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Instrument-free, portable and direct read-out mini-devices have wider application prospects in various fields, especially for real-time/on-site detection in environmental science. Herein, a colorimetric fluorescent sensor for detecting cadmium ions (Cd2+) based on aggregation-induced emission (AIE) was established, fluorescent paper strips integrated with smartphone platform was further designed for the visualization, on-site and quantitative detection of Cd2+. The colorimetric fluorescent sensor was prepared by mixing orange emission glutathione-stabilized gold nanoclusters (AuNCs) with blue emission ethylenediamine functionalized graphene oxide (EDA-GO), and introducing copper ions (Cu2+) to quench the orange emission of AuNCs while the blue emission served as a background reference without color change. The Cd2+ can induce Cu2+-GSH-AuNCs to aggregation and emit orange fluorescence, causing the fluorescent color of the sensor changed from blue to red with the limit of detection (LOD) as low as 33.3 nM in solution. Moreover, fluorescent paper strips integrated with smartphone platform has a sensitive detection of Cd2+ with the LOD of 0.1 μM in rice samples. The method reported here might have great application prospects in real-time monitoring of foods safety and environmental protection. Poly(ionic liquid)s (PILs) are attractive for their various applications, but the use of porous PILs have rarely been reported in anionic pollutants removal via ion-exchange by column. Herein, we report a serial of crosslinked imidazolium-based mesoporous PILs with Cl- and Br- as anions for hexavalent chromium (Cr(VI)) and methyl orange (MO) removal. Among them, PDVIm-Cl-SCD, from the free-radical polymerization of a dicationic monomer (N,N'-methylene-bis(1-(3-vinylimidazolium)) chloride, DVIm-Cl) and further supercritical carbon dioxide drying (SCD), displayed a very high sorption capacity (328.2 mg g-1 at 25 °C) and excellent utilization of adsorption sites (UOA, 86.2%) towards Cr(VI), and an unprecedentedly high sorption capacity (1615.0 mg g-1 at 25 °C) with a UOA of 67.4% to MO. Moreover, PDVIm-Cl-SCD also exhibited a broad pH range, excellent regeneration and remarkable reusability. Regarding to Cr(VI) removal, the volume of saturated KCl aqueous used for regenerating the Cr(VI) saturated PDVIm-Cl-SCD column (7.5-9.5 mL) was much less than the volume of treated Cr(VI) solution (160-200 mL). IDO-IN-2 IDO inhibitor For MO removal, the volume of saturated NaCl solution used for regenerating the MO saturated PDVIm-Cl-SCD column (10.5-13.5 mL) was also much less than the volume of treated MO solution (220-235 mL), implying the great potential of PDVIm-Cl-SCD in sustainable wastewater treatment. A fresh adsorbent nanostructured chitosan/molecular sieve 4A hybrid (NSC@MS-4A) was fabricated for the rapid adsorption of strontium (Sr2+) and cesium (Cs+) ions from aqueous solutions. The as-obtained NSC@MS-4A were thoroughly characterized by XRD, FE-SEM, EDS, BET, XPS and FT-IR. The physio-chemical properties and structural aspects revealed that NSC@MS-4A acquires fine surface area (72 m2/g), porous structure as well as compatible functional groups (-P-O-P and -C-O-C) for the admission of Cs+ and Sr2+ ions. The batch adsorption studies concluded that prepared adsorbent displayed a maximum adsorption of 92-94 % within 40 min. Fast adsorption of Cs+ and Sr2+ was achieved at neutral pH (6-7), ambient temperature (25-30 °C) and slow agitation speed (50-60 rpm) which could propose vast benefits such as little power utilization and uncomplicated operation. Among six types of adsorption isotherms, Freundlich isotherm showed the best fit with R2>0.997. Pseudo-second order made a better agreement as compare to other kinetic models. The thermodynamic coefficients suggested the passage of Cs+ and Sr2+ ions through the liquid solid boundary is exothermic and spontaneous. The NSC@MS-4A displayed excellent regenerability properties over five repetitive adsorption/desorption cycles, which specified that as-obtained NSC@MS-4A is a sustainable as well as efficient adsorbent for practical decontamination of radioactive liquid waste. Developing efficient low-cost absorbents has been recognized as a prerequisite for industrial application of wet flue gas desulfurization (WFGD). Herein, hardened cement mortar (HCM) particles developed from waste concrete blocks were used as an innovative absorbent for SO2. The results show that the SO2 in flue gas can be completely absorbed by the highly alkaline HCM slurry. Under optimum operating conditions, 0.8 g of SO2 was retained by per gram of HCM. Under acid conditions produced upon dissolving SO2 in water, the Ca-rich compounds in HCM particles can continuously release Ca2+ and OH- into the HCM slurry. The Ca2+ ions released can effectively combine with SO32-, resulting in the absorption of SO2 dissolved in water. The dissolution process of HCM particles is well described by the pseudo-second-order model. The desulphurization byproduct was characterized by X-Ray diffraction (XRD) analysis, scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy and energy dispersive spectrometry (EDS). The results show that the desulphurization product mainly consists of gypsum. The technology developed provides a type of new material for removing SO2 in waste flue gas. It also offers an innovative solution for the disposal of waste concrete which is also a global environmental concern. Microorganisms play a vital role in soil biochemical process in contaminated managed ecosystems. In the present study, a field investigation was conducted in farmland around an industrial intensive region contaminated with cadmium, and the changes of microbial assemblages in contaminated soils were assessed by 16S rRNA sequencing and the further statistical analysis. The results revealed obvious variations in microbial richness between referenced and contaminated soils, with Proteobacteri, Chloroflexi, Actinobacteria, Acidobacteria and Nitrospirae dominating the studied communities around the industrial intensive region. Redundancy analysis and Spearman correlation heatmap revealed that about 68.95 % of overall variation in microbial community composition was explained by soil physiochemical properties and Cd existence, among which pH, soil total phosphorus, total nitrogen, organic carbon (OC) and available Cd were identified as dominant factors. No significant difference was found in the similarities and Beta-diversity analysis among different groups. In conclusion, this study revealed the ecological effects of physiochemical parameters and Cd stress on the diversity and abundance of microbial communities, and these findings provided the detailed and integrated correlation between the main factors and microbial indexes in Cd contaminated farmland around the industrial intensive region. V.The widely usage of ethylenediaminetetraacetic acid (EDTA) arises environmental concerns on toxic metal mobilization, and challenges the conventional processes in water treatment. In the study Cu(II)-EDTA in near natural water was efficiently removed during a two-step electrocoagulation using Fe(0) anode (Fe-EC), including a transformation to Fe(III)-EDTA induced mainly by structural Fe(II) in anoxic Fe-EC and further degradation in oxic Fe-EC. The degradation of Fe(III)-EDTA was mostly attributed to an oxygen activation mechanism that involving O2- and hydroxyl radical (OH) generation, as validated by the quenching experiments and electron spin resonance. Furthermore, O2- generated during Fe(II) oxidation took a dominant role on Fe(III)/Fe(II)-EDTA transformation instead of electrochemical reduction. Six intermediates during the Fe(III)-EDTA degradation were identified by LC-Q-TOF, indicating a pathway of stepwise breakage of NC bonds. The results revealed in this work is helpful to understand the contribution and fate of EDTA during Fe-EC treatment of metal-EDTA polluted water. V.Sorption is one of the key process that affects the fate and mobility of pharmaceuticals in the soil environment. Several models have been developed for estimating the sorption of organic chemicals, including ionisable compounds, in soil. However, the applicability of these models to pharmaceuticals has not been extensively tested. In this study, we generated a high-quality dataset on the sorption of twenty-one pharmaceuticals in different soil types and used these data to evaluate existing models and to develop new improved models. Sorption coefficients (Kd) of the pharmaceuticals ranged from 0.2 to 1249.2 L/kg. Existing models were unable to adequately estimate the measured sorption data. Using the data, new models were developed, incorporating molecular and soil descriptors, that outperformed the published models when evaluated against external data sets. While there is a need for further evaluation of these new models against broader sorption datasets obtained at environmentally relevant concentrations, in the future they could be highly useful in supporting environmental risk assessment and prioritization efforts for pharmaceutical ingredients. The accumulation of industrial plastic waste in the environment is a global growing concern. Thermochemical process is a preferred method to dispose plastic waste mainly because it can reduce volume of the waste; however, the thermochemical disposal of plastic waste can emit harmful chemical species such as benzene derivatives and polycyclic hydrocarbons. As an effort to overcome this challenge, supported metal catalysts (carbon-supported Pd and Pt catalysts) were used to inhibit the formation of polycyclic compounds and biphenyl derivatives by pyrolysis of polyethylene terephthalate (PET). Less polycyclic compounds and biphenyl derivatives were generated during the Pd or Pt-catalyzed PET pyrolysis than non-catalytic PET pyrolysis. The concentrations of polycyclic compounds and biphenyl derivatives were 107 % and 56 % lower for the Pt-catalyzed pyrolysis at 700 °C than non-catalytic pyrolysis, respectively. The Pt catalyst was more effective to suppress the generation of polycyclic compounds and biphenyl derivatives during the PET pyrolysis than the Pd catalyst at temperatures from 400 to 800 °C. This was likely because the Pt sites catalyzes decyclization reaction and/or free radical mechanism that is dominant in thermal cracking of carbonaceous substances such as PET. The results of this study would help develop environmentally friendly industrial plastic waste treatment methods via thermochemical processes. High saline phenolic wastewater is a typical toxic and refractory industrial wastewater. A single membrane-aerated biofilm reactor (MABR) was used to treat wastewater containing phenol, p-nitrophenol and hydroquinone under increasing phenolic loading and salinity conditions. More than 95 % of phenolic compounds were removed, and a removal efficiency of 8.9 g/m2 d for total phenolic (TP) contents was achieved under conditions with 32 g/L of salt and 763 mg/L of influent TP contents. The microbial diversity, structure and function of a biofilm exposed to different conditions were investigated by high-throughput 16S rRNA gene sequencing and metagenomics. Salinity and specific TP loading substantially affected the bacterial community. Gammaproteobacteria, Actinobacteria and Betaproteobacteria contributed more to initial phenolic compound degradation than other classes, with Pseudomonas and Rhodococcus as the main contributing genera. The key phenolic-degrading genes of different metabolic pathways were explored, and their relative abundance was strengthened with increasing phenolic loading and salinity.