integration (FRI) method, it is found that the T-EPS solution can be degraded 75.8% by Fe-ZnO in 12 min, while ZnO can only degrade 32.2%. Combining with high-resolution scanning probe microscope (HR-SPM) and attenuated total reflection method (ATR-FTIR), hydration layers consist with hydroxyl layer (∼0.23 nm) and water molecular layer (∼0.27 nm) are observed at the interface between Fe-ZnO and T-EPS solution, and terminal hydroxyl group (OHt) is considered to be the active site for the generation of radicals. This study provides an idea for exploring the mechanism of tribo-catalytic reaction and shows its application prospect in the field of microbial inhibition in water.Volatile organic compounds (VOC) and polycyclic aromatic hydrocarbons (PAH), emitted in the environment from a wide range of combustion sources, are hazardous to human health and considered important precursors of both primary and secondary particulate pollutants. In the present work, light hydrocarbons up to C9, as main components of combustion-derived VOC, and PAH produced in fuel-rich conditions of premixed ethylene flames were analyzed by implementing a molecular-beam time of flight mass spectrometer (MB-TOFMS), purposely built for on-line fast monitoring of the environmental impact of combustion systems. The reliability of the MB-TOFMS was preliminarily verified on a slightly-sooting flame, comparing the results with those obtained by batch sampling and gas chromatographic techniques. Electron ionization (EI) and multi-photon ionization (MPI) were used as MB-TOFMS sources and tested on combustion gases of a no-sooting premixed ethylene flame where VOC and PAH are present in traces not detectable with batch sampling and conventional analytical techniques. The mass identification accuracy was improved and guaranteed by systematically performing internal mass calibration, exploiting the formation of "in situ" clusters from combustion water in the molecular beam apparatus. Selective and sensitive monitoring of light hydrocarbons and PAH, derived from oxidation and pyrolysis reactions featuring combustion, was shown to be especially effective when using the MB-TOFMS equipped with MPI source. This technique showed to be effective also for the detection of radical species that are important for the risk assessment of aerosol and fundamental understanding of aerosol chemistry at a molecular level.Industrial waste materials such as Fly Ash (FA), Foundry Sand (FS) were used as support material by mixing them with clay to fix the catalyst. Where FA and FS served as an iron (Fe) source to induce the photo-Fenton process. The presence of Fe in FA and FS was affirmed by SEM-EDS characterization. UV-DRS was performed to analyze the bandgap of the composite which reduced from 2.96 to 2.82 eV after doping TiO2 with Ag. This composite was used to initiate photocatalysis. The fixing of catalyst on a support formed the Fe-Ag-TiO2 complex which led to the commencement of the in-situ dual process(i.e. photocatalysis and photo-Fenton) in fixed bed mode. After the optimization of several parameters such as H2O2 dose, the area covered by beads, A/V ratio, Flow rate, pH under solar irradiations for 60 min, 94.4% degradation of CIP was attained. XRD analysis was carried out to confirm the crystallographic phases of the composite anatase and rutile phases of TiO2 were present in the composite. The systematic leaching of iron took place in this process and was confirmed by iron estimation during the reaction process. To understand the elemental composition of the composite SEM-EDS was performed and the present of TiO2, Fe and Ag was affirmed. Composite beads were stable and active even after the 30 recycles as confirmed by SEM-EDS. G150 The intermediate products were analyzed by GC-MS analysis whereas the toxicity of the treated samples was studied by the zone inhibition test.Several air pollution episodes occurred in Beijing before and after the 2014 Asia-Pacific Economic Cooperation (APEC) summit, during which air-pollution control measures were implemented. Within this autumn-winter transit season, domestic heating started. Such interesting period merits comprehensive chemical characterization, particularly the organic species, to look into the influence of additional heating sources and the control measures on air pollution. Therefore, this study performed daily and 6h time resolved PM2.5 sampling from the 24th October to 7th December, 2014, followed by comprehensive chemical analyses including water-soluble ions, elements and organic source-markers. Apparent alterations of chemical profiles were observed with the initiation of domestic heating. Through positive matrix factorization (PMF) source apportionment modeling, six PM2.5 sources including secondary inorganic aerosol (SIA), traffic emission, coal combustion, industry emission, biomass burning and dust were separated and identified. Coal combustion was successfully distinguished from traffic emission by hopane diagnostic ratio. The result of this study reveals a gradual shift of dominating sources for PM pollution episodes from SIA to primary sources after starting heating. BaPeq toxicity from coal combustion increased on average by several to dozens of times in the heating period, causing both long-term and short-term health risk. Air mass trajectory analysis highlights the regional influence of the industry emissions from the area south to Beijing. Control measures taken during APEC were found to be effective for reducing industry source, but less effective in reducing the overall PM2.5 level. These results provide implications for policy making regarding appropriate air pollution control measures.