Simpsonproctor8012

School psychologists have a variety of evidence-based interventions from which to choose when recommending classroom-based strategies for students with attention deficit hyperactivity disorder (ADHD); however, strategies frequently found on individualized education plans are accommodations designed to remove barriers to learning, which have limited empirical evidence. As such, the purpose of the current study was to compare the efficacy of three interventions (i.e., organization training, self-management, note-taking instruction) and three accommodations (i.e., organization support, extended time, copy of teacher notes) to address difficulties with organization and maintaining attention during a science lesson and associated independent practice. The study included 64 middle school students with ADHD randomized to either an intervention or an accommodation condition. The intervention group was further divided into two subgroups, consisting of (a) students who were willing to follow intervention procedures and (b) students who were not willing to follow the procedures (behavioral indicators of social validity). Results indicated that adolescents with ADHD in the intervention group were statistically significantly more likely to organize and maintain binder organization and to take complete and accurate notes than those in the accommodation group. In addition, exploratory analyses indicated that adolescents who demonstrated willingness to follow intervention procedures were more likely to be academically engaged during instruction and independent work and to complete independent work accurately than those who resisted the procedures.Many anti-bullying programs now emphasize the role of bystanders - youth who witness peer victimization. Using a large sample of adolescents (aged 12-18) from the United Kingdom who completed an online survey, the present study examined the types of bystander interventions, their outcomes, and reasons for intervening and not intervening. No significant group differences by any demographic group were found in intervening or not. Results showed that those who had a negative affective reaction when they witnessed bullying were more likely to intervene. Two intervening behaviors (telling the bully to stop and telling an adult) were the strongest predictors of positive results. The most frequently selected reason for not intervening was not knowing what to do, and for intervening, having prosocial and altruistic motives was most common. These and other results are discussed for theoretical and practical implications.Gas-liquid chromatography is an effective method to determine infinite dilution activity coefficients (γ∞). Wall-coated open-tubular (WCOT) column which offers more advantages over packed column should be a preferable column type; however, the small carrier gas flow rate and stationary phase amount in WCOT columns limit its application in the determination of γ∞. Mathematical strategy made some progress to avoid the quantification problem in the determination of γ∞ by static-wall-coated open-tubular (SWCOT) columns. However, the previously reported strategy was based on the assumption that SWCOT column was geometrically an ideal hollow cylinder, which indeed deviates from the reality. In this study, without that assumption, we derived a new microgeometry-independent equation by using the relationship between the hold-up volume (VM) and the volume of stationary phase (VL), and used it to measure the γ∞ of various organic solutes in two ionic liquids (ILs) 1‑butyl‑3-methylimidazolium dicyanamide and 1,3-dibutyronitrile-imidazolium bis((trifluoromethyl)sulfonyl)imide, both of which contain double cyano groups in the anion or cation. Phase loading study was adopted to eliminate the influence of interfacial adsorption to partition. selleck compound The infinite dilution partial molar excess enthalpy, selectivity and capacity were directly calculated from the experimental γ∞ values, and the linear solvation energy relationship (LSER) model was used to characterize the specific properties of both ILs. This new established equation will promote the application of SWCOT columns in thermodynamic measurement and benefit the fast screening of novel solvents for chemical separation processes.Complexation between poly(vinyl alcohol) (PVA) and borax in aqueous solution yields a dynamic polyelectrolyte. Study of chain conformation of such a polyelectrolyte is challenging due to the difficulty in separating different macromolecular species. In this study, we investigated conformation of dilute PVA chains complexed with borax in a wide concentration range between 0.02 and 78.6 mM using asymmetrical flow field-flow fractionation (AF4). We find that elution of the complexes is strongly influenced by the borax concentration owing to (1) the charged complex is repelled electrostatically by the charged bottom membrane of the AF4 channel, and (2) the Debye screening length reduces with increasing a charge density. The chain conformation of PVA-borax complexes depends on both polymer molar mass and borax concentration. At low borax concentrations of 0.02~0.5 mM, a transition from random coil to rod-like conformation is observed with increasing the chain size. At borax concentrations of 1 mM and higher, all chains become random coil owing to a reduced screening length of the electrostatic repulsion.An analytical procedure for the rapid and selective derivatization of free fatty acids into methyl esters directly in plasma without transmethylation of lipid-bound fatty acids was developed for their analysis by gas chromatography-mass spectrometry. The methyl esters of free fatty acids were obtained by reaction with methyl iodide in the solution of dipolar aprotic solvents and in the presence of solid bases. The mechanism of the methylation reaction with these reagents was investigated. Optimal conditions for the selective methylation of free fatty acids were established using different dipolar aprotic solvents and different solid bases. The possible transmethylation of covalently bonded fatty acids from plasma lipids has been investigated under different experimental conditions in order to be avoided. Total methylation of free fatty acids was achieved in 1 min at room temperature using methyl iodide and anhydrous potassium carbonate or sodium carbonate in dimethyl sulfoxide. Under these conditions, transmethylation of lipid-bound fatty acids was avoided.