Clinesteffensen9830

Organic matter effectively regulates nanoparticles transport. However, little is known about the effect of agricultural organic inputs on the transport of ferrihydrite nanoparticles (FHNPs) during aging. In this study, columns were filled with sand mixed with varying proportions of pristine, water-processing, or alkali-processing biochar or swine manure and used to simulate the release of organic matter and changes in surface roughness of sand grains during field aging. The influence of these factors on FHNPs transport was investigated using column experiments. The dissolved organic matter (DOM) (0.008-24.8 mg L-1) released from agricultural organic inputs decreased the zeta potential of the FHNPs from 30.8 mV to 14.6--48.9 mV and further caused electrostatic repulsion, osmotic repulsion, and elastic-steric repulsion between FHNPs and mixed sand, thus enhancing FHNPs transport. Ferrihydrite nanoparticles transport increased with increasing content of biochar and swine manure due to the increased amount of DOM. However, with the presence of organic inputs, surface roughness up to a certain degree (the increase in specific surface area up to 4.6 m2) became the dominant inhibition factor affecting FHNPs transport. After DOM release, agricultural organic inputs decreased the enhancement of FHNPs transport; with the increase input, their rougher surface gradually increased inhibition of FHNPs transport. The strongest FHNPs retention in the alkali-processing biochar (0.2-10%) or swine manure (1-2%) mixed sand columns indicated that fully aged agricultural organic inputs strongly inhibited FHNPs transport. Our findings provided novel insights into the critical influence of agricultural organic inputs and their aging on FHNPs transport, which changed gradually from enhancement to inhibition gradually. In this paper, the specific primary production required (SPPR expressed as kg-NPP/kg-fish in wet weight) of more than 1700 marine species were calculated directly from 96 published food web models using the newly developed SPPR calculation framework. The relationship between SPPR and other ecological factors were then statistically analyzed. Among- and within-species variability of SPPR were found to be both explained by trophic level (TL), suggesting similar mechanisms underpinning both sources of variability. Among species, we found that harvesting species at higher mean trophic levels (MTL) increases the mean SPPR by a factor of 19 per 1 unit increase in MTL. Based on our empirical relationship, the mean SPPR of more than 9000 marine species were predicted and subsequently used to assess the primary production required (PPR) to support fisheries in five major fishing countries in Europe. The results indicated that conventional approach to estimating PPR, which neglects food web ecology, can underestimate PPR by up to a factor of 5. Within species, we found that harvesting populations occupying a higher TL leads to a higher SPPR. For example, the SPPR of Atlantic cod in the Celtic Sea (TL = 4.75) was 5 times higher than in the Gilbert Bay (TL = 3.3). Our results, which are based on large amounts of field data, highlight the importance of properly accounting for ecological factors during the impact assessment of fisheries. The unexpected impact of nanoparticles on environment and human health remains as a matter of concern. In this sense, understanding the interaction between nanoparticles and biological indicators such as microorganism may help to understand their fate and effect in environmental systems. However, the adverse effect of nanoparticles greatly depends on their properties and, therefore, a precise evaluation of nanoparticles physicochemical characteristics is mandatory as the first step in accurately elucidating their behaviour in different ecosystems. Here in this work, in house-synthesized tellurium-based nanoparticles have been fully characterized for first time by means of a multi-method approach. Once characterized, the effect of these nanoparticles on Staphylococcus aureus and Escherichia coli biofilm biomass and structure was explored and quantified for first time. Moreover, the morphological transformations of tellurium based nanoparticles within the confines of a biofilm are also highlighted. Architectural metric calculations evidenced that nanoparticles were able to reduce the biovolume of the biofilm produced for both bacteria. Interestingly, the interaction between nanoparticles and bacterial communities led to the transformation of tellurium nanoparticles from sphere to rod-shaped nanoparticles. These findings open new insights into the behaviour of a type of uncommon nanoparticles such as tellurium-based nanoparticles on microbial communities. The dependence of aerosol optical properties on the chemical composition and size of particles in haze in Beijing was studied. We measured the scattering coefficient of dehydrated PM2.5 aerosols (σsp_dry) and analyzed the chemical composition of PM2.5. We also monitored the size distribution of particles in the range of ~10-700 nm to observe the particle growth (PGsize). Results showed that the concentrations of secondary inorganic aerosols (SIAs) and the mean size of PM2.5 particles (scattering Ångström exponent decreasing) increased with the deterioration of the air quality and increase in relative humidity (RH) which enhanced mass scattering efficiency and increased PM2.5. Thus, the increase in σsp_dry was particularly dramatic and highly sensitive to the ambient RH in severe haze stages. GSK-3 inhibitor When the ratio of SIAs to PM2.5 (MSIAs) exceeded 0.35 during the polluted environment, the water content, PGsize, and σsp_dry showed distinct increases, indicating that the formation of SIAs enhanced water vapor condensation and particle growth. This finding revealed the existence of a critical value for MSIAs in terms of describing the correlation of σsp_dry variation with pollution severity. The estimation of the respective contributions of individual components to σsp_dry with the IMPROVE formula revealed that ammonium nitrate and ammonium sulfate were the two largest contributors. These results indicate that the rapid formation of SIAs and PGsize under humid conditions are the key factors contributing to the increased σsp_dry via enhanced mass scattering efficiency and increased PM2.5 in the severe haze observed in this study.